scholarly journals Taming C60fullerene: tuning intramolecular photoinduced electron transfer process with subphthalocyanines

2015 ◽  
Vol 6 (7) ◽  
pp. 4141-4147 ◽  
Author(s):  
Marc Rudolf ◽  
Olga Trukhina ◽  
Josefina Perles ◽  
Lai Feng ◽  
Takeshi Akasaka ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electron Donor ◽  
Transfer Process ◽  
Photoinduced Electron Transfer ◽  
Electron Transfer Process ◽  
Donor Acceptor

Two subphthalocyanine–C60fullerene electron donor–acceptor conjugates have been prepared from electron deficient subphthalocyanines and C60, with evidence of an ultrafast oxidative electron transfer from C60to the subphthalocyanines.

scholarly journals Two-electron transfer stabilized by excited-state aromatization

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Jinseok Kim ◽  
Juwon Oh ◽  
Seongchul Park ◽  
Jose L. Zafra ◽  
Justin R. DeFrancisco ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Excited State ◽  
Excited States ◽  
Transfer Process ◽  
Comprehensive Understanding ◽  
Electron Transfer Process ◽  
Photoactive Materials ◽  
Donor Acceptor ◽  
Scientific Significance

Abstract The scientific significance of excited-state aromaticity concerns with the elucidation of processes and properties in the excited states. Here, we focus on TMTQ, an oligomer composed of a central 1,6-methano[10]annulene and 5-dicyanomethyl-thiophene peripheries (acceptor-donor-acceptor system), and investigate a two-electron transfer process dominantly stabilized by an aromatization in the low-energy lying excited state. Our spectroscopic measurements quantitatively observe the shift of two π-electrons between donor and acceptors. It is revealed that this two-electron transfer process accompanies the excited-state aromatization, producing a Baird aromatic 8π core annulene in TMTQ. Biradical character on each terminal dicyanomethylene group of TMTQ allows a pseudo triplet-like configuration on the 8π core annulene with multiexcitonic nature, which stabilizes the energetically unfavorable two-charge separated state by the formation of Baird aromatic core annulene. This finding provides a comprehensive understanding of the role of excited-state aromaticity and insight to designing functional photoactive materials.

Electron donor-acceptor quenching and photoinduced electron transfer for coumarin dyes

1984 ◽  
Vol 49 (15) ◽  
pp. 2705-2708 ◽  
Author(s):  
Guilford Jones ◽  
Susan F. Griffin ◽  
Chol Yoo Choi ◽  
William R. Bergmark
Keyword(s):  
Electron Transfer ◽  
Electron Donor ◽  
Photoinduced Electron Transfer ◽  
Donor Acceptor ◽  
Coumarin Dyes

Immobilization of a boronic receptor for fructose recognition: influence on the photoinduced electron transfer process

2003 ◽  
Vol 90 (1-3) ◽  
pp. 256-263 ◽  
Author(s):  
E.Vélez López ◽  
G.Pina Luis ◽  
J.L. Suárez-Rodrı́guez ◽  
I.A. Rivero ◽  
M.E. Dı́az-Garcı́a
Keyword(s):  
Electron Transfer ◽  
Transfer Process ◽  
Photoinduced Electron Transfer ◽  
Electron Transfer Process

Synthesis and Photoinduced Electron-Transfer Process of a Novel Triphenylamine-Substituted Polyfluorene–C60 Triad

2007 ◽  
Vol 13 (6) ◽  
pp. 1709-1714 ◽  
Author(s):  
Yu Chen ◽  
Mohamed E. El-Khouly ◽  
Xiao-Dong Zhuang ◽  
Nan He ◽  
Yasuyuki Araki ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Transfer Process ◽  
Photoinduced Electron Transfer ◽  
Electron Transfer Process

scholarly journals Tracing photoinduced electron transfer process in conjugated polymer/fullerene bulk heterojunctions in real time

2001 ◽  
Vol 340 (3-4) ◽  
pp. 232-236 ◽  
Author(s):  
Christoph J Brabec ◽  
Gerald Zerza ◽  
Giulio Cerullo ◽  
Sandro De Silvestri ◽  
Silvia Luzzati ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Real Time ◽  
Transfer Process ◽  
Conjugated Polymer ◽  
Photoinduced Electron Transfer ◽  
Bulk Heterojunctions ◽  
Electron Transfer Process
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