Compact polar moieties induce lipid–water systems to form discontinuous reverse micellar phase

Soft Matter ◽  
2015 ◽  
Vol 11 (27) ◽  
pp. 5417-5424 ◽  
Author(s):  
Manoj Kumar ◽  
Naganath G. Patil ◽  
Chandan Kumar Choudhury ◽  
Sudip Roy ◽  
Ashootosh V. Ambade ◽  
...  

Macromolecules with a compact architecture and, that strongly interact with the lipid headgroup trigger an unusual pathway to the formation of a discontinuous AB2 micellar morphology.

2000 ◽  
Vol 16 (6) ◽  
pp. 1071-1078 ◽  
Author(s):  
S. Jarudilokkul ◽  
E. Paulsen ◽  
D.C. Stuckey

2013 ◽  
Vol 15 (3) ◽  
pp. 930-939 ◽  
Author(s):  
Animesh Patra ◽  
Trung Quan Luong ◽  
Rajib Kumar Mitra ◽  
Martina Havenith

2006 ◽  
Vol 16 (4) ◽  
pp. 190-197 ◽  
Author(s):  
Luigi Coppola ◽  
Domenico Gabriele ◽  
Isabella Nicotera ◽  
Cesare Oliviero

Abstract This paper deals with a Magnetic Resonance micro-Imaging (MRI) analysis of asymptotic kinematics which is a condition adopted in some rheological characterisations. Asymptotic kinematics (for example the slow shearing) aim is to evaluate material properties at “equilibrium”, avoiding structural changes induced by external stimuli. Measured material functions in these mechanical conditions deal with the structure/morphology of materials and can be used to investigate the structure as a function of the state variables only, as temperature, pressure and composition. In this paper MRI experiments were performed to study some shear flow behaviours of surfactant wormy micelles made by lecithin/water and diluted in cyclohexane (reverse micellar phase L2). MRI was used as a non-invasive tool in order to follow the structural responses both during slow shearing and when the sample is stirred outside the linear behaviour range. Relations can be found between the typical NMR parameters, strictly related to the microstructure, and the rheological macroscopic parameters as zero-shear viscosity.


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