Gold–palladium bimetallic nanoalloy decorated ultrathin 2D TiO2 nanosheets as efficient photocatalysts with high hydrogen evolution activity

2015 ◽  
Vol 3 (16) ◽  
pp. 8659-8666 ◽  
Author(s):  
Yongji Xin ◽  
Linen Wu ◽  
Lei Ge ◽  
Changcun Han ◽  
Yujing Li ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Hydrogen Evolution ◽  
Synthesis Method ◽  
High Hydrogen ◽  
Tio2 Nanosheets

In this work, a novel AuPd bimetallic nanoalloy decorated ultrathin 2D titanium dioxide (TiO2) nanosheet with high H2 evolution activity was prepared via a facile in situ synthesis method.

In situ synthesis of novel Cu2CO3(OH)2 decorated 2D TiO2 nanosheets with efficient photocatalytic H2 evolution activity

2018 ◽  
Vol 47 (2) ◽  
pp. 348-356 ◽  
Author(s):  
Hao Xu ◽  
Dongsheng Dai ◽  
Songsong Li ◽  
Lei Ge ◽  
Yangqin Gao
Keyword(s):  
Hydrogen Evolution ◽  
Low Cost ◽  
In Situ Synthesis ◽  
H2 Evolution ◽  
Photocatalytic Hydrogen Evolution ◽  
Co Catalysts ◽  
Tio2 Nanosheets ◽  
Earth Abundant ◽  
Photocatalytic H2 Evolution

Semiconductor-based photocatalytic hydrogen evolution from water with earth-abundant and low cost co-catalysts has attracted much attention.

In-situ Platinum Plasmon Resonance Effect Prompt Titanium Dioxide Nanocube Photocatalytic Hydrogen Evolution

2019 ◽  
Vol 14 (4) ◽  
pp. 592-596 ◽  
Author(s):  
Shan Hu ◽  
Panzhe Qiao ◽  
Yunqi Fu ◽  
Fuxiang Li ◽  
Xudong Xiao ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Hydrogen Evolution ◽  
Plasmon Resonance ◽  
Resonance Effect ◽  
Photocatalytic Hydrogen Evolution

Preparation of Ti mesh supported N–S–C-tridoped TiO2 nanosheets to achieve high utilization of optical energy for photocatalytic degradation of norfloxacin

RSC Advances ◽  
2016 ◽  
Vol 6 (22) ◽  
pp. 17906-17912 ◽  
Author(s):  
Xiaoyun Zhang ◽  
Dong Li ◽  
Jiafeng Wan ◽  
Xiujuan Yu
Keyword(s):  
Hydrothermal Synthesis ◽  
Photocatalytic Degradation ◽  
Synthesis Method ◽  
Optical Energy ◽  
Tio2 Nanosheets ◽  
One Step ◽  
High Utilization ◽  
The One ◽  
Ti Mesh

The Ti mesh supported N–S–C-tridoped TiO2 nanosheet (N–S–C/TiO2/TMs) catalysts were successfully fabricated by the one-step in situ hydrothermal synthesis method, and then used for photocatalytic degradation of norfloxacin.

Structural Characteristics of Nanocomposites Fabricated With In-Situ Particle Synthesis Method

2010 ◽  
Author(s):  
Enis Tuncer ◽  
Isidor Sauers ◽  
D. Randy James ◽  
Georgios Polizos ◽  
Alvin R. Ellis ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Titanium Dioxide Nanoparticles ◽  
Structural Characteristics ◽  
National Laboratory ◽  
Synthesis Method ◽  
Electrical Insulation ◽  
Particle Synthesis ◽  
Oak Ridge ◽  
Electrical Insulation Materials

In this article we discuss fabrication of nanocomposites using an in-situ particle synthesis method. The nanocomposites discussed were prepared with solution based chemistry using a particle precursor mixture, which produces the nanoparticles. The nanocomposites presented were synthesized with titanium dioxide nanoparticles. The efforts of Oak Ridge National Laboratory to deliver better electrical insulation materials using nanotechnology are presented.

A solvent-switched in situ confinement approach for immobilizing highly-active ultrafine palladium nanoparticles: boosting catalytic hydrogen evolution

2018 ◽  
Vol 6 (14) ◽  
pp. 5544-5549 ◽  
Author(s):  
Qi-Long Zhu ◽  
Fu-Zhan Song ◽  
Qiu-Ju Wang ◽  
Nobuko Tsumori ◽  
Yuichiro Himeda ◽  
...  
Keyword(s):  
Metal Nanoparticles ◽  
Hydrogen Evolution ◽  
Palladium Nanoparticles ◽  
High Hydrogen ◽  
Highly Active ◽  
Catalytic Hydrogen ◽  
Catalytic Hydrogen Evolution ◽  
Clean Metal

A solvent-switched in situ confinement approach has been developed to synthesize highly active nanocatalysts with ultrafine and clean metal nanoparticles encapsulated within carbon nanopores, over which record-high hydrogen evolution has been achieved under heterogeneous conditions.

Promoting Hydrogen Evolution of g-C3N4 Based Photocatalyst by Indium and Phosphorus Co-doping

2021 ◽  
Author(s):  
Xiao-Hang Yang ◽  
Chi Cao ◽  
Zilong Guo ◽  
Xiaoyu Zhang ◽  
Yaxin Wang ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Post Treatment ◽  
Experimental Results ◽  
Indium Chloride ◽  
Co Doping ◽  
In Situ Copolymerization ◽  
Co Doped

Indium and phosphorus co-doped g-C3N4 photocatalyst (In,P-g-C3N4) was prepared by K2HPO4 post-treatment of indium doped g-C3N4 photocatalyst (In-g-C3N4) derived from in-situ copolymerization of dicyandiamide and indium chloride. The experimental results...

scholarly journals A cross-dehydrogenative C(sp3)−H heteroarylation via photo-induced catalytic chlorine radical generation

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Chia-Yu Huang ◽  
Jianbin Li ◽  
Chao-Jun Li
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Evolution ◽  
Alkyl Radical ◽  
Cobalt Catalyst ◽  
Alkylation Reaction ◽  
Hydrogen Atom Abstraction ◽  
Dehydrogenative Coupling ◽  
Radical Generation ◽  
Limited Scope

AbstractHydrogen atom abstraction (HAT) from C(sp3)–H bonds of naturally abundant alkanes for alkyl radical generation represents a promising yet underexplored strategy in the alkylation reaction designs since involving stoichiometric oxidants, excessive alkane loading, and limited scope are common drawbacks. Here we report a photo-induced and chemical oxidant-free cross-dehydrogenative coupling (CDC) between alkanes and heteroarenes using catalytic chloride and cobalt catalyst. Couplings of strong C(sp3)–H bond-containing substrates and complex heteroarenes, have been achieved with satisfactory yields. This dual catalytic platform features the in situ engendered chlorine radical for alkyl radical generation and exploits the cobaloxime catalyst to enable the hydrogen evolution for catalytic turnover. The practical value of this protocol was demonstrated by the gram-scale synthesis of alkylated heteroarene with merely 3 equiv. alkane loading.

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