Synthesis of a 3D hierarchical structure of γ-AlO(OH)/Mg–Al-LDH/C and its performance in organic dyes and antibiotics adsorption

2015 ◽  
Vol 3 (42) ◽  
pp. 21106-21115 ◽  
Author(s):  
Jia Li ◽  
Ning Zhang ◽  
Dickon H. L. Ng

We demonstrated an efficient route to synthesize a novel 3D hierarchically porous superstructure composed of edge-to-face stacks of Mg–Al-layered double hydroxide nanosheets, directionally arranged γ-AlO(OH) nanowires and amorphous carbon by a facile biotemplate method.

2021 ◽  
Author(s):  
Zihao Liu ◽  
Shifeng Li ◽  
Fangfang Wang ◽  
Mingxia Li ◽  
Yonghong Ni

FeNi-layered double hydroxide (LDH) is thought to be an excellent electrocatalyst for oxygen evolution reaction (OER), but it always shows extremely poor electrocatalytic activity toward hydrogen evolution reaction (HER) in...


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Garima Rathee ◽  
Amardeep Awasthi ◽  
Damini Sood ◽  
Ravi Tomar ◽  
Vartika Tomar ◽  
...  

Abstract It would be of great significance to introduce a new biocompatible Layered Double Hydroxide (LDH) for the efficient remediation of wastewater. Herein, we designed a facile, biocompatible and environmental friendly layered double hydroxide (LDH) of NiFeTi for the very first time by the hydrothermal route. The materialization of NiFeTi LDH was confirmed by FTIR, XRD and Raman studies. BET results revealed the high surface area (106 m2/g) and the morphological studies (FESEM and TEM) portrayed the sheets-like structure of NiFeTi nanoparticles. The material so obtained was employed as an efficient adsorbent for the removal of organic dyes from synthetic waste water. The dye removal study showed >96% efficiency for the removal of methyl orange, congo red, methyl blue and orange G, which revealed the superiority of material for decontamination of waste water. The maximum removal (90%) of dyes was attained within 2 min of initiation of the adsorption process which supported the ultrafast removal efficiency. This ultrafast removal efficiency was attributed to high surface area and large concentration of -OH and CO32− groups present in NiFeTi LDH. In addition, the reusability was also performed up to three cycles with 96, 90 and 88% efficiency for methyl orange. Furthermore, the biocompatibility test on MHS cell lines were also carried which revealed the non-toxic nature of NiFeTi LDH at lower concentration (100% cell viability at 15.6 μg/ml). Overall, we offer a facile surfactant free method for the synthesis of NiFeTi LDH which is efficient for decontamination of anionic dyes from water and also non-toxic.


CrystEngComm ◽  
2022 ◽  
Author(s):  
Meng Ya Yang ◽  
Rong Zhao ◽  
Yi Liu ◽  
Hua Lin

In this work, high efficient electrocatalyst Fe-Ni2P/N-GO with hierarchical structure was developed through phosphating NiFe-based layered double hydroxide (LDH) supported by N-doped graphene oxide (GO), which was assembled by the...


Chemosphere ◽  
2018 ◽  
Vol 204 ◽  
pp. 11-21 ◽  
Author(s):  
Xiufei Zhao ◽  
Chenggang Niu ◽  
Lei Zhang ◽  
Hai Guo ◽  
Xiaoju Wen ◽  
...  

2013 ◽  
Vol 37 (7) ◽  
pp. 2128 ◽  
Author(s):  
Qi Liu ◽  
Jing Yu ◽  
Xiaofei Zhang ◽  
Jun Wang ◽  
Zhanshuang Li ◽  
...  

2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Najma Memon ◽  
Urooj Kanwal ◽  
Abdullah Memon ◽  
Safia Sanam Memon ◽  
Saima Qayoom Memon

Decontamination of organic dyes from wastewater requires efficient and compatible materials that must be able to remove dyes with different charges at the same time. In this study, composites of layered double hydroxide (LDH) and hydrochar (HC) were prepared and tested for use as general-purpose sorbents for the simultaneous removal of cationic and anionic dyes (i.e., methylene blue (MB), methyl orange (MO), and reactive yellow (RY)). Characterization studies reveal that the surface functional groups on composites are –OH, NO3, M–O bonds. It was observed that crystallinity of LDH decreased with an increasing amount of HC. Preliminary experiments showed that the dyes (i.e., MB, MO, and RY) were well removed simultaneously onto the composite with HC (2.0 g HC/prepared composite). This composite was selected for more experiments, and the adsorption efficiency was optimized by the multivariate technique using the response surface methodology (RSM). Removal efficiency of 100% was obtained for all three dyes with an adsorption capacity of 243, 5.3, and 16.3 µmol g−1 for MB, MO, and RY, respectively. Elovich’s initial intake rates (α) were 4,272, 441, and 99.5 mg g−1 min−1 for RY, MB, and MO, respectively. Data fitted in various models suggested second-order multiplex kinetics, where the surface heterogeneity response was sorbate dependent.


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