A giant polymer lattice in a polymer-stabilized blue phase liquid crystal

Soft Matter ◽  
2015 ◽  
Vol 11 (23) ◽  
pp. 4572-4575 ◽  
Author(s):  
H. Kikuchi ◽  
S. Izena ◽  
H. Higuchi ◽  
Y. Okumura ◽  
K. Higashiguchi

Ultra-small angle X-ray diffraction patterns of a polymer-stabilized blue phase liquid crystal and a possible three-dimensional giant polymer lattice with body-centered cubic O8− symmetry formed in it.

2012 ◽  
Vol 482-484 ◽  
pp. 855-858
Author(s):  
Ying Li

Chemical structure and liquid crystal behavior of mesogenic monomer(Trans, trans)-4-propyl-4’-vinyl- bicyclohexane(3HHV) with platelet texture of a blue phase and mesogenic monomer(Trans, trans)-4-propyl-4’-propenyl –bicyclohexane(4HHV) with cholesteric phase were studied. The chemical structure of mesogenic monomers were determined by Fourier transform infrared spectroscopy, and Hydrogen-nuclear magnetic resonance spectra. Liquid crystal behavior of mesogenic monomers were analyzed by polarizing optical microscopy and X-ray diffraction. Thermal properties of mesogenic monomers were researched by differential scanning calorimetry. The results were that: 3HHV showed the platelet texture of a blue phase was considerably different from single color texture of blue phase we always refer to, and assuredly belong to a new kind of blue phase liquid crystal. These two kinds of cyclohexane liquid crystal monomer also showed good thermal stability.


2021 ◽  
pp. 096739112199822
Author(s):  
Ahmed I Abou-Kandil ◽  
Gerhard Goldbeck

Studying the crystalline structure of uniaxially and biaxially drawn polyesters is of great importance due to their wide range of applications. In this study, we shed some light on the behaviour of PET and PEN under uniaxial stress using experimental and molecular modelling techniques. Comparing experiment with modelling provides insights into polymer crystallisation with extended chains. Experimental x-ray diffraction patterns are reproduced by means of models of chains sliding along the c-axis leading to some loss of three-dimensional order, i.e. moving away from the condition of perfect register of the fully extended chains in triclinic crystals of both PET and PEN. This will help us understand the mechanism of polymer crystallisation under uniaxial stress and the appearance of mesophases in some cases as discussed herein.


2018 ◽  
Vol 49 (1) ◽  
pp. 1758-1761
Author(s):  
Quanming Chen ◽  
Yan Li ◽  
Shuxin Liu ◽  
Pengcheng Zhou ◽  
Sida Li ◽  
...  

2012 ◽  
Vol 10 (2) ◽  
pp. 022301-22303 ◽  
Author(s):  
Feng Zhou Feng Zhou ◽  
Qionghua Wang Qionghua Wang ◽  
Di Wu Di Wu ◽  
Jianpeng Cui Jianpeng Cui

2015 ◽  
Vol 30 (4) ◽  
pp. 576-580 ◽  
Author(s):  
李伟欢 LI Wei-huan ◽  
孙骁扬 SUN Xiao-yang ◽  
李泳锐 LEE Yung-jui ◽  
罗长诚 LO Chang-cheng ◽  
连水池 Lien Alan ◽  
...  

2013 ◽  
Vol 44 (1) ◽  
pp. 182-183 ◽  
Author(s):  
Cheng-Yeh Tsai ◽  
Te-Jen Tseng ◽  
Lin-Yung Wang ◽  
Fang-Cheng Yu ◽  
Yi-Fen Lan ◽  
...  

1999 ◽  
Vol 32 (6) ◽  
pp. 1069-1083 ◽  
Author(s):  
J. A. Elliott ◽  
S. Hanna

A model-independent maximum-entropy method is presented which will produce a structural model from small-angle X-ray diffraction data of disordered systems using no other prior information. In this respect, it differs from conventional maximum-entropy methods which assume the form of scattering entitiesa priori. The method is demonstrated using a number of different simulated diffraction patterns, and applied to real data obtained from perfluorinated ionomer membranes, in particular Nafion™, and a liquid crystalline copolymer of 1,4-oxybenzoate and 2,6-oxynaphthoate (B–N).


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