Shape-controlled synthesis of 3D copper nicotinate hollow microstructures and their catalytic properties

RSC Advances ◽  
2016 ◽  
Vol 6 (22) ◽  
pp. 18033-18039 ◽  
Author(s):  
Shanshan Fu ◽  
Qingdong Xia ◽  
Shuang Li ◽  
Guojuan Ren ◽  
Fang Chai ◽  
...  

View of the process of preparation and catalysis of Cu hollow microstructures.

2012 ◽  
Vol 1446 ◽  
Author(s):  
Gilles Berhault ◽  
Hafedh Kochkar ◽  
Abdelhamid Ghorbel

ABSTRACTShape-controlled Ag and Pd nanocrystals were synthesized using seed-mediated techniques using β-cyclodextrin (β-CD) as structuring agent. First, seeds were obtained by reacting Na2PdCl4 or AgNO3 with a strong reducing agent, NaBH4 in the presence of sodium citrate dihydrate acting as stabilizing agent. These seeds were then injected into a growth solution containing the same metallic precursor, ascorbic acid (as a weak reducing agent) and β-CD as structuring agent. TEM results emphasize a strong influence of the relative concentration of β-CD on the final morphology. In the case of silver, well-facetted nanocrystals were obtained with a progressive shift from kinetically to thermodynamically-controlled nanoobjects when increasing the β-CD/Ag molar ratio. On palladium, β-CD leads to the formation of dendrites (urchin-like) or multipods through controlled aggregation of primary particles. The use of β-CD does not interfere negatively with the catalytic properties of the Pd nanocrystals in the hydrogenation of cinnamaldehyde.


CrystEngComm ◽  
2015 ◽  
Vol 17 (38) ◽  
pp. 7406-7413 ◽  
Author(s):  
Ruiting Dong ◽  
Honglei Wang ◽  
Quan Zhang ◽  
Xuetang Xu ◽  
Fan Wang ◽  
...  

Nanoscale ◽  
2021 ◽  
Author(s):  
Tao Sun ◽  
Yiding Liu ◽  
Chunyu Zhou ◽  
Liang Zhang ◽  
Xun Kang ◽  
...  

Herein, we developed a novel strategy for the shape-controlled synthesis of fluorine-doped iron oxide nanostructures with superior r2 values through the introduction of fluoride ions as a morphology controlling agent...


Materials ◽  
2018 ◽  
Vol 11 (6) ◽  
pp. 891 ◽  
Author(s):  
Hyun-Jin Kim ◽  
Jun-Goo Shin ◽  
Choon-Sang Park ◽  
Dae Kum ◽  
Bhum Shin ◽  
...  

Author(s):  
Hongxia Guo ◽  
Mingye Li ◽  
Zhenping Qin ◽  
Fan Li ◽  
Xuehong Zhang ◽  
...  

2010 ◽  
Vol 10 (12) ◽  
pp. 5312-5318 ◽  
Author(s):  
Xiuli Wang ◽  
Zhaochi Feng ◽  
Dayong Fan ◽  
Fengtao Fan ◽  
Can Li

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