scholarly journals Multistep energy and electron transfer processes in novel rotaxane donor–acceptor hybrids generating microsecond-lived charge separated states

2015 ◽  
Vol 6 (12) ◽  
pp. 7293-7304 ◽  
Author(s):  
Sabrina V. Kirner ◽  
Christian Henkel ◽  
Dirk M. Guldi ◽  
Jackson D. Megiatto Jr ◽  
David I. Schuster

A new set of [Cu(phen)2]+ based rotaxanes, featuring [60]-fullerene as an electron acceptor and a variety of electron donating moieties, namely zinc porphyrin (ZnP), zinc phthalocyanine (ZnPc) and ferrocene (Fc), has been synthesized and fully characterized.

2016 ◽  
Vol 18 (11) ◽  
pp. 7875-7887 ◽  
Author(s):  
K. J. Lee ◽  
J. H. Woo ◽  
E. Kim ◽  
Y. Xiao ◽  
X. Su ◽  
...  

The photophysical properties of novel donor–acceptor dyad and triad molecules show an intricate interplay between energy and electron transfer processes.


Nanoscale ◽  
2015 ◽  
Vol 7 (15) ◽  
pp. 6813-6826 ◽  
Author(s):  
Chandra B. KC ◽  
Gary N. Lim ◽  
Francis D'Souza

Charge stabilization as a result of electron transfer followed by a hole-shift mechanism is demonstrated in a supramolecular multi-modular donor–acceptor assembly.


2004 ◽  
Vol 08 (09) ◽  
pp. 1118-1128 ◽  
Author(s):  
Bhaskar G. Maiya

This article reviews recent developments that have taken place in research related to new porphyrin architectures and their host-guest chemistry, as described in a microsymposium bearing the same name held during the 3rd International Conference on Porphyrins and Phthalocyanines (ICPP-3). The usefulness of representative arrays, aggregates, donor-acceptor systems, and receptor motifs based on porphyrin architectures is highlighted as it applies to the fabrication of molecular devices, understanding the biomimetic electron transfer processes, and recognition of bioorganic substrates.


2007 ◽  
Vol 111 (5) ◽  
pp. 998-1006 ◽  
Author(s):  
Martin Regehly ◽  
Eugeny A. Ermilov ◽  
Matthias Helmreich ◽  
Andreas Hirsch ◽  
Norbert Jux ◽  
...  

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