Modeling of CO2/CH4 gas mixture permeation and CO2 induced plasticization through an asymmetric cellulose acetate membrane

RSC Advances ◽  
2016 ◽  
Vol 6 (20) ◽  
pp. 16561-16567 ◽  
Author(s):  
M. Saberi ◽  
S. A. Hashemifard ◽  
Ali. A. Dadkhah

A mathematical model for permeation and diffusion of mixed gases in glassy polymeric membranes in the presence of plasticization was derived.

1984 ◽  
Vol 29 (2) ◽  
pp. 583-594 ◽  
Author(s):  
A. Tanioka ◽  
K. Ishikawa ◽  
A. Kakuta ◽  
M. Kuramoto ◽  
M. Ohno

2017 ◽  
Vol 528 ◽  
pp. 135-146 ◽  
Author(s):  
Carmen Rizzuto ◽  
Alessio Caravella ◽  
Adele Brunetti ◽  
Chi Hoon Park ◽  
Young Moo Lee ◽  
...  

2021 ◽  
Vol 55 (5-6) ◽  
pp. 697-704
Author(s):  
HANANE ABURIDEH ◽  
ZAHIA TIGRINE ◽  
DJAMILA ZIOUI ◽  
SARAH HOUT ◽  
DJILALI TASSALIT ◽  
...  

The main objective of this work has been to study the performance of membranes developed for treating purified wastewater. Polymeric membranes have been developed from solutions containing cellulose acetate (AC) and polysulfone (PSF), using N,N-dimethylformamide (DMF) as solvent and polyethylene glycol (PEG) as additive. The phase inversion method was chosen as a technique for producing the membrane films. The incorporation of PEG allowed us to study the effect of the additive on the morphological structure, and to predict the performance of the membranes formed. Examining the flux, permeability and selectivity of the membranes allowed studying the efficiency and performance of each membrane. The application results achieved in wastewater treatment at Chenoua/TIPAZA station were very satisfactory and in accordance with the standards required by WHO. The optimal performance, in terms of permeability and selectivity, was obtained for the MC membrane with the composition: PSF/PEG/AC of 25/12/63.


1981 ◽  
Vol 37 (1) ◽  
pp. T32-T38
Author(s):  
Takatoshi Kinoshita ◽  
Masatomi Sasaki ◽  
Akira Takizawa ◽  
Yoshiharu Tsujita

2013 ◽  
Vol 12 (8) ◽  
pp. 1583-1591 ◽  
Author(s):  
Eugenia Teodora Iacob Tudose Ioan Mamaliga ◽  
Ciprian Constantin Negoescu ◽  
Nicoleta Bunduc

1990 ◽  
Vol 55 (12) ◽  
pp. 2933-2939 ◽  
Author(s):  
Hans-Hartmut Schwarz ◽  
Vlastimil Kůdela ◽  
Klaus Richau

Ultrafiltration cellulose acetate membrane can be transformed by annealing into reverse osmosis membranes (RO type). Annealing brings about changes in structural properties of the membranes, accompanied by changes in their permeability behaviour and electrical properties. Correlations between structure parameters and electrochemical properties are shown for the temperature range 20-90 °C. Relations have been derived which explain the role played by the dc electrical conductivity in the characterization of rejection ability of the membranes in the reverse osmosis, i.e. rRO = (1 + exp (A-B))-1, where exp A and exp B are statistically significant correlation functions of electrical conductivity and salt permeation, or of electrical conductivity and water flux through the membrane, respectively.


2019 ◽  
Vol 97 ◽  
pp. 05023 ◽  
Author(s):  
Daler Sharipov ◽  
Sharofiddin Aynakulov ◽  
Otabek Khafizov

The paper deals with the development of mathematical model and numerical algorithms for solving the problem of transfer and diffusion of aerosol emissions in the atmospheric boundary layer. The model takes into account several significant parameters such as terrain relief, characteristics of underlying surface and weather-climatic factors. A series of numerical experiments were conducted based on the given model. The obtained results presented here show how these factors affect aerosol emissions spread in the atmosphere.


Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 286
Author(s):  
Roba M. Almuhtaseb ◽  
Ahmed Awadallah-F ◽  
Shaheen A. Al-Muhtaseb ◽  
Majeda Khraisheh

Polysulfone membranes exhibit resistance to high temperature with low manufacturing cost and high efficiency in the separation process. The composition of gases is an important step that estimates the efficiency of separation in membranes. As membrane types are currently becoming in demand for CO2/CH4 segregation, polysulfone will be an advantageous alternative to have in further studies. Therefore, research is undertaken in this study to evaluate two solvents: chloroform (CF) and tetrahydrofuran (THF). These solvents are tested for casting polymeric membranes from polysulfone (PSF) to separate every single component from a binary gas mixture of CO2/CH4. In addition, the effect of gas pressure was conducted from 1 to 10 bar on the behavior of the permeability and selectivity. The results refer to the fact that the maximum permeability of CO2 and CH4 for THF is 62.32 and 2.06 barrer at 1 and 2 bars, respectively. Further, the maximum permeability of CF is 57.59 and 2.12 barrer at 1 and 2 bars, respectively. The outcome selectivity values are 48 and 36 for THF and CF at 1 bar, accordingly. Furthermore, the study declares that with the increase in pressure, the permeability and selectivity values drop for CF and THF. The performance for polysulfone (PSF) membrane that is manufactured with THF is superior to that of CF relative to the Robeson upper bound. Therefore, through the results, it can be deduced that the solvent during in-situ synthesis has a significant influence on the gas separation of a binary mixture of CO2/CH4.


Chemosphere ◽  
2015 ◽  
Vol 136 ◽  
pp. 204-210 ◽  
Author(s):  
Hyeon-gyu Choi ◽  
Moon Son ◽  
SangHyeon Yoon ◽  
Evrim Celik ◽  
Seoktae Kang ◽  
...  

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