scholarly journals Highly pseudocapacitive Nb-doped TiO2 high power anodes for lithium-ion batteries

2015 ◽  
Vol 3 (45) ◽  
pp. 22908-22914 ◽  
Author(s):  
Mechthild Lübke ◽  
Juhun Shin ◽  
Peter Marchand ◽  
Dan Brett ◽  
Paul Shearing ◽  
...  

Nb-doped and pure TiO2 (anatase) nanoparticles were synthesized via a continuous hydrothermal flow synthesis reactor and investigated as electrode material for lithium-ion batteries.

2011 ◽  
Vol 158 (8) ◽  
pp. A930 ◽  
Author(s):  
Haegyeom Kim ◽  
Sung-Wook Kim ◽  
Jihyun Hong ◽  
Hee-Dae Lim ◽  
Hyung Sub Kim ◽  
...  

2015 ◽  
Vol 294 ◽  
pp. 94-102 ◽  
Author(s):  
Mechthild Lübke ◽  
Ian Johnson ◽  
Neel M. Makwana ◽  
Dan Brett ◽  
Paul Shearing ◽  
...  

2015 ◽  
Vol 51 (43) ◽  
pp. 8970-8973 ◽  
Author(s):  
Chunfu Lin ◽  
Guizhen Wang ◽  
Shiwei Lin ◽  
Jianbao Li ◽  
Li Lu

TiNb6O17, with a significantly larger capacity than Li4Ti5O12, fulfils the requirements of high power and energy density for electric vehicles.


2011 ◽  
Vol 196 (20) ◽  
pp. 8625-8631 ◽  
Author(s):  
J. Bains ◽  
L. Croguennec ◽  
J. Bréger ◽  
F. Castaing ◽  
S. Levasseur ◽  
...  

Author(s):  
Xinyue Li ◽  
Marco Fortunato ◽  
Anna Maria Cardinale ◽  
Angelina Sarapulova ◽  
Christian Njel ◽  
...  

AbstractNickel aluminum layered double hydroxide (NiAl LDH) with nitrate in its interlayer is investigated as a negative electrode material for lithium-ion batteries (LIBs). The effect of the potential range (i.e., 0.01–3.0 V and 0.4–3.0 V vs. Li+/Li) and of the binder on the performance of the material is investigated in 1 M LiPF6 in EC/DMC vs. Li. The NiAl LDH electrode based on sodium alginate (SA) binder shows a high initial discharge specific capacity of 2586 mAh g−1 at 0.05 A g−1 and good stability in the potential range of 0.01–3.0 V vs. Li+/Li, which is better than what obtained with a polyvinylidene difluoride (PVDF)-based electrode. The NiAl LDH electrode with SA binder shows, after 400 cycles at 0.5 A g−1, a cycling retention of 42.2% with a capacity of 697 mAh g−1 and at a high current density of 1.0 A g−1 shows a retention of 27.6% with a capacity of 388 mAh g−1 over 1400 cycles. In the same conditions, the PVDF-based electrode retains only 15.6% with a capacity of 182 mAh g−1 and 8.5% with a capacity of 121 mAh g−1, respectively. Ex situ X-ray photoelectron spectroscopy (XPS) and ex situ X-ray absorption spectroscopy (XAS) reveal a conversion reaction mechanism during Li+ insertion into the NiAl LDH material. X-ray diffraction (XRD) and XPS have been combined with the electrochemical study to understand the effect of different cutoff potentials on the Li-ion storage mechanism. Graphical abstract The as-prepared NiAl-NO3−-LDH with the rhombohedral R-3 m space group is investigated as a negative electrode material for lithium-ion batteries (LIBs). The effect of the potential range (i.e., 0.01–3.0 V and 0.4–3.0 V vs. Li+/Li) and of the binder on the material’s performance is investigated in 1 M LiPF6 in EC/DMC vs. Li. Ex situ X-ray photoelectron spectroscopy (XPS) and ex situ X-ray absorption spectroscopy (XAS) reveal a conversion reaction mechanism during Li+ insertion into the NiAl LDH material. X-ray diffraction (XRD) and XPS have been combined with the electrochemical study to understand the effect of different cutoff potentials on the Li-ion storage mechanism. This work highlights the possibility of the direct application of NiAl LDH materials as negative electrodes for LIBs.


Author(s):  
Motaz G. Fayed ◽  
Sayed Y. Attia ◽  
Yosry F. Barakat ◽  
E.E. El-Shereafy ◽  
M.M. Rashad ◽  
...  

2011 ◽  
Vol 196 (11) ◽  
pp. 5133-5137 ◽  
Author(s):  
Sang-Jun Park ◽  
Young-Jun Kim ◽  
Hyukjae Lee

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