Highly crystalline, small sized, monodisperse α-NiS nanocrystal ink as an efficient counter electrode for dye-sensitized solar cells

2015 ◽  
Vol 3 (31) ◽  
pp. 15905-15912 ◽  
Author(s):  
Xiuwen Wang ◽  
Buhe Batter ◽  
Ying Xie ◽  
Kai Pan ◽  
Yongping Liao ◽  
...  

α-NiS nanocrystals exhibit excellent catalytic activity for I3− reduction due to the strong interaction between I1 and α-NiS active sites.

RSC Advances ◽  
2017 ◽  
Vol 7 (82) ◽  
pp. 51958-51964 ◽  
Author(s):  
Manshu Han ◽  
Shuang Lu ◽  
Jiangang Ma ◽  
Haiyang Xu ◽  
Yinglin Wang ◽  
...  

Vertical Bi2Se3 flake arrays work as counter-electrode in DSSCs due to its high electrical conductivity and abundance of catalytic active sites.


Physics ◽  
2020 ◽  
Vol 2 (3) ◽  
pp. 412-424
Author(s):  
Chi-Ang Tseng ◽  
Chuan-Pei Lee

Dye-sensitized solar cells (DSSCs) have emerged as promising alternatives to traditional silicon-based solar cells due to their relatively high conversion efficiency, low cost, flexibility, and environmentally benign fabrication processes. In DSSCs, platinum (Pt)-based materials used as the counter electrode (CE) exhibit the superior catalytic ability toward the reduction reaction of triiodide ions, which are attributed to their excellent catalytic activity and high electrical conductivity. However, Pt-based materials with high cost and limited supply hinder them from mass production. Developing highly active and stable CE materials without noble metals has been a persistent challenge for the practical application in DSSCs. Recently, a number of earth-abundant catalysts, especially carbon-based materials, display high activity, low cost, and good stability that render them attractive candidates to replace Pt in DSSCs. Herein, we will briefly review recent progress on carbon-based electrocatalysts as CEs in DSSC applications. The strategies of improving the catalytic activity of carbon-based materials such as structural engineering and/or heteroatom doping will be introduced. The active sites toward the reduction reaction of triiodide ions summarized from experimental results or theoretical calculation will also be discussed. Finally, the futuristic prospects and challenges of carbon-based electrocatalysts as CEs in DSSCs will be briefly mentioned.


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