A facile one-pot dealloying strategy to synthesize monolithic asymmetry-patterned nanoporous copper ribbons with tunable microstructure and nanoporosity

RSC Advances ◽  
2016 ◽  
Vol 6 (4) ◽  
pp. 2662-2670 ◽  
Author(s):  
Wenbo Liu ◽  
Chenglai Xin ◽  
Long Chen ◽  
Jiazhen Yan ◽  
Ning Li ◽  
...  
Keyword(s):  
One Pot ◽  
Cu Alloy ◽  

In the present work, an effective and facile one-pot dealloying strategy has been developed to synthesize monolithic asymmetry-patterned nanoporous copper ribbons (AP-NPCRs) from melt-spun bi-phase Al 32 at% Cu alloy with trace α-Al.

Author(s):  
Sawsan Ibrahim ◽  
Alexandra Dworzak ◽  
Daniel Crespo ◽  
Frank Uwe Renner ◽  
Carsten Dosche ◽  
...  
Keyword(s):  

1999 ◽  
Vol 40 (8) ◽  
pp. 779-786 ◽  
Author(s):  
Yukichi Umakoshi ◽  
Wataru Fujitani
Keyword(s):  
Cu Alloy ◽  

2017 ◽  
Vol 12 (1) ◽  
Author(s):  
Jingyi Zhang ◽  
Anni Feng ◽  
Jie Bai ◽  
Zhibing Tan ◽  
Wenyao Shao ◽  
...  

2013 ◽  
Vol 06 (03) ◽  
pp. 1350033 ◽  
Author(s):  
GUIJING LI ◽  
YANYAN SONG ◽  
LINPING ZHANG ◽  
XIN WEI ◽  
XIAOPING SONG ◽  
...  

A novel and simple method has been developed to prepare the Cu-Si composite as anode material for lithium-ion batteries. Nanoporous Cu-Si composite with pore sizes of 1~30 nm was prepared by dealloying the melt-spun Al-Cu-Si-Ce ribbons in a 5 wt.% HCl solution. Electrochemical tests revealed that the nanoporous Cu-Si electrodes exhibited highly reversible capacity of 2317 mAhg-1 and retained a capacity of 1030 mAhg-1 over 20 cycles. The excellent electrochemical performance is attributed to the unique porous structure of the Cu-Si composite. Our results demonstrate that this novel composite is a promising anode candidate for high-capacity rechargeable lithium-ion batteries.


2016 ◽  
Vol 8 (45) ◽  
pp. 30948-30955 ◽  
Author(s):  
Shu-He Han ◽  
Juan Bai ◽  
Hui-Min Liu ◽  
Jing-Hui Zeng ◽  
Jia-Xing Jiang ◽  
...  

2014 ◽  
Vol 636 ◽  
pp. 111-114
Author(s):  
Hua Wei Jiang ◽  
Jie Zhang ◽  
Mei Li ◽  
Hao Ran Geng ◽  
Min Zuo

We present a new Al-Cu-Mn system to fabricate nanoporous copper ribbons by dealloying. The microstructures of the nanoporous copper ribbons are characterized using X-ray diffraction, scanning electron microscopy and energy dispersive X-ray analysis. The results show that the compositions of the melt-spun Al-Cu-Mn alloys have an important effect on the dealloying process and microstructures of the nanoporous copper ribbons. The melt-spun Cu30Al40Mn30, Cu30Al35Mn35, Cu30Al30Mn40 and Cu30Al25Mn45 (at.%) alloys can completely form a bicontinuous interpenetrating ligament-channel structure. Compared with other alloys, the dealloying of Cu30Al40Mn30 alloys is more difficult. In addition, for Cu30Al35Mn35 and Cu30Al30Mn40 alloys, porous structures are relatively uniform. But for the Cu30Al25Mn45 alloys, porous structure is not uniform, occurring aggregation phenomenon.


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