scholarly journals The lighter side of MOFs: structurally photoresponsive metal–organic frameworks

2016 ◽  
Vol 4 (18) ◽  
pp. 6714-6723 ◽  
Author(s):  
C. L. Jones ◽  
A. J. Tansell ◽  
T. L. Easun
Keyword(s):  
Metal Organic Frameworks ◽  
Design Strategies ◽  
Metal Organic

Shedding light on the design strategies used to make structurally photoactive metal–organic frameworks.

Metal–organic frameworks as separators and electrolytes for lithium–sulfur batteries

2021 ◽  
Vol 9 (12) ◽  
pp. 7301-7316
Author(s):  
Zihao Chu ◽  
Xiaochun Gao ◽  
Chengyin Wang ◽  
Tianyi Wang ◽  
Guoxiu Wang
Keyword(s):  
Metal Organic Frameworks ◽  
Design Strategies ◽  
Lithium Sulfur Batteries ◽  
Metal Organic ◽  
Lithium Sulfur

This review provides a specialized summary of metal–organic frameworks as separators and electrolytes for lithium–sulfur batteries, including design strategies and applications.

Recent advances in molecular logic gate chemosensors based on luminescent metal organic frameworks

2021 ◽  
Author(s):  
Bei Li ◽  
Dongsheng Zhao ◽  
Feng Wang ◽  
Xiaoxian Zhang ◽  
Wenqian Li ◽  
...  
Keyword(s):  
Logic Gate ◽  
Metal Organic Frameworks ◽  
Logic Gates ◽  
Design Strategies ◽  
Molecular Logic Gate ◽  
Future Developments ◽  
Molecular Logic ◽  
Molecular Logic Gates ◽  
Recent Advances ◽  
Metal Organic

This review covers the latest advancements of molecular logic gates based on LMOF. The classification, design strategies, related sensing mechanisms, future developments, and challenges of LMOFs-based logic gates are discussed.

Conductive Metal–Organic Frameworks: Mechanisms, Design Strategies and Recent Advances

2020 ◽  
Vol 378 (2) ◽  
Author(s):  
Xiangling Deng ◽  
Jie-Ying Hu ◽  
Jiye Luo ◽  
Wei-Ming Liao ◽  
Jun He
Keyword(s):  
Metal Organic Frameworks ◽  
Design Strategies ◽  
Recent Advances ◽  
Metal Organic

scholarly journals A Review on Breathing Behaviors of Metal-Organic-Frameworks (MOFs) for Gas Adsorption

2021 ◽  
Author(s):  
Mays Alhamami ◽  
Huu Doan ◽  
Chil-Hung Cheng
Keyword(s):  
Molecular Sieves ◽  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Design Strategies ◽  
Surface Areas ◽  
Host Materials ◽  
Potential Applications ◽  
Metal Organic ◽  
Definition Of ◽  
Dynamics Simulations

Metal-organic frameworks (MOFs) are a new class of microporous materials that possess framework flexibility, large surface areas, “tailor-made” framework functionalities, and tunable pore sizes. These features empower MOFs superior performances and broader application spectra than those of zeolites and phosphine-based molecular sieves. In parallel with designing new structures and new chemistry of MOFs, the observation of unique breathing behaviors upon adsorption of gases or solvents stimulates their potential applications as host materials in gas storage for renewable energy. This has attracted intense research energy to understand the causes at the atomic level, using in situ X-ray diffraction, calorimetry, Fourier transform infrared spectroscopy, and molecular dynamics simulations. This article is developed in the following order: first to introduce the definition of MOFs and the observation of their framework flexibility. Second, synthesis routes of MOFs are summarized with the emphasis on the hydrothermal synthesis, owing to the environmental-benign and economically availability of water. Third, MOFs exhibiting breathing behaviors are summarized, followed by rationales from thermodynamic viewpoint. Subsequently, effects of various functionalities on breathing behaviors are appraised, including using post-synthetic modification routes. Finally, possible framework spatial requirements of MOFs for yielding breathing behaviors are highlighted as the design strategies for new syntheses.

scholarly journals Electrical Conductivity in a Porous, Cubic Rare-Earth Catecholate

2020 ◽  
Author(s):  
Grigorii Skorupskii ◽  
Mircea Dinca
Keyword(s):  
Charge Transport ◽  
Electronic Materials ◽  
Metal Organic Frameworks ◽  
Electrical Current ◽  
Design Strategies ◽  
Electrically Conductive ◽  
Surface Areas ◽  
New Family ◽  
Structures And Properties ◽  
Metal Organic

Electrically conductive metal-organic frameworks (MOFs) provide a rare example of porous materials that can efficiently transport electrical current, a combination favorable for a variety of technological applications. The vast majority of such MOFs are highly anisotropic in both their structures and properties: only two electrically conductive MOFs reported to date exhibit cubic structures that enable isotropic charge transport. Here, we report a new family of intrinsically porous frameworks made from rare earths and hexahydroxytriphenylene that are cubic, porous, and intrinsically conductive with conductivities reaching 10−5 S/cm and surface areas of up to 780 m2/g. By expanding the list of MOFs with isotropic charge transport, these results will help improve our understanding of design strategies for porous electronic materials.<br>

scholarly journals Design and properties of multiple-emitter luminescent metal–organic frameworks

2020 ◽  
Vol 56 (82) ◽  
pp. 12290-12306 ◽  
Author(s):  
Shanghua Xing ◽  
Christoph Janiak
Keyword(s):  
Metal Organic Frameworks ◽  
Emission Sources ◽  
Design Strategies ◽  
Feature Article ◽  
Metal Organic

This feature article reviews the design strategies by which multiple different emission sources could be combined for creating multi-emitter luminescent metal–organic frameworks (LMOFs).

scholarly journals Design Strategies for Enhanced Conductivity in Metal–Organic Frameworks

2021 ◽  
Vol 7 (3) ◽  
pp. 445-453
Author(s):  
Eric M. Johnson ◽  
Stefan Ilic ◽  
Amanda J. Morris
Keyword(s):  
Metal Organic Frameworks ◽  
Design Strategies ◽  
Metal Organic ◽  
Enhanced Conductivity

Design strategies of two-dimensional metal-organic frameworks toward efficient electrocatalysts for N2 reduction: Cooperativity of transition metals and organic linkers

Nanoscale ◽  
2021 ◽  
Author(s):  
Ran Wang ◽  
Chaozheng He ◽  
Weixing Chen ◽  
Ling Fu ◽  
Chenxu Zhao ◽  
...  
Keyword(s):  
Transition Metals ◽  
Active Sites ◽  
Metal Organic Frameworks ◽  
High Conductivity ◽  
Two Dimensional ◽  
Design Strategies ◽  
Metal Organic

Two-dimensional (2D) metal-organic frameworks (MOFs) serve as emerging electrocatalysts due to high conductivity, chemical tunability, and accessibility of active sites. We herein proposed a series of 2D MOFs with different...

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