Porous TiNb2O7 nanofibers decorated with conductive Ti1−xNbxN bumps as a high power anode material for Li-ion batteries

2015 ◽  
Vol 3 (16) ◽  
pp. 8590-8596 ◽  
Author(s):  
Hyunjung Park ◽  
Taeseup Song ◽  
Ungyu Paik

Porous TiNb2O7 nanofibers with metal nitride bumps show ultra-fast rate capability even at 100 C.

2017 ◽  
Vol 5 (15) ◽  
pp. 6958-6965 ◽  
Author(s):  
Hyunjung Park ◽  
Dong Hyeok Shin ◽  
Taeseup Song ◽  
Won Il Park ◽  
Ungyu Paik

TiNb2O7 nanotubes with a hierarchical porous structure show ultra-fast rate capability at an extremely high rate of 50C.


Author(s):  
Haichang Zhang ◽  
Rui Zhang ◽  
Xingjiang Liu ◽  
Fei Ding ◽  
Chunsheng Shi ◽  
...  

High cost, complex synthesis routes and low yield are pressing challenges hindering the practical application of organic battery materials. Herein, copper(II) phthalocyanine (CuPc), one of the most frequently used blue...


Nano Energy ◽  
2017 ◽  
Vol 39 ◽  
pp. 346-354 ◽  
Author(s):  
Hongbin Wang ◽  
Runwei Wang ◽  
Lijia Liu ◽  
Shang Jiang ◽  
Ling Ni ◽  
...  

2016 ◽  
Vol 319 ◽  
pp. 104-110 ◽  
Author(s):  
Youzhong Dong ◽  
Yanming Zhao ◽  
He Duan ◽  
Preetam Singh ◽  
Quan Kuang ◽  
...  

2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Binitha Gangaja ◽  
Shantikumar Nair ◽  
Dhamodaran Santhanagopalan

AbstractMaterials with high-power charge–discharge capabilities are of interest to overcome the power limitations of conventional Li-ion batteries. In this study, a unique solvothermal synthesis of Li4Ti5O12 nanoparticles is proposed by using an off-stoichiometric precursor ratio. A Li-deficient off-stoichiometry leads to the coexistence of phase-separated crystalline nanoparticles of Li4Ti5O12 and TiO2 exhibiting reasonable high-rate performances. However, after the solvothermal process, an extended aging of the hydrolyzed solution leads to the formation of a Li4Ti5O12 nanoplate-like structure with a self-assembled disordered surface layer without crystalline TiO2. The Li4Ti5O12 nanoplates with the disordered surface layer deliver ultrahigh-rate performances for both charging and discharging in the range of 50–300C and reversible capacities of 156 and 113 mAh g−1 at these two rates, respectively. Furthermore, the electrode exhibits an ultrahigh-charging-rate capability up to 1200C (60 mAh g−1; discharge limited to 100C). Unlike previously reported high-rate half cells, we demonstrate a high-power Li-ion battery by coupling Li4Ti5O12 with a high-rate LiMn2O4 cathode. The full cell exhibits ultrafast charging/discharging for 140 and 12 s while retaining 97 and 66% of the anode theoretical capacity, respectively. Room- (25 °C), low- (− 10 °C), and high- (55 °C) temperature cycling data show the wide temperature operation range of the cell at a high rate of 100C.


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