scholarly journals Rapid oxidative hydrogen evolution from a family of square-planar nickel hydride complexes

2016 ◽  
Vol 7 (1) ◽  
pp. 117-127 ◽  
Author(s):  
Srinivasan Ramakrishnan ◽  
Sumit Chakraborty ◽  
William W. Brennessel ◽  
Christopher E. D. Chidsey ◽  
William D. Jones
Keyword(s):  
Hydrogen Evolution ◽  
Hydride Complexes ◽  
Nickel Hydride ◽  
Square Planar

One-electron oxidation in a family of square planar nickel hydride complexes leads to facile H2 evolution.

ChemInform Abstract: Reaction of Methane with Nickel Hydride Complexes Yielding Methyl Derivatives.

ChemInform ◽  
2010 ◽  
Vol 25 (33) ◽  
pp. no-no
Author(s):  
T. B. RUBTSOVA ◽  
N. V. KIRJAKOV ◽  
G. L. SOLOVEICHIK ◽  
A. E. SHILOV
Keyword(s):  
Hydride Complexes ◽  
Nickel Hydride ◽  
Methyl Derivatives

scholarly journals Light-promoted catalytic hydrogenation of olefins with nickel complexes: the formation of nickel hydrides from the reaction of Ni(I) complexes with hydrogen

1988 ◽  
Vol 66 (11) ◽  
pp. 2920-2927 ◽  
Author(s):  
Yuan L. Chow ◽  
Huali Li ◽  
Meng-Su Yang
Keyword(s):  
Double Bond ◽  
Hydride Complexes ◽  
Alkyl Complexes ◽  
Heterogeneous Catalytic ◽  
Nickel Hydride ◽  
Bicyclic System ◽  
Wide Range ◽  
Nickel Hydrides ◽  
Heterogeneous Catalytic Processes ◽  
Homogeneous Catalytic Process

The conditions pertaining to triplet excited state ketone-sensitized photoreduction of Ni(acac)2 under hydrogen were shown to serve as a method for light-promoted hydrogenation of olefins with clean chemospecificity. For example, the double bond in the bicyclic system was preferentially hydrogenated over the other double bond in dicyclopentadiene and in 5-methylenebicyclo-[2.2.1]heptene. This photohydrogenation could be run under a wide range of conditions and was apparently a homogeneous catalytic process; in a late stage of photohydrogenation, concurrence of heterogeneous catalytic processes was not ruled out. The Ni(I) complexes of tetrahydrofuran and olefins generated from the photoreduction of Ni(acac)2 were shown to react with hydrogen to give nickel hydride complexes. By analogy with the generally accepted reaction pattern, coordinated olefins in these nickel hydride complexes probably spontaneously undergo intramolecular addition to give Ni–alkyl complexes. It is suggested that these Ni–alkyl complexes are photoexcited to generate a vacant coordination site so that the reaction with hydrogen can proceed to give products and regenerate a nickel hydride catalyst.

Skeletal isomerization of dienes by nickel hydride complexes

1971 ◽  
Vol 12 (27) ◽  
pp. 2555-2558 ◽  
Author(s):  
L.W. Gosser ◽  
G.W. Parshall
Keyword(s):  
Skeletal Isomerization ◽  
Hydride Complexes ◽  
Nickel Hydride

Stable nickel hydride complexes

1970 ◽  
Vol 9 (2) ◽  
pp. 394-395 ◽  
Author(s):  
R. A. Schunn
Keyword(s):  
Hydride Complexes ◽  
Nickel Hydride

Copper catalysts for photo- and electro-catalytic hydrogen production

2021 ◽  
Author(s):  
Abdullah M. Abudayyeh ◽  
Olivier Schott ◽  
Humphrey L. C. Feltham ◽  
Garry S. Hanan ◽  
Sally Brooker
Keyword(s):  
Hydrogen Production ◽  
Hydrogen Evolution ◽  
Copper Complexes ◽  
Copper Catalysts ◽  
Trigonal Bipyramidal ◽  
Square Planar ◽  
Catalytic Hydrogen

Square planar 1, square pyramidal 2 and trigonal bipyramidal 3 copper complexes are poor catalysts for hydrogen evolution (HER) under photocatalytic conditions, whereas 1 is, or forms, a good and enduring electrocatalyst for HER, but 2 and 3 do not.

Synthesis and Hydride Transfer Reactions of Cobalt and Nickel Hydride Complexes to BX3Compounds

2011 ◽  
Vol 50 (23) ◽  
pp. 11914-11928 ◽  
Author(s):  
Michael T. Mock ◽  
Robert G. Potter ◽  
Molly J. O’Hagan ◽  
Donald M. Camaioni ◽  
William G. Dougherty ◽  
...  
Keyword(s):  
Hydride Transfer ◽  
Transfer Reactions ◽  
Hydride Complexes ◽  
Nickel Hydride ◽  
Hydride Transfer Reactions ◽  
Cobalt And Nickel

Synthesis of Surface-Analogue Square-Planar Tetranuclear Nickel Hydride Clusters and Bonding to μ4-NR, -O and -BH Ligands

2017 ◽  
Vol 57 (5) ◽  
pp. 2438-2446 ◽  
Author(s):  
Manar M. Shoshani ◽  
Robert Beck ◽  
Xiaoping Wang ◽  
Matthew J. McLaughlin ◽  
Samuel A. Johnson
Keyword(s):  
Nickel Hydride ◽  
Square Planar

Reaction of Methane with Nickel Hydride Complexes Yielding Methyl Derivatives

1993 ◽  
Vol 3 (3) ◽  
pp. 89 ◽  
Author(s):  
Tatiana B. Rubtsova ◽  
Nikolai V. Kirjakov ◽  
Grigorii L. Soloveichik ◽  
Alexander E. Shilov
Keyword(s):  
Hydride Complexes ◽  
Nickel Hydride ◽  
Methyl Derivatives

Nickel Hydride Complexes

2016 ◽  
Vol 116 (15) ◽  
pp. 8373-8426 ◽  
Author(s):  
Nathan A. Eberhardt ◽  
Hairong Guan
Keyword(s):  
Hydride Complexes ◽  
Nickel Hydride
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