Adsorption of phosphate on surface of magnetic reed: characteristics, kinetic, isotherm, desorption, competitive and mechanistic studies

RSC Advances ◽  
2016 ◽  
Vol 6 (6) ◽  
pp. 5089-5099 ◽  
Author(s):  
Tiantian Wang ◽  
Xing Xu ◽  
Zhongfei Ren ◽  
Baoyu Gao ◽  
Hantao Wang
Keyword(s):  
Starting Material ◽  
Amine Functionalization ◽  
Mechanistic Studies ◽  
Co Precipitation

A magnetic biocomposite was prepared by Fe3O4in situ co-precipitation and amine functionalization processes by using virgin reed as starting material.

Removal of phosphate and chromium(vi) from liquids by an amine-crosslinked nano-Fe3O4 biosorbent derived from corn straw

RSC Advances ◽  
2016 ◽  
Vol 6 (53) ◽  
pp. 47237-47248 ◽  
Author(s):  
Hantao Wang ◽  
Xing Xu ◽  
Zhongfei Ren ◽  
Baoyu Gao
Keyword(s):  
Amine Functionalization ◽  
Corn Straw ◽  
Chromium Vi ◽  
Nano Fe3o4 ◽  
Co Precipitation

A magnetic biocomposite based bio-sorbent (corn straw) was prepared after in situ co-precipitation with Fe2+ and Fe3+ solutions and amine functionalization.

scholarly journals A Review on LDH-Smart Functionalization of Anodic Films of Mg Alloys

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 536
Author(s):  
Mosab Kaseem ◽  
Karna Ramachandraiah ◽  
Shakhawat Hossain ◽  
Burak Dikici
Keyword(s):  
Industrial Applications ◽  
Mg Alloys ◽  
Anodic Films ◽  
Electrolytic Oxidation ◽  
Recent Developments ◽  
Plasma Electrolytic ◽  
Co Precipitation ◽  
Corrosive Environments ◽  
Double Hydroxide

This review presents an overview of the recent developments in the synthesis of layered double hydroxide (LDH) on the anodized films of Mg alloys prepared by either conventional anodizing or plasma electrolytic oxidation (PEO) and the applications of the formed composite ceramics as smart chloride traps in corrosive environments. In this work, the main fabrication approaches including co-precipitation, in situ hydrothermal, and an anion exchange reaction are outlined. The unique structure of LDH nanocontainers enables them to intercalate several corrosion inhibitors and release them when required under the action of corrosion-relevant triggers. The influences of different variables, such as type of cations, the concentration of salts, pH, and temperature, immersion time during the formation of LDH/anodic film composites, on the electrochemical response are also highlighted. The correlation between the dissolution rate of PEO coating and the growth rate of the LDH film was discussed. The challenges and future development strategies of LDH/anodic films are also highlighted in terms of industrial applications of these materials.

scholarly journals Phase Transition and Coefficients of Thermal Expansion in Al2−xInxW3O12 (0.2 ≤ x ≤ 1)

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4021
Author(s):  
Andrés Esteban Cerón Cerón Cortés ◽  
Anja Dosen ◽  
Victoria L. Blair ◽  
Michel B. Johnson ◽  
Mary Anne White ◽  
...  
Keyword(s):  
Phase Transition ◽  
Thermal Expansion ◽  
Thermal Shock ◽  
Monoclinic Phase ◽  
Ceramic Materials ◽  
Precipitation Method ◽  
Scanning Calorimetry ◽  
Orthorhombic Crystal ◽  
Co Precipitation

Materials from theA2M3O12 family are known for their extensive chemical versatility while preserving the polyhedral-corner-shared orthorhombic crystal system, as well as for their consequent unusual thermal expansion, varying from negative and near-zero to slightly positive. The rarest are near-zero thermal expansion materials, which are of paramount importance in thermal shock resistance applications. Ceramic materials with chemistry Al2−xInxW3O12 (x = 0.2–1.0) were synthesized using a modified reverse-strike co-precipitation method and prepared into solid specimens using traditional ceramic sintering. The resulting materials were characterized by X-ray powder diffraction (ambient and in situ high temperatures), differential scanning calorimetry and dilatometry to delineate thermal expansion, phase transitions and crystal structures. It was found that the x = 0.2 composition had the lowest thermal expansion, 1.88 × 10−6 K−1, which was still higher than the end member Al2W3O12 for the chemical series. Furthermore, the AlInW3O12 was monoclinic phase at room temperature and transformed to the orthorhombic form at ca. 200 °C, in contrast with previous reports. Interestingly, the x = 0.2, x = 0.4 and x = 0.7 materials did not exhibit the expected orthorhombic-to-monoclinic phase transition as observed for the other compositions, and hence did not follow the expected Vegard-like relationship associated with the electronegativity rule. Overall, compositions within the Al2−xInxW3O12 family should not be considered candidates for high thermal shock applications that would require near-zero thermal expansion properties.

scholarly journals PCl3-mediated transesterification and aminolysis of tert-butyl esters via acid chloride formation

2021 ◽  
pp. 174751982098753
Author(s):  
Xiaofang Wu ◽  
Lei Zhou ◽  
Fangshao Li ◽  
Jing Xiao
Keyword(s):  
Acid Chloride ◽  
Bioactive Molecules ◽  
Mechanistic Studies ◽  
One Pot ◽  
Tert Butyl ◽  
Butyl Esters

A PCl3-mediated conversion of tert-butyl esters into esters and amides in one-pot under air is developed. This novel protocol is highlighted by the synthesis of skeletons of bioactive molecules and gram-scale reactions. Mechanistic studies revealed that this transformation involves the formation of an acid chloride in situ, which is followed by reactions with alcohols or amines to afford the desired products.

