Size dependent catalytic activities of green synthesized gold nanoparticles and electro-catalytic oxidation of catechol on gold nanoparticles modified electrode

RSC Advances ◽  
2015 ◽  
Vol 5 (120) ◽  
pp. 99364-99377 ◽  
Author(s):  
Aftab Ahmad ◽  
Yun Wei ◽  
Fatima Syed ◽  
Muhammad Imran ◽  
Zia Ul Haq Khan ◽  
...  

A green and facile method for the synthesis of gold nanoparticles with efficient catalytic activity.

2015 ◽  
Vol 358 (1) ◽  
pp. 106-111 ◽  
Author(s):  
Anatoly Zinchenko ◽  
Shota Taniguchi ◽  
Shizuaki Murata

RSC Advances ◽  
2018 ◽  
Vol 8 (44) ◽  
pp. 24819-24826 ◽  
Author(s):  
N. K. R. Bogireddy ◽  
U. Pal ◽  
L. Martinez Gomez ◽  
V. Agarwal

Size dependent catalytic activity of AuNPs synthesized at room temperature from Coffea arabica seed extract.


2010 ◽  
Vol 132 (1) ◽  
pp. 138-146 ◽  
Author(s):  
Xiaochun Zhou ◽  
Weilin Xu ◽  
Guokun Liu ◽  
Debashis Panda ◽  
Peng Chen

2017 ◽  
Vol 4 (8) ◽  
pp. 1268-1272 ◽  
Author(s):  
Baozhan Zheng ◽  
Xiaoxia Liu ◽  
Yu Wu ◽  
Lei Yan ◽  
Juan Du ◽  
...  

Surfactant-free AuNPs/r-CDs, synthