Order–disorder phase transition coupled with torsion in tri-n-butylammonium trichloroacetate (TBAT)

2015 ◽  
Vol 3 (23) ◽  
pp. 6053-6057 ◽  
Author(s):  
Muhammad Adnan Asghar ◽  
Chengmin Ji ◽  
Yuelan Zhou ◽  
Zhihua Sun ◽  
Tariq Khan ◽  
...  
Keyword(s):  
Phase Transition ◽  
Hybrid Material ◽  
Disorder Phase Transition ◽  
Reversible Phase Transition ◽  
Reversible Phase

Tri-n-butylammonium trichloroacetate (TBAT), a novel hybrid material, undergoes a reversible phase transition around 196 K, which is triggered by torsion in the cations and the order–disorder transformations of both ions.

Reversible phase transition driven by order–disorder transformations of metal-halide moieties in [(C6H14)NH2]2·CuBr4

2016 ◽  
Vol 4 (32) ◽  
pp. 7537-7540 ◽  
Author(s):  
Muhammad Adnan Asghar ◽  
Shuquan Zhang ◽  
Tariq Khan ◽  
Zhihua Sun ◽  
Aurang Zeb ◽  
...  
Keyword(s):  
Phase Transition ◽  
Order Phase Transition ◽  
Hybrid Material ◽  
Metal Halide ◽  
Inorganic Hybrid ◽  
First Order ◽  
First Order Phase Transition ◽  
Reversible Phase Transition ◽  
First Order Phase ◽  
Reversible Phase

[(C6H14)NH2]2·CuBr4 (1), an organic–inorganic hybrid material, undergoes a reversible first-order phase transition around 194 K, triggered by the order–disorder transformation of metal-coordinated halogen atoms.

Temperature-Dependent Solid-state Luminescence and Reversible Phase Transition of (n-Bu4N)[Au(SC6H3-3,5-Me2)2]

2003 ◽  
Vol 32 (11) ◽  
pp. 1002-1003 ◽  
Author(s):  
Seiji Watase ◽  
Takayuki Kitamura ◽  
Nobuko Kanehisa ◽  
Masami Nakamoto ◽  
Yasushi Kai ◽  
...  
Keyword(s):  
Phase Transition ◽  
Solid State ◽  
Temperature Dependent ◽  
Reversible Phase Transition ◽  
Reversible Phase ◽  
State Luminescence

Photoinduced reversible phase transition of azobenzene-containing polydiacetylene crystals

2016 ◽  
Vol 52 (97) ◽  
pp. 14059-14062 ◽  
Author(s):  
Woohyun Baek ◽  
Jung-Moo Heo ◽  
Seungwhan Oh ◽  
Sang-hwa Lee ◽  
Jaeyong Kim ◽  
...  
Keyword(s):  
Phase Transition ◽  
Reversible Phase Transition ◽  
Reversible Phase

A photoinduced reversible phase transition with a simultaneous crystal tearing phenomenon was observed in an azobenzene-containing supramolecular polydiacetylene (PDA) crystal.

Preparation of PVA/PEG Phase Change Composite Nanofibers by Electrospinning

2011 ◽  
Vol 306-307 ◽  
pp. 37-40 ◽  
Author(s):  
Da Hui Sun ◽  
Tian Yu Xu ◽  
Yong Jia Liu ◽  
Mei Zhang
Keyword(s):  
Phase Transition ◽  
Phase Change ◽  
Composite Nanofibers ◽  
Diameter Distribution ◽  
Weight Percentage ◽  
Weight Content ◽  
Reversible Phase Transition ◽  
Change Characteristics ◽  
Micro Morphology ◽  
Reversible Phase

Phase change PVA / PEG composite nanofibers were prepared by electrospinning, micro-morphology of PVA / PEG fibers with different weight content were analyzed, the phase change characteristics were also analyzed. The result showed that well distributed composite nanofibers which composed by PVA/PEG blend solution can be obtained by electrospinning.PVA fibreforming were influenced because of the existence of PEG, including bond, irregular block, small rough, uneven diameter distribution in fibers. PVA/PEG blend solution of 4:6 weight content was well fibreforming compared with other different weight content.The continuity of spinneret flow in electrospinning would directly affected by polymer solution consentrition and viscosity. Further research about which and the influence in fibers diameter and morphology will be explored. Composite nanofibers possessed reversible phase transition characteristics,Tm Essentially unchanged ,Tcwere related to the weight percentage of PEG/PVA, at the same time, the enthalpy will increase along with the gradually increase in weight percentage of PEG.

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