One-step synthesis of an urchin-like sulfur/polyaniline nano-composite as a promising cathode material for high-capacity rechargeable lithium–sulfur batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (113) ◽  
pp. 92918-92922 ◽  
Author(s):  
Qi Lu ◽  
Hong Gao ◽  
Yujie Yao ◽  
Nianjiang Liu ◽  
Xianhong Wang ◽  
...  

Urchine-like sulfur/polyaniline nano-composite has been synthesized by a soft and facile approach. This novel composite could be directly utilized as the cathode material for Li–S battery and display high specific capacity and good cycle stability.

Membranes ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 483
Author(s):  
Jing Wang ◽  
Riwei Xu ◽  
Chengzhong Wang ◽  
Jinping Xiong

We report on the preparation and characterization of a novel lamellar polypyrrole using an attapulgite–sulfur composite as a hard template. Pretreated attapulgite was utilized as the carrier of elemental sulfur and the attapulgite–sulfur–polypyrrole (AT @400 °C–S–PPy) composite with 50 wt.% sulfur was obtained. The structure and morphology of the composite were characterized with infrared spectroscopy (IR), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). An AT @400 °C–S–PPy composite was further utilized as the cathode material for lithium–sulfur batteries. The first discharge specific capacity of this kind of battery reached 1175 mAh/g at a 0.1 C current rate and remained at 518 mAh/g after 100 cycles with capacity retention close to 44%. In the rate test, compared with the polypyrrole–sulfur (PPy–S) cathode material, the AT @400 °C–S–PPy cathode material showed lower capacity at a high current density, but it showed higher capacity when the current came back to a low current density, which was attributed to the “recycling” of pores and channels of attapulgite. Therefore, the lamellar composite with special pore structure has great value in improving the performance of lithium–sulfur batteries.


2021 ◽  
Author(s):  
Zhikang Wang ◽  
Guiqiang Cao ◽  
Da Bi ◽  
Tian-Xiong Tan ◽  
Qingxue Lai ◽  
...  

Lithium-Sulfur batteries have been regarded as the most promising electrochemical energy storage device in consideration of their satisfactory high specific capacity and high energy density. However, the inferior conversion efficiency...


RSC Advances ◽  
2015 ◽  
Vol 5 (114) ◽  
pp. 93926-93936 ◽  
Author(s):  
Xuebing Yang ◽  
Wen Zhu ◽  
Guobao Cao ◽  
Xudong Zhao

Sulfur is a promising cathode material for lithium–sulfur batteries as it possesses high theoretical specific capacity and low cost.


RSC Advances ◽  
2016 ◽  
Vol 6 (9) ◽  
pp. 7159-7171 ◽  
Author(s):  
Xuebing Yang ◽  
Wen Zhu ◽  
Guobao Cao ◽  
Xudong Zhao

Sulfur is a promising cathode material for lithium batteries as it possesses high theoretical specific capacity and low cost.


RSC Advances ◽  
2016 ◽  
Vol 6 (80) ◽  
pp. 76568-76574 ◽  
Author(s):  
Chunli Wang ◽  
Feifei Zhang ◽  
Xuxu Wang ◽  
Gang Huang ◽  
Dongxia Yuan ◽  
...  

One of the challenges for lithium–sulfur batteries is a rapid capacity fading owing to the insulating of sulfur and Li2S2/Li2S compounds, the dissolving and consequent shuttling of polysulfide.


Nanoscale ◽  
2019 ◽  
Vol 11 (33) ◽  
pp. 15418-15439 ◽  
Author(s):  
Fang Li ◽  
Quanhui Liu ◽  
Jiawen Hu ◽  
Yuezhan Feng ◽  
Pengbin He ◽  
...  

Li–S batteries are regarded as a promising candidate for next-generation energy storage systems due to their high specific capacity (1675 mA h g−1) and energy density (2600 W h kg−1) as well as the abundance, safety and low cost of S material.


2014 ◽  
Vol 2 (26) ◽  
pp. 10126-10130 ◽  
Author(s):  
Yuming Chen ◽  
Xiaoyan Li ◽  
Kyu-Sung Park ◽  
Jianhe Hong ◽  
Jie Song ◽  
...  

A novel carbon-sulfur nanoarchitecture with a high Brunauer–Emmett–Teller (BET) specific surface area of ~80 m2 g−1 and a total pore volume of ~0.2cm3 g−1 shows a high capacity of ~ 700 mAh g−1 at 1 C and 520 mAh g−1 at 5 C after 100 cycles, which makes it a superior cathode material for a rechargeable Li–S battery.


2016 ◽  
Vol 18 (1) ◽  
pp. 261-266 ◽  
Author(s):  
Junkai Wang ◽  
Kaiqiang Yue ◽  
Xiaodan Zhu ◽  
Kang L. Wang ◽  
Lianfeng Duan

C–S@PANI composite with conductive polymer spherical network was synthesized. Its 3D structure inhibits the dissolution and migration of polysulfides into electrolyte, delivering high specific capacity and a stable cycling performance.


RSC Advances ◽  
2014 ◽  
Vol 4 (54) ◽  
pp. 28636-28639 ◽  
Author(s):  
Wangliang Wu ◽  
Yi Zhao ◽  
Chuxin Wu ◽  
Lunhui Guan

A new SWCNHs–S composite exhibits excellent cycle stability with a high capacity of 693 mA h g−1 retained after 100 cycles at 1600 mA g−1.


Sign in / Sign up

Export Citation Format

Share Document