A multifunctional microporous anionic metal–organic framework for column-chromatographic dye separation and selective detection and adsorption of Cr3+

2015 ◽  
Vol 3 (46) ◽  
pp. 23426-23434 ◽  
Author(s):  
Shu-Ran Zhang ◽  
Jing Li ◽  
Dong-Ying Du ◽  
Jun-Sheng Qin ◽  
Shun-Li Li ◽  
...  

An anionic MOFNENU-505exhibits selective adsorption toward cationic dyes and has been exploited for selectively sensing and adsorbing Cr3+for the first time.

CrystEngComm ◽  
2019 ◽  
Vol 21 (7) ◽  
pp. 1159-1167 ◽  
Author(s):  
Wei Gao ◽  
Feng Liu ◽  
Chang-Wei Pan ◽  
Xiu-Mei Zhang ◽  
Jie-Ping Liu ◽  
...  

A multifunctional anionic metal–organic framework was successfully synthesized using a new pyridyl–tricarboxylate ligand. It could be applied as a luminescent sensor for Fe3+ ions and TNP and it showed selective adsorption of cationic dyes.


2016 ◽  
Vol 362 ◽  
pp. 517-524 ◽  
Author(s):  
Xiaoxia Liu ◽  
Wenpeng Gong ◽  
Jing Luo ◽  
Chentao Zou ◽  
Yun Yang ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (34) ◽  
pp. 28165-28170 ◽  
Author(s):  
Xiang Shen ◽  
Bing Yan

An anionic metal–organic framework, [HDMA]2[Zn2(BDC)3(DMA)]·6DMF is modified by lanthanides and they exhibit selective adsorption ability to cationic dyes. RhB@1 has a rapidest response and realizes sensing acetone and aniline.


ACS Omega ◽  
2020 ◽  
Vol 5 (23) ◽  
pp. 13595-13600 ◽  
Author(s):  
Xiaochun Xie ◽  
Xiajuan Huang ◽  
Wenxin Lin ◽  
Yufeng Chen ◽  
Xiurui Lang ◽  
...  

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.


2021 ◽  
Author(s):  
Sudip Kumar Mondal ◽  
Partha Mahata ◽  
Pooja Daga ◽  
Sourav Sarkar ◽  
Prakash Majee ◽  
...  

A new metal-organic framework (MOF) showed excellent recognition ability towards five toxic oxo-anions viz. arsenate (HAsO42-), phosphate (PO43-), permanganate (MnO4-), chromate (CrO42-) and dichromate (Cr2O72-) in aqueous medium upon irradiation...


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