Studies on Adsorption Performance of Reactive Dye Remazol Navy RGB (RN-RGB) via Epoxide Functional Magnetic ?-Al2O3 Nanocomposite Particles

2017 ◽  
Vol 9 (4) ◽  
pp. 421-429
Author(s):  
S. S. Bristy ◽  
H. Ahmad
Keyword(s):  
Sol Gel ◽  
Reactive Dye ◽  
Al2o3 Nanoparticles ◽  
Silica Layer ◽  
Seeded Polymerization ◽  
Nanocomposite Particles ◽  
Adsorption Performance ◽  
Magnetite Fe3o4 ◽  
Co Precipitation

The nanocomposite particles named as ?-Al2O3/Fe3O4/SiO2/poly(glycidyl methacrylate) or ?-Al2O3/Fe3O4/SiO2/PGMA were prepared by multi-step process. At first, ?- Al2O3 nanoparticles were prepared by sol-gel method. Magnetite, Fe3O4, nanoparticles were then precipitated by in situ co-precipitation in presence of ?-Al2O3 particles, followed by incorporation of mesoporous silica layer using Stöber process. Finally, the surface of the ?-Al2O3/Fe3O4/SiO2 nanocomposite particles was modified by seeded polymerization of GMA using free radical polymerization. The surface modification, morphology and size distribution of the prepared nanocomposite particles were confirmed by FTIR, scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). The adsorption capacity of ?-Al2O3/Fe3O4/SiO2/PGMA nanocomposite particles was evaluated using remazol navy RGB (RN-RGB) as a model dye.

scholarly journals Mechanistic studies on lithium intercalation in a lithium-rich layered material using Li2RuO3epitaxial film electrodes and in situ surface X-ray analysis

2014 ◽  
Vol 2 (42) ◽  
pp. 17875-17882 ◽  
Author(s):  
Sou Taminato ◽  
Masaaki Hirayama ◽  
Kota Suzuki ◽  
KyungSu Kim ◽  
Yueming Zheng ◽  
...  
Keyword(s):  
Layered Material ◽  
Lithium Intercalation ◽  
Mechanistic Studies ◽  
X Ray

scholarly journals Determination of 137Cs in Sea Water Samples Using Gamma Spectrometry

2020 ◽  
Vol 13 ◽  
pp. 247
Author(s):  
N. Evaggeliou ◽  
Ch. Lykomitrou ◽  
A. Zafiropoulou
Keyword(s):  
Gamma Spectrometry ◽  
Comparative Evaluation ◽  
Sea Water ◽  
Germanium Detector ◽  
Advantages And Disadvantages ◽  
High Purity Germanium ◽  
Co Precipitation ◽  
Radioanalytical Procedures

In the present study a comparative evaluation of two methods for 137Cs determination (pretreatment for gamma spectrometry) is attempted. One of them is the conventional AMP (ammonium molybdophosphate, (ΝΗ4)3Ρ(Μo3O10)4) method (radiochemical treatment based on coprecipitation) and the other one is a method based on pre-concentration of cesium in situ by using the Mark III Centrifugal Pump. The pump, which is described analytically in the study, is composed of a mo­tor (pump), four cartridge housings (containing the scavengers), a flow meter and a pressure tube (containing the battery pack and the timer board). For justification, this method is compared with the AMP co-precipitation one. Following up the radioanalytical procedures, the gamma spectrometry system (relative efficiency of high purity germanium detector 90%) is also demonstrated, as conformed to mea­ suring obtained parameters. Finally, the advantages and disadvantages of these two methods are recorded and the application of each one is suggested.

scholarly journals THE REACTION BETWEEN 2,2-DIPHENYL-1-PICRYLHYDRAZYL FREE STABLE RADICAL AND N-BROMOSUCCINIMIDE

1998 ◽  
Vol 6 (7) ◽  
pp. 101-106
Author(s):  
Petre Ionita
Keyword(s):  
Nitro Group ◽  
Stable Radical ◽  
Starting Material ◽  
Secondary Product ◽  
Ipso Substitution

The reactions of 2,2-diphenyl-1-picrylhydrazyl (DPPH) or 2,2-diphenyl-1-picrylhidrazine (DPPH-H) with N-bromosuccinimide (NBS) were studied. Two main compounds Br-DPPH and (Br)2 DPPH were obtained, by bromination of the starting material in para-phenyl position, and also a secondary product, N02 DPPH. It was shown that the reactions of NBS with DPPH include a substitution at the picryl group of PPH with liberation in situ of N02 (ipso-substitution of a nitro group with bromine) and subsequently N02 is scavenged by DPPH with the foundation of N02 DPPH.

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