Carbon dioxide capture by amino-functionalized ionic liquids: DFT based theoretical analysis substantiated by FT-IR investigation

RSC Advances ◽  
2016 ◽  
Vol 6 (13) ◽  
pp. 10462-10470 ◽  
Author(s):  
Bobo Cao ◽  
Jiuyao Du ◽  
Shuangyue Liu ◽  
Xiao Zhu ◽  
Xuejun Sun ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Theoretical Analysis ◽  
Carbon Dioxide Capture ◽  
Experimental Studies ◽  
Ft Ir

Both computational and experimental studies show amino-functionalized ionic liquids, [aEMMIM][X] (X = F, Cl, Br, and I), can chemically capture CO2.

scholarly journals Carbon dioxide capture using water-imidazolium ionic liquids-amines ternary systems

2021 ◽  
Vol 105 ◽  
pp. 103210
Author(s):  
Mariusz Zalewski ◽  
Tomasz Krawczyk ◽  
Agnieszka Siewniak ◽  
Aleksander Sobolewski
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Carbon Dioxide Capture ◽  
Ternary Systems ◽  
Imidazolium Ionic Liquids

Carbon Dioxide Capture by Superbase-Derived Protic Ionic Liquids

2010 ◽  
Vol 122 (34) ◽  
pp. 6114-6117 ◽  
Author(s):  
Congmin Wang ◽  
Huimin Luo ◽  
De-en Jiang ◽  
Haoran Li ◽  
Sheng Dai
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Carbon Dioxide Capture ◽  
Protic Ionic Liquids

The study of bicyclic amidine-based ionic liquids as promising carbon dioxide capture agents

2020 ◽  
Vol 304 ◽  
pp. 112805 ◽  
Author(s):  
Hui Fu ◽  
Xinyu Wang ◽  
Haina Sang ◽  
Ruoyao Fan ◽  
Yufen Han ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Carbon Dioxide Capture

scholarly journals Ionic Liquids: Potential Materials for Carbon Dioxide Capture and Utilization

2019 ◽  
Vol 6 ◽  
Author(s):  
Shashi Kant Shukla ◽  
Santosh G. Khokarale ◽  
Thai Q. Bui ◽  
Jyri-Pekka T. Mikkola
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Carbon Dioxide Capture

Carbon Dioxide Capture by Superbase-Derived Protic Ionic Liquids

2010 ◽  
Vol 49 (34) ◽  
pp. 5978-5981 ◽  
Author(s):  
Congmin Wang ◽  
Huimin Luo ◽  
De-en Jiang ◽  
Haoran Li ◽  
Sheng Dai
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Carbon Dioxide Capture ◽  
Protic Ionic Liquids

Screening of conventional ionic liquids for carbon dioxide capture and separation

2016 ◽  
Vol 162 ◽  
pp. 1160-1170 ◽  
Author(s):  
Yingying Zhang ◽  
Xiaoyan Ji ◽  
Yujiao Xie ◽  
Xiaohua Lu
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Carbon Dioxide Capture

scholarly journals Synthesis and Comprehensive Study of Quaternary-Ammonium-Based Sorbents for Natural Gas Sweetening

Environments ◽  
2021 ◽  
Vol 8 (12) ◽  
pp. 134
Author(s):  
Maria E. Atlaskina ◽  
Artem A. Atlaskin ◽  
Olga V. Kazarina ◽  
Anton N. Petukhov ◽  
Dmitriy M. Zarubin ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Quaternary Ammonium ◽  
Physical Nature ◽  
Chemical Absorption ◽  
Solid Sorbents ◽  
Environmental Care ◽  
Carbon Dioxide Sorption ◽  
Ionic Compounds ◽  
Ft Ir

The present study provides a solvent-free organic synthesis of quaternary ammonium salts: bis(2-hydroxyethyl)dimethylammonium taurate ([BHEDMA][Tau]) and bis(2-hydroxyethyl)dimethylammonium acetate ([BHEDMA][OAc]). These ionic compounds are promising materials for carbon dioxide capture processes, as mono sorbents, supplemental components in the conventional process of chemical absorption, and in the combined membrane approach for improving sorption efficiency. The synthesized compounds were characterized by 1H NMR and FT-IR spectroscopies and elemental analysis. Afterward, the sorption properties of the compounds were evaluated using the inverse gas chromatography (IGC) method, and their thermodynamic parameters were calculated in the temperature range of 303.15–333.15 K. The enthalpy change (∆sH) was less than 80 kJ·mol−1, indicated by the physical nature of sorption and also proved by FT-IR. Henry’s law constant in regard to carbon dioxide at 303.15 K was equal to 4.76 MPa for [BHEDMA][Tau], being almost 2.5 lower than for [BHEDMA][OAc] (11.55 MPa). The calculated carbon dioxide sorption capacity for [BHEDMA][Tau] and [BHEDMA][OAc] amounted to 0.58 and 0.30 mmol·g−1, respectively. The obtained parameters are comparable with the known solid sorbents and ionic liquids used for CO2 capture. However, the synthesized compounds, combining the advantages of both alkanolamines and ionic liquids, contain no fluorine in their structure and thus match the principles of environmental care.

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