scholarly journals Enantioselective reductive multicomponent coupling reactions between isatins and aldehydes

2015 ◽  
Vol 6 (11) ◽  
pp. 6086-6090 ◽  
Author(s):  
Matthew A. Horwitz ◽  
Naoya Tanaka ◽  
Takuya Yokosaka ◽  
Daisuke Uraguchi ◽  
Jeffrey S. Johnson ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Coupling Reactions ◽  
Reductive Coupling ◽  
Multicomponent Coupling Reactions ◽  
Multicomponent Coupling

A reductive coupling of two different carbonyls via a polar two-electron reaction mechanism was developed and the stereochemical outcome of this multicomponent process is precisely controlled by a chiral triaminoiminophosphorane.

Transition-metal-catalyzed multicomponent coupling reactions with imines and carbon monoxide

2013 ◽  
Vol 85 (2) ◽  
pp. 377-384 ◽  
Author(s):  
Jeffrey S. Quesnel ◽  
Bruce A. Arndtsen
Keyword(s):  
Transition Metal ◽  
Building Blocks ◽  
Coupling Reactions ◽  
Metal Catalysis ◽  
Heterocyclic Derivatives ◽  
One Step ◽  
Multicomponent Coupling Reactions ◽  
Metal Catalyzed ◽  
And Control ◽  
Multicomponent Coupling

Multicomponent coupling reactions provide a method to combine several substrates in a single reaction. When coupled with transition-metal catalysis, these reactions can be used to both activate and control the assembly of multiple simple building blocks directly into useful products. This account will describe our work in this area, with a focus on the use of palladium catalysis as a tool to couple imines and CO with other substrates into a range of heterocyclic derivatives in one-step reactions.

Second Generation Protocol for Multicomponent Coupling Reactions of Aldehydes, Amides and Dienophiles

2004 ◽  
Vol 346 (8) ◽  
pp. 970-978 ◽  
Author(s):  
Stefan Klaus ◽  
Sandra Hübner ◽  
Helfried Neumann ◽  
Dirk Strübing ◽  
Axel Jacobi von Wangelin ◽  
...  
Keyword(s):  
Second Generation ◽  
Coupling Reactions ◽  
Multicomponent Coupling Reactions ◽  
Multicomponent Coupling

An Easy and General Protocol for Multicomponent Coupling Reactions of Aldehydes, Amides, and Dienophiles.

ChemInform ◽  
2007 ◽  
Vol 38 (7) ◽  
Author(s):  
Dirk Struebing ◽  
Helfried Neumann ◽  
Axel Jacobi von Wangelin ◽  
Stefan Klaus ◽  
Sandra Huebner ◽  
...  
Keyword(s):  
Coupling Reactions ◽  
Multicomponent Coupling Reactions ◽  
Multicomponent Coupling

Metallaphotoredox Catalysis for Multicomponent Coupling Reactions

2021 ◽  
Author(s):  
Wen-Jing Xiao ◽  
Fu-Dong Lu ◽  
Gui-Feng He ◽  
Liang-Qiu Lu
Keyword(s):  
Transition Metal ◽  
Transition Metal Catalysis ◽  
Coupling Reactions ◽  
Complex Molecules ◽  
Metal Catalysis ◽  
Mild Conditions ◽  
Multicomponent Coupling Reactions ◽  
Multicomponent Coupling

The combination of photoredox and transition metal catalysis, which is termed metallaphotoredox catalysis, is a powerful platform for building complex molecules under mild conditions. In particular, metallaphotoredox-catalyzed multicomponent coupling reactions,...

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