Multi-stimuli-responsive self-healing metallo-supramolecular polymer nanocomposites

2016 ◽  
Vol 4 (9) ◽  
pp. 3324-3334 ◽  
Author(s):  
Qifeng Zheng ◽  
Zhenqiang Ma ◽  
Shaoqin Gong
Keyword(s):  
Mechanical Properties ◽  
Polymer Nanocomposites ◽  
Supramolecular Polymer ◽  
Self Healing ◽  
Stimuli Responsive ◽  
Rare Combination

Metallo-supramolecular polymer nanocomposites show a rare combination of strong, tough, and elastic mechanical properties and were able to self-heal via multiple stimuli.

Supramolecular polymer gel with multi stimuli responsive, self-healing and erasable properties generated by host–guest interactions

Polymer ◽  
2013 ◽  
Vol 54 (26) ◽  
pp. 6929-6935 ◽  
Author(s):  
Fei Zeng ◽  
Ying Han ◽  
Zhi-Chao Yan ◽  
Chen-Yang Liu ◽  
Chuan-Feng Chen
Keyword(s):  
Supramolecular Polymer ◽  
Self Healing ◽  
Polymer Gel ◽  
Stimuli Responsive

Light- and Magnetic-Responsive Synergy Controlled Reconfiguration of Polymer Nanocomposites with Shape Memory Assisted Self-Healing Performance for Soft Robotics

2021 ◽  
Author(s):  
Yi Chen ◽  
Xing Zhao ◽  
Yan Li ◽  
Zhao-Yuan Jin ◽  
Yi Yang ◽  
...  
Keyword(s):  
Shape Memory ◽  
Polymer Nanocomposites ◽  
Soft Robotics ◽  
Self Healing ◽  
Stimuli Responsive ◽  
Biomimetic Materials ◽  
Intelligent Materials

Stimuli-responsive intelligent biomimetic materials are promoting the development of soft robotics. Despite tremendous advances in stimuli-responsive intelligent materials, it is still a challenge to design facile methods to integrate multifunctional...

scholarly journals Healable thermoset polymer composite embedded with stimuli-responsive fibres

2012 ◽  
Vol 9 (77) ◽  
pp. 3279-3287 ◽  
Author(s):  
Guoqiang Li ◽  
Harper Meng ◽  
Jinlian Hu
Keyword(s):  
Mechanical Properties ◽  
Human Skin ◽  
Biological Systems ◽  
Healing Process ◽  
Self Healing ◽  
Stimuli Responsive ◽  
Closed Crack ◽  
Healing Efficiency ◽  
Thermoset Polymer ◽  
Crack Interface

Severe wounds in biological systems such as human skin cannot heal themselves, unless they are first stitched together. Healing of macroscopic damage in thermoset polymer composites faces a similar challenge. Stimuli-responsive shape-changing polymeric fibres with outstanding mechanical properties embedded in polymers may be able to close macro-cracks automatically upon stimulation such as heating. Here, a stimuli-responsive fibre (SRF) with outstanding mechanical properties and supercontraction capability was fabricated for the purpose of healing macroscopic damage. The SRFs and thermoplastic particles (TPs) were incorporated into regular thermosetting epoxy for repeatedly healing macroscopic damages. The system works by mimicking self-healing of biological systems such as human skin, close (stitch) then heal, i.e. close the macroscopic crack through the thermal-induced supercontraction of the SRFs, and bond the closed crack through melting and diffusing of TPs at the crack interface. The healing efficiency determined using tapered double-cantilever beam specimens was 94 per cent. The self-healing process was reasonably repeatable.

scholarly journals Recent developments: self-healing polymers based on quadruple hydrogen bonds

2021 ◽  
Vol 290 ◽  
pp. 01037
Author(s):  
Guangpu Zhang ◽  
Zhe Sun ◽  
Miaomiao Li
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Supramolecular Polymer ◽  
Self Healing ◽  
Wearable Electronics ◽  
Stimuli Responsive ◽  
High Thermodynamic Stability ◽  
Recent Developments ◽  
Quadruple Hydrogen Bonding ◽  
Quadruple Hydrogen Bond

The microcrack of materials was inevitable in the process of transportation, storage and utilization, which may cause functional failure and resources waste. Inspired by nature, self-healing polymers have attracted significant attention owing to widespread applications in wearable electronics, cartilage replacement, coatings and elastomer. Compared with extrinsic healing, intrinsically healable polymers offer multiple self-healing by supramolecular reversible interactions, such as host-guest interactions, π-π stacking, ionic interactions and hydrogen-bonding. Self-healing polymers based on quadruple hydrogen bonds have been extensively investigated due to its high thermodynamic stability and rapid kinetic reversibility, and have been well developed for the past two decades. In this paper, the strategies and designs of self-repairing polymers based on quadruple hydrogen bond were classified and summarized, including main-chain self-healing polymers, side-chain self-healing polymers and supramolecular self-healing polymers. It is expected that quadruple hydrogen bonding can be construct more robust, highly tough, multi-stimuli-responsive, and fast self-healing supramolecular polymer, and is potential to be applied to numerous civilian and military fields in the future.

Autonomous self-healing polyisoprene elastomers with high modulus and good toughness based on the synergy of dynamic ionic crosslinks and highly disordered crystals

2020 ◽  
Vol 11 (41) ◽  
pp. 6549-6558
Author(s):  
Yohei Miwa ◽  
Mayu Yamada ◽  
Yu Shinke ◽  
Shoichi Kutsumizu
Keyword(s):  
Mechanical Properties ◽  
Room Temperature ◽  
Self Healing ◽  
High Modulus ◽  
Disordered Crystals ◽  
Ionic Crosslinks

We designed a novel polyisoprene elastomer with high mechanical properties and autonomous self-healing capability at room temperature facilitated by the coexistence of dynamic ionic crosslinks and crystalline components that slowly reassembled.

Polypyrrole/PU hybrid hydrogels: electrically conductive and fast self-healing for the potential application in body-monitor sensor

2021 ◽  
Author(s):  
Zhanyu Jia ◽  
Guangyao Li ◽  
Juan Wang ◽  
shouhua Su ◽  
Jie Wen ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Electrical Conductivity ◽  
Potential Application ◽  
Self Healing ◽  
Electrically Conductive ◽  
Sensor Application ◽  
Hybrid Hydrogels ◽  
Health Monitor

Conductivity, self-healing and moderate mechanical properties are necessary for multifunctional hydrogels which have great potential in health-monitor sensor application. However, the combination of electrical conductivity, self-healing and good mechanical properties...

Self-healing, Highly Elastic and Amphiphilic Silicone-based Polyurethane for Antifouling Coatings

2021 ◽  
Author(s):  
Xiaobin Lin ◽  
Qingyi Xie ◽  
Chunfeng Ma ◽  
Guangzhao Zhang
Keyword(s):  
Mechanical Properties ◽  
Silicone Elastomer ◽  
Self Healing ◽  
Fouling Resistance ◽  
The Poor ◽  
Antifouling Coatings ◽  
Fouling Release

Silicone elastomer coatings have attracted increasing attention owing to its eco-friendly nature, excellent fouling release ability and drag-reducing property. However, the poor mechanical properties and lack of fouling resistance limits...

Sign in / Sign up

Export Citation Format

Share Document