scholarly journals Electro-oxidation of ethylene glycol and glycerol at palladium-decorated FeCo@Fe core–shell nanocatalysts for alkaline direct alcohol fuel cells: functionalized MWCNT supports and impact on product selectivity

2015 ◽  
Vol 3 (13) ◽  
pp. 7145-7156 ◽  
Author(s):  
Omobosede O. Fashedemi ◽  
Hamish A. Miller ◽  
Andrea Marchionni ◽  
Francesco Vizza ◽  
Kenneth I. Ozoemena

FeCo@Fe@Pd nanocatalyst exhibits excellent selectivity towards the oxidation of EG and glycerol in ADAFCs.

ChemSusChem ◽  
2013 ◽  
Vol 6 (3) ◽  
pp. 390-390 ◽  
Author(s):  
Andrea Marchionni ◽  
Manuela Bevilacqua ◽  
Claudio Bianchini ◽  
Yan-Xin Chen ◽  
Jonathan Filippi ◽  
...  

2020 ◽  
Vol 22 (31) ◽  
pp. 17646-17658
Author(s):  
Raquel C. Bezerra ◽  
Paulo C. D. Mendes ◽  
Raimundo R. Passos ◽  
Juarez L. F. Da Silva

Ethylene glycol (EG) has been considered as a promising alcohol for direct alcohol fuel cells. In this study, we develop an atomistic understanding of its interaction with doped transition-metal surfaces.


2006 ◽  
Vol 4 (2) ◽  
pp. 203-209 ◽  
Author(s):  
Shuqin Song ◽  
Vasiliki Maragou ◽  
Panagiotis Tsiakaras

Direct alcohol fuel cells (DAFCs) have been attracting more and more attention and interest during the last decade due to their simplicity, the easy handle and the high power density of the liquid alcohol fuels. However, along with DAFCs’ development several problems related to their performance optimizations have arisen that are well established and researches are already in progress for their solutions. These problems are responsible for the short lifetime and low cell performance and can be summarized as follows: (a) low alcohol electro-oxidation kinetics, (b) alcohol crossover, and (c) electrode delamination. This article briefly reviews DAFCs’ state of the art, the pertinent work done for the localization and quantification of the above-mentioned problems and the work aiming at the identification and use of novel materials which could catalyze the rate-determining step for the DAFCs’ development and further commercialization. Furthermore, taking into account that fuel choice is still a disputed issue, the alcohols suitable as potential fuels for DAFCs are also summarized and compared.


2016 ◽  
Vol 8 (20) ◽  
pp. 12859-12870 ◽  
Author(s):  
Vinod Kumar Puthiyapura ◽  
Dan J. L. Brett ◽  
Andrea E. Russell ◽  
Wen-Feng Lin ◽  
Christopher Hardacre

ChemSusChem ◽  
2013 ◽  
Vol 6 (3) ◽  
pp. 518-528 ◽  
Author(s):  
Andrea Marchionni ◽  
Manuela Bevilacqua ◽  
Claudio Bianchini ◽  
Yan-Xin Chen ◽  
Jonathan Filippi ◽  
...  

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