scholarly journals A pendant proton shuttle on [Fe4N(CO)12]− alters product selectivity in formate vs. H2 production via the hydride [H–Fe4N(CO)12]−

2016 ◽  
Vol 7 (4) ◽  
pp. 2728-2735 ◽  
Author(s):  
Natalia D. Loewen ◽  
Emily J. Thompson ◽  
Michael Kagan ◽  
Carolina L. Banales ◽  
Thomas W. Myers ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
H2 Production ◽  
Product Selectivity ◽  
Second Coordination Sphere

A proton shuttle in the second coordination sphere of [Fe4N(CO)12]− promotes H2 evolution over formate formation from CO2.

Cobalt Complexes Containing Pendant Amines in the Second Coordination Sphere as Electrocatalysts for H2 Production

2014 ◽  
Vol 33 (20) ◽  
pp. 5820-5833 ◽  
Author(s):  
Ming Fang ◽  
Eric S. Wiedner ◽  
William G. Dougherty ◽  
W. Scott Kassel ◽  
Tianbiao Liu ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Cobalt Complexes ◽  
H2 Production ◽  
Second Coordination Sphere

scholarly journals Recent advances in metalloporphyrin-based catalyst design towards carbon dioxide reduction: from bio-inspired second coordination sphere modifications to hierarchical architectures

2020 ◽  
Vol 49 (8) ◽  
pp. 2381-2396 ◽  
Author(s):  
Philipp Gotico ◽  
Zakaria Halime ◽  
Ally Aukauloo
Keyword(s):  
Carbon Dioxide ◽  
Coordination Sphere ◽  
Three Dimensional ◽  
Carbon Dioxide Reduction ◽  
Catalyst Design ◽  
Recent Advances ◽  
Hierarchical Architectures ◽  
Second Coordination Sphere

The progress in CO2 reduction catalyst design was examined starting from simple metalloporphyrin structures and progressing to three-dimensional active architectures.

scholarly journals An amide-based second coordination sphere promotes the dimer pathway of Mn-catalyzed CO2-to-CO reduction at low overpotential

2021 ◽  
Vol 12 (13) ◽  
pp. 4779-4788
Author(s):  
Yong Yang ◽  
Mehmed Z. Ertem ◽  
Lele Duan
Keyword(s):  
Coordination Sphere ◽  
Bond Cleavage ◽  
Low Overpotential ◽  
Second Coordination Sphere ◽  
Co Reduction ◽  
Reduction Catalysts

The amide NH group decreases the overpotential of Mn-based CO2 reduction catalysts by promoting the dimer and protonation-first pathways in the presence of H2O and enhances the CO2 electroreduction activity by facilitating C–OH bond cleavage.

Macromolecular Engineering of the Outer Coordination Sphere of [2Fe-2S] Metallopolymers to Enhance Catalytic Activity for H2 Production

2018 ◽  
Vol 7 (11) ◽  
pp. 1383-1387 ◽  
Author(s):  
William P. Brezinski ◽  
Metin Karayilan ◽  
Kayla E. Clary ◽  
Keelee C. McCleary-Petersen ◽  
Liye Fu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Coordination Sphere ◽  
H2 Production ◽  
Outer Coordination Sphere

scholarly journals Selective Formation of an FeIV O or an FeIII OOH Intermediate From Iron(II) and H2 O2 : Controlled Heterolytic versus Homolytic Oxygen-Oxygen Bond Cleavage by the Second Coordination Sphere

2018 ◽  
Vol 131 (3) ◽  
pp. 864-868 ◽  
Author(s):  
Khaled Cheaib ◽  
M. Qadri E. Mubarak ◽  
Katell Sénéchal-David ◽  
Christian Herrero ◽  
Régis Guillot ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Bond Cleavage ◽  
Oxygen Oxygen ◽  
Second Coordination Sphere ◽  
Selective Formation ◽  
Oxygen Bond
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