scholarly journals Effect of side chain length on the charge transport, morphology, and photovoltaic performance of conjugated polymers in bulk heterojunction solar cells

2016 ◽  
Vol 4 (5) ◽  
pp. 1855-1866 ◽  
Author(s):  
Chunhui Duan ◽  
Robin E. M. Willems ◽  
Jacobus J. van Franeker ◽  
Bardo J. Bruijnaers ◽  
Martijn M. Wienk ◽  
...  

The effect of side chain length on the photovoltaic properties of conjugated polymers is systematically investigated.

2015 ◽  
Vol 6 (6) ◽  
pp. 962-972 ◽  
Author(s):  
M. G. Murali ◽  
Arun D. Rao ◽  
Sarita Yadav ◽  
Praveen C. Ramamurthy

A new low band gap conjugated polymer PBDO-T-TDP is synthesized and used as a sensitizer in P3HT:PCBM based BHJ solar cells and its effect on their photovoltaic properties is investigated by blending them at various weight ratios.


2019 ◽  
Vol 43 (33) ◽  
pp. 12950-12956 ◽  
Author(s):  
Kangqiao Ma ◽  
Tao Zhang ◽  
Pan Wan ◽  
Bowei Xu ◽  
Pengxin Zhou ◽  
...  

Two conjugated polymers with different side chains were synthesized to study their photovoltaic performances.


Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1064 ◽  
Author(s):  
Tomasz Jarosz ◽  
Karolina Gebka ◽  
Kinga Kepska ◽  
Mieczyslaw Lapkowski ◽  
Przemyslaw Ledwon ◽  
...  

A new type of polysiloxane copolymers, with conjugated–regioregular poly(3-hexylthiophene) (P3HT) and non-conjugated-poly(ethylene glycol) (PEG)-grafts have been synthesised, and their properties have been studied alongside those of the parent conjugated polymer (P3HT). Spectroelectrochemical and conductometric analyses revealed an early rise of the conductance of the polymers. Once spectral changes begin taking place, the conductance is stable, implying a loss of mobility of charge carriers, even though standard doping/dedoping patterns are observed. Prototype bulk heterojunction solar cells have been fabricated, based on P3HT/[6,6]-Phenyl-C61-butyric acid methyl ester (PCBM), as well as by substituting P3HT for each of the copolymers. The prototype solar cells achieved PCEs of up to 2.11%. This is one of the highest reported power conversion efficiency (PCE) for devices based on P3HT with low average molecular weight Mn = 12 kDa. Strong correlation between the structure of the copolymer and its photovoltaic performance was found. Elongation of PEG copolymer chain and the use of methyl group instead of terminal hydroxyl groups significantly improved photovoltaic performance.


RSC Advances ◽  
2017 ◽  
Vol 7 (2) ◽  
pp. 1016-1025 ◽  
Author(s):  
Rong-Ho Lee ◽  
Lun-Cheng Yang ◽  
Jeng-Yue Wu ◽  
Ru-Jong Jeng

Synthesis of diketopyrrolopyrrole derivatives based side-chain conjugated polymers for solar cells.


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