A novel solid-state electrolyte based on a crown ether lithium salt complex

2015 ◽  
Vol 3 (41) ◽  
pp. 20541-20546 ◽  
Author(s):  
Minda Gao ◽  
Yun Wang ◽  
Qinghua Yi ◽  
Ying Su ◽  
Pengfei Sun ◽  
...  

A novel solid-state electrolyte based on a crown ether lithium salt complex [Li∈12-C-4][I] has been designed, synthesized and characterized.

Nano Energy ◽  
2021 ◽  
pp. 105972
Author(s):  
Zizheng Tong ◽  
Shu-Bo Wang ◽  
Mu-Huai Fang ◽  
Yen-Ting Lin ◽  
Kun Ta Tsai ◽  
...  

2021 ◽  
pp. 2100707
Author(s):  
Sina Stegmaier ◽  
Roland Schierholz ◽  
Ivan Povstugar ◽  
Juri Barthel ◽  
Simon P. Rittmeyer ◽  
...  

2021 ◽  
pp. 1639-1648
Author(s):  
Yu-Ting Chen ◽  
Marc Duquesnoy ◽  
Darren H. S. Tan ◽  
Jean-Marie Doux ◽  
Hedi Yang ◽  
...  

2021 ◽  
Vol 492 ◽  
pp. 229661
Author(s):  
Haitian Zhang ◽  
Hui Wu ◽  
Li Wang ◽  
Hong Xu ◽  
Xiangming He

Author(s):  
Jingfeng Zheng ◽  
Hong Fang ◽  
Longlong Fan ◽  
Yang Ren ◽  
Puru Jena ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1206
Author(s):  
Xuansen Fang ◽  
Yaolong He ◽  
Xiaomin Fan ◽  
Dan Zhang ◽  
Hongjiu Hu

The prediction of electrochemical performance is the basis for long-term service of all-solid-state-battery (ASSB) regarding the time-aging of solid polymer electrolytes. To get insight into the influence mechanism of electrolyte aging on cell fading, we have established a continuum model for quantitatively analyzing the capacity evolution of the lithium battery during the time-aging process. The simulations have unveiled the phenomenon of electrolyte-aging-induced capacity degradation. The effects of discharge rate, operating temperature, and lithium-salt concentration in the electrolyte, as well as the electrolyte thickness, have also been explored in detail. The results have shown that capacity loss of ASSB is controlled by the decrease in the contact area of the electrolyte/electrode interface at the initial aging stage and is subsequently dominated by the mobilities of lithium-ion across the aging electrolyte. Moreover, reducing the discharge rate or increasing the operating temperature can weaken this cell deterioration. Besides, the thinner electrolyte film with acceptable lithium salt content benefits the durability of the ASSB. It has also been found that the negative effect of the aging electrolytes can be relieved if the electrolyte conductivity is kept being above a critical value under the storage and using conditions.


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