Facile template-free preparation of hierarchical TiO2 hollow microspheres assembled by nanocrystals and their superior cycling performance as anode materials for lithium-ion batteries

2015 ◽  
Vol 3 (20) ◽  
pp. 10829-10836 ◽  
Author(s):  
Qinghua Tian ◽  
Yang Tian ◽  
Zhengxi Zhang ◽  
Chuansheng Qiao ◽  
Li Yang ◽  
...  

Uniformly distributed hierarchical anatase TiO2 hollow microspheres assembled by nanocrystals prepared via a facile template-free strategy exhibit an excellent cycling performance as the anode material for lithium-ion batteries.

CrystEngComm ◽  
2021 ◽  
Author(s):  
Jinxuan Wei ◽  
Senyang Xu ◽  
Zhaolin Tan ◽  
Linrui Hou ◽  
Changzhou Yuan

Spinel ZnMn2O4 with high theoretical lithium storage capacity and appropriate oxidation potential has been regarded as a promising anode material for lithium-ion batteries (LIBs). However, its practical application is always...


RSC Advances ◽  
2016 ◽  
Vol 6 (19) ◽  
pp. 15492-15500 ◽  
Author(s):  
Zhanyu Li ◽  
Jianling Li ◽  
Yuguang Zhao ◽  
Kai Yang ◽  
Fei Gao ◽  
...  

Sm doping has a great impact on discharge capacity, rate capability and cycling performance of LTO anode materials for lithium-ion batteries.


2020 ◽  
Vol 44 (33) ◽  
pp. 14278-14285 ◽  
Author(s):  
Hongqiang Wang ◽  
Yajun Ding ◽  
Jiaying Nong ◽  
Qichang Pan ◽  
Zhian Qiu ◽  
...  

A 2D Si@GC nanosheet composite is synthesized through a facile ball-milling method using NaCl as a bifunctional template, which can achieve a high reversible capacity and long-term cycling performance when evaluated as an anode material for LIBs.


2015 ◽  
Vol 44 (21) ◽  
pp. 9909-9914 ◽  
Author(s):  
Hailong Fei ◽  
Xin Liu ◽  
Zhiwei Li ◽  
Wenjing Feng

Manganese 3,5-pyridinedicarboxylate as an anode material for Li-ion batteries showed good cycling stability.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4348
Author(s):  
Chi Zhang ◽  
Zheng Wang ◽  
Yu Cui ◽  
Xuyao Niu ◽  
Mei Chen ◽  
...  

The volume expansion during Li ion insertion/extraction remains an obstacle for the application of Sn-based anode in lithium ion-batteries. Herein, the nanoporous (np) Cu6Sn5 alloy and Cu6Sn5/Sn composite were applied as a lithium-ion battery anode. The as-dealloyed np-Cu6Sn5 has an ultrafine ligament size of 40 nm and a high BET-specific area of 15.9 m2 g−1. The anode shows an initial discharge capacity as high as 1200 mA h g−1, and it remains a capacity of higher than 600 mA h g−1 for the initial five cycles at 0.1 A g−1. After 100 cycles, the anode maintains a stable capacity higher than 200 mA h g−1 for at least 350 cycles, with outstanding Coulombic efficiency. The ex situ XRD patterns reveal the reverse phase transformation between Cu6Sn5 and Li2CuSn. The Cu6Sn5/Sn composite presents a similar cycling performance with a slightly inferior rate performance compared to np-Cu6Sn5. The study demonstrates that dealloyed nanoporous Cu6Sn5 alloy could be a promising candidate for lithium-ion batteries.


2015 ◽  
Vol 3 (7) ◽  
pp. 3962-3967 ◽  
Author(s):  
Xiaolei Wang ◽  
Ge Li ◽  
Fathy M. Hassan ◽  
Matthew Li ◽  
Kun Feng ◽  
...  

High-performance robust CNT–graphene–Si composites are designed as anode materials with enhanced rate capability and excellent cycling stability for lithium-ion batteries. Such an improvement is mainly attributed to the robust sponge-like architecture, which holds great promise in future practical applications.


2015 ◽  
Vol 26 (12) ◽  
pp. 9535-9545 ◽  
Author(s):  
Wanli Zhang ◽  
Xianhua Hou ◽  
Zanrui Lin ◽  
Lingmin Yao ◽  
Xinyu Wang ◽  
...  

2013 ◽  
Vol 1540 ◽  
Author(s):  
Chia-Yi Lin ◽  
Chien-Te Hsieh ◽  
Ruey-Shin Juang

ABSTRACTAn efficient microwave-assisted polyol (MP) approach is report to prepare SnO2/graphene hybrid as an anode material for lithium ion batteries. The key factor to this MP method is to start with uniform graphene oxide (GO) suspension, in which a large amount of surface oxygenate groups ensures homogeneous distribution of the SnO2 nanoparticles onto the GO sheets under the microwave irradiation. The period for the microwave heating only takes 10 min. The obtained SnO2/graphene hybrid anode possesses a reversible capacity of 967 mAh g-1 at 0.1 C and a high Coulombic efficiency of 80.5% at the first cycle. The cycling performance and the rate capability of the hybrid anode are enhanced in comparison with that of the bare graphene anode. This improvement of electrochemical performance can be attributed to the formation of a 3-dimensional framework. Accordingly, this study provides an economical MP route for the fabrication of SnO2/graphene hybrid as an anode material for high-performance Li-ion batteries.


2020 ◽  
Vol 344 ◽  
pp. 115132 ◽  
Author(s):  
Wenhan Zhang ◽  
Jinjin Ai ◽  
Yike Lei ◽  
Yong Li ◽  
Chunyan Lai ◽  
...  

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