When block copolymer self-assembly in hierarchically ordered honeycomb films depicts the breath figure process

Soft Matter ◽  
2016 ◽  
Vol 12 (3) ◽  
pp. 790-797 ◽  
Author(s):  
Pierre Escalé ◽  
Maud Save ◽  
Laurent Billon ◽  
Janne Ruokolainen ◽  
Laurent Rubatat
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Film Formation ◽  
Detailed Observation ◽  
Breath Figure

A detailed observation of the block copolymer self-assembly, kinetically trapped during the breath figure process, and used as an imprint to elucidate the complex honeycomb film formation.

Hierarchically porous bio-inspired films prepared by combining “breath figure” templating and selectively degradable block copolymer directed self-assembly

2016 ◽  
Vol 52 (61) ◽  
pp. 9562-9565 ◽  
Author(s):  
Arthur Bertrand ◽  
Antoine Bousquet ◽  
Christine Lartigau-Dagron ◽  
Laurent Billon
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Bottom Up ◽  
Hierarchically Porous ◽  
Breath Figure

Hierarchically porous bio-inspired honeycomb films prepared by combining the breath figure bottom-up process and selectively degradable block copolymer directed self-assembly.

CO2-Driven reversible wettability in a reactive hierarchically patterned bio-inspired honeycomb film

2019 ◽  
Vol 10 (27) ◽  
pp. 3751-3757 ◽  
Author(s):  
Pierre Marcasuzaa ◽  
Hongyao Yin ◽  
Yujun Feng ◽  
Laurent Billon
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Surface Wettability ◽  
Breath Figure

A triple structured honeycomb film is fabricated through block copolymer directed self-assembly in “Breath Figure” templating as a clickable patterned platform to enhance its reversible surface wettability between hydrophobicity and hydrophilicity upon a biological CO2 trigger.

Hierarchically organized honeycomb films through block copolymer directed self-assembly in “breath figure” templating and soft microwave-triggered annealing

Soft Matter ◽  
2018 ◽  
Vol 14 (23) ◽  
pp. 4874-4880 ◽  
Author(s):  
Nicolas Benoot ◽  
Pierre Marcasuzaa ◽  
Laurence Pessoni ◽  
Sirikorn Chasvised ◽  
Stéphanie Reynaud ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Polymer Films ◽  
Self Assembly ◽  
Breath Figure

Hierarchical polymer films are elaborated from the combination of block copolymer nanophase segregation in “breath figure” templating and microwave-triggered annealing.

Reactive Nanopattern in a Triple Structured Bio-Inspired Honeycomb Film as a Clickable Platform

2018 ◽  
Author(s):  
Pierre Marcasuzaa ◽  
Samuel Pearson ◽  
Karell Bosson ◽  
Laurence Pessoni ◽  
Jean-Charles Dupin ◽  
...  
Keyword(s):  
Self Assembly ◽  
Double Porosity ◽  
Surface Groups ◽  
Specific Chemical ◽  
Site Specific ◽  
Surface Functionality ◽  
Wenzel State ◽  
Breath Figure ◽  
Responsive Surfaces ◽  
Secondary Population

A hierarchically structured platform was obtained from spontaneous self-assembly of a poly(styrene)-<i>b</i>-poly(vinylbenzylchloride) (PS-<i>b</i>-PVBC) block copolymer (BCP) during breath figure (BF) templating. The BF process using a water/ethanol atmosphere gave a unique double porosity in which hexagonally arranged micron-sized pores were encircled by a secondary population of smaller, nano-sized pores. A third level of structuration was simultaneously introduced between the pores by directed BCP self-assembly to form out-of-the-plane nano-cylinders, offering very rapid bottom-up access to a film with unprecedented triple structure which could be used as a reactive platform for introducing further surface functionality. The surface nano-domains of VBC were exploited as reactive nano-patterns for site-specific chemical functionalization by firstly substituting the exposed chlorine moiety with azide, then “clicking” an alkyne by copper (I) catalyzed azide-alkyne Huisgen cycloaddition (CuAAC). Successful chemical modification was verified by NMR spectroscopy, FTIR spectroscopy, and XPS, with retention of the micro- and nanostructuration confirmed by SEM and AFM respectively. Protonation of the cyclotriazole surface groups triggered a switch in macroscopic behavior from a Cassie-Baxter state to a Wenzel state, highlighting the possibility of producing responsive surfaces with hierarchical structure.

The Self-Assembly of an Amphiphilic Block Copolymer: A Dissipative Particle Dynamics Study

2005 ◽  
Vol 42 (3) ◽  
pp. 180-183 ◽  
Author(s):  
S. G. Schulz ◽  
U. Frieske ◽  
H. Kuhn ◽  
G. Schmid ◽  
F. Müller ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Dissipative Particle Dynamics ◽  
Particle Dynamics ◽  
The Self ◽  
Amphiphilic Block Copolymer

Nanoscratch-Directed Self-Assembly of Block Copolymer Thin Films

2021 ◽  
Vol 13 (4) ◽  
pp. 5772-5781
Author(s):  
Dong Hyup Kim ◽  
Ahram Suh ◽  
Geonhyeong Park ◽  
Dong Ki Yoon ◽  
So Youn Kim
Keyword(s):  
Thin Films ◽  
Block Copolymer ◽  
Self Assembly

Oxidation and ATP dual-responsive block copolymer containing tertiary sulfoniums: self-assembly, protein complexation and triggered release

2021 ◽  
Author(s):  
Yanfen Jiang ◽  
Shuqi Dong ◽  
Guoyang Qin ◽  
Li Liu ◽  
Hanying Zhao
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Phenylboronic Acid ◽  
Cationic Polymer ◽  
Release Profile ◽  
Triggered Release ◽  
Dual Responsive ◽  
Protein Complexation

Alkylation of thioether-containing block copolymer simultaneously incorporated sulfoniums and phenylboronic acid moieties. The co-assembly of this cationic polymer and protein generated micelles with an H2O2-and ATP-responsive release profile.

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