Fabrication of super tough poly(lactic acid)/ethylene-co-vinyl-acetate blends via a melt recirculation approach: static-short term mechanical and morphological interpretation

RSC Advances ◽  
2016 ◽  
Vol 6 (18) ◽  
pp. 14580-14588 ◽  
Author(s):  
Rajendra Kumar Singla ◽  
Saurindra N. Maiti ◽  
Anup K. Ghosh
Keyword(s):  
Lactic Acid ◽  
Impact Strength ◽  
Vinyl Acetate ◽  
Poly Lactic Acid ◽  
Short Term ◽  
Izod Impact Strength ◽  
Izod Impact

The notched Izod impact strength of PLA/EVA blends was enhanced significantly with improved toughness making blends super tough.

Effects of Poly(Methyl Methacrylate)-Encapsulated Nanosilica on Mechanical Properties of Poly(Lactic Acid)/Ethylene Vinyl Acetate Nanocomposites

2018 ◽  
Vol 773 ◽  
pp. 51-55
Author(s):  
Jasmine Pongkasem ◽  
Saowaroj Chuayjuljit ◽  
Phasawat Chaiwutthinan ◽  
Amnouy Larpkasemsuk ◽  
Anyaporn Boonmahitthisud
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Impact Strength ◽  
Methyl Methacrylate ◽  
Tensile Properties ◽  
Vinyl Acetate ◽  
Ethylene Vinyl Acetate ◽  
Poly Lactic Acid ◽  
Poly Methyl Methacrylate ◽  
The Impact

In this study, poly(lactic acid) (PLA) was melt mixed with three weight percentages (10–30wt%) of ethylene vinyl acetate copolymer (EVA) in an internal mixer, followed by a compression molding. According to a better combination of mechanical properties, the 90/10 (w/w) PLA/EVA was selected for preparing hybrid nanocomposites with three loadings (1, 3 and 5 parts per hundred of resin , phr) of poly(methyl methacrylate)-encapsulated nanosilica (PMMA-nSiO2). The nanolatex of PMMA-nSiO2 was synthesized via in situ differential microemulsion polymerization. The obtained PMMA-nSiO2 showed a core-shell morphology with nSiO2 as a core and PMMA as a shell, having an average diameter of 43.4nm. The influences of the EVA and PMMA-nSiO2 on the impact strength and the tensile properties of the PLA/EVA nanocomposites were studied and compared. It is found that the impact strength and the tensile properties of the 90/10 (w/w) PLA/EVA were improved with the appropriate amounts of the EVA and PMMA-nSiO2.

Mechanical, Thermal, and Morphological Properties of Thermoplastic Starch/Poly(lactic acid/Poly(butylene adipate-co-terephthalate) Blends

2014 ◽  
Vol 970 ◽  
pp. 312-316
Author(s):  
Sujaree Tachaphiboonsap ◽  
Kasama Jarukumjorn
Keyword(s):  
Lactic Acid ◽  
Impact Strength ◽  
Interfacial Adhesion ◽  
Tensile Modulus ◽  
Thermoplastic Starch ◽  
Morphological Properties ◽  
Poly Lactic Acid ◽  
Melt Blending ◽  
Elongation At Break ◽  
Blending Method

Thermoplastic starch (TPS)/poly (lactic acid) (PLA) blend and thermoplastic starch (TPS)/poly (lactic acid) (PLA)/poly (butylene adipate-co-terephthalate) (PBAT) blend were prepared by melt blending method. PLA grafted with maleic anhydride (PLA-g-MA) was used as a compatibilizer to improve the compatibility of the blends. As TPS was incorporated into PLA, elongation at break was increased while tensile strength, tensile modulus, and impact strength were decreased. Tensile properties and impact properties of TPS/PLA blend were improved with adding PLA-g-MA indicating the enhancement of interfacial adhesion between PLA and TPS. With increasing PBAT content, elongation at break and impact strength of TPS/PLA blends were improved. The addition of TPS decreased glass transition temperature (Tg), crystallization temperature (Tc), and melting temperature (Tm) of PLA. Tgand Tcof TPS/PLA blend were decreased by incorporating PLA-g-MA. However, the presence of PBAT reduced Tcof TPS/PLA blend. Thermal properties of TPS/PLA/PBAT blends did not change with increasing PBAT content. SEM micrographs revealed that the compatibilized TPS/PLA blends exhibited finer morphology when compared to the uncompatibilized TPS/PLA blend.

scholarly journals Impact Toughness and Ductility Enhancement of Biodegradable Poly(lactic acid)/Poly(ε-caprolactone) Blends via Addition of Glycidyl Methacrylate

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Wei Kit Chee ◽  
Nor Azowa Ibrahim ◽  
Norhazlin Zainuddin ◽  
Mohd Faizal Abd Rahman ◽  
Buong Woei Chieng
Keyword(s):  
Lactic Acid ◽  
Impact Strength ◽  
Glycidyl Methacrylate ◽  
Interfacial Adhesion ◽  
Tensile Modulus ◽  
Sem Analysis ◽  
Poly Lactic Acid ◽  
Biodegradable Poly ◽  
Interfacial Compatibility ◽  
The Impact

Poly(lactic acid) (PLA)/poly(ε-caprolactone) (PCL) blends were prepared via melt blending technique. Glycidyl methacrylate (GMA) was added as reactive compatibilizer to improve the interfacial adhesion between immiscible phases of PLA and PCL matrices. Tensile test revealed that optimum in elongation at break of approximately 327% achieved when GMA loading was up to 3wt%. Slight drop in tensile strength and tensile modulus at optimum ratio suggested that the blends were tuned to be deformable. Flexural studies showed slight drop in flexural strength and modulus when GMA wt% increases as a result of improved flexibility by finer dispersion of PCL in PLA matrix. Besides, incorporation of GMA in the blends remarkably improved the impact strength. Highest impact strength was achieved (160% compared to pure PLA/PCL blend) when GMA loading was up to 3 wt%. SEM analysis revealed improved interfacial adhesion between PLA/PCL blends in the presence of GMA. Finer dispersion and smooth surface of the specimens were noted as GMA loading increases, indicating that addition of GMA eventually improved the interfacial compatibility of the nonmiscible blend.

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