scholarly journals Kinetic molecular sieving, thermodynamic and structural aspects of gas/vapor sorption on metal organic framework [Ni1.5(4,4′-bipyridine)1.5(H3L)(H2O)3][H2O]7 where H6L = 2,4,6-trimethylbenzene-1,3,5-triyl tris(methylene)triphosphonic acid

2016 ◽  
Vol 4 (4) ◽  
pp. 1353-1365 ◽  
Author(s):  
Xuebo Zhao ◽  
Jon G. Bell ◽  
Si-Fu Tang ◽  
Liangjun Li ◽  
K. Mark Thomas
Keyword(s):  
Metal Organic Framework ◽  
Vapor Sorption ◽  
Adsorption Characteristics ◽  
Vapor Adsorption ◽  
Metal Organic ◽  
Molecular Sieving ◽  
Structural Aspects ◽  
Organic Framework

A phosphonate based MOF was synthesized, the structure determined and gas/vapor adsorption characteristics studied.

Metal-organic framework nanosheets as building blocks for molecular sieving membranes

Science ◽  
2014 ◽  
Vol 346 (6215) ◽  
pp. 1356-1359 ◽  
Author(s):  
Y. Peng ◽  
Y. Li ◽  
Y. Ban ◽  
H. Jin ◽  
W. Jiao ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Building Blocks ◽  
Metal Organic ◽  
Molecular Sieving ◽  
Organic Framework

Photo-switchable smart metal–organic framework membranes with tunable and enhanced molecular sieving performance

2018 ◽  
Vol 6 (48) ◽  
pp. 24949-24955 ◽  
Author(s):  
Chuanyao Liu ◽  
Yunzhe Jiang ◽  
Chen Zhou ◽  
Jürgen Caro ◽  
Aisheng Huang
Keyword(s):  
Separation Factor ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Molecular Sieving ◽  
Organic Framework

A novel photo-switchable Cu(AzDC)(4,4′-BPE)0.5 membrane was developed with the H2/CO2 separation factor being switched reversibly between 21.3 and 43.7 after irradiation with Vis light (455 nm) and UV (365 nm).

Interfacial microfluidic processing of metal-organic framework hollow fiber membranes

Science ◽  
2014 ◽  
Vol 345 (6192) ◽  
pp. 72-75 ◽  
Author(s):  
Andrew J. Brown ◽  
Nicholas A. Brunelli ◽  
Kiwon Eum ◽  
Fereshteh Rashidi ◽  
J. R. Johnson ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Hollow Fibers ◽  
Membrane Fabrication ◽  
Separation Factors ◽  
Metal Organic ◽  
Membrane Defects ◽  
Molecular Sieving ◽  
Positional Control ◽  
Organic Framework

Molecular sieving metal-organic framework (MOF) membranes have great potential for energy-efficient chemical separations, but a major hurdle is the lack of a scalable and inexpensive membrane fabrication mechanism. We describe a route for processing MOF membranes in polymeric hollow fibers, combining a two-solvent interfacial approach for positional control over membrane formation (at inner and outer surfaces, or in the bulk, of the fibers), a microfluidic approach to replenishment or recycling of reactants, and an in situ module for membrane fabrication and permeation. We fabricated continuous molecular sieving ZIF-8 membranes in single and multiple poly(amide-imide) hollow fibers, with H2/C3H8 and C3H6/C3H8 separation factors as high as 370 and 12, respectively. We also demonstrate positional control of the ZIF-8 films and characterize the contributions of membrane defects and lumen bypass.

scholarly journals One-dimensional metal–organic framework photonic crystals used as platforms for vapor sorption

2012 ◽  
Vol 22 (20) ◽  
pp. 10356 ◽  
Author(s):  
Florian M. Hinterholzinger ◽  
Annekathrin Ranft ◽  
Johann M. Feckl ◽  
Bastian Rühle ◽  
Thomas Bein ◽  
...  
Keyword(s):  
Photonic Crystals ◽  
Metal Organic Framework ◽  
Vapor Sorption ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

Vapor Sorption and Solvatochromism in a Metal–Organic Framework of an Asymmetric Pyridylcarboxylate

2017 ◽  
Vol 18 (1) ◽  
pp. 416-423 ◽  
Author(s):  
Christelle N. Dzesse T ◽  
Emmanuel N. Nfor ◽  
Susan A. Bourne
Keyword(s):  
Metal Organic Framework ◽  
Vapor Sorption ◽  
Metal Organic ◽  
Organic Framework

Guest Adsorption in the Nanoporous Metal–Organic Framework Cu3(1,3,5-Benzenetricarboxylate)2: Combined In Situ X-ray Diffraction and Vapor Sorption

2014 ◽  
Vol 26 (16) ◽  
pp. 4712-4723 ◽  
Author(s):  
Vanessa K. Peterson ◽  
Peter D. Southon ◽  
Gregory J. Halder ◽  
David J. Price ◽  
Joseph J. Bevitt ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Vapor Sorption ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nanoporous Metal ◽  
Metal Organic ◽  
Organic Framework

Efficient SO2 Removal Using a Microporous Metal–Organic Framework with Molecular Sieving Effect

2019 ◽  
Vol 59 (2) ◽  
pp. 874-882 ◽  
Author(s):  
Yan Zhang ◽  
Zhonghang Chen ◽  
Xing Liu ◽  
Ze Dong ◽  
Peixin Zhang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
So2 Removal ◽  
Metal Organic ◽  
Molecular Sieving ◽  
Sieving Effect ◽  
Organic Framework
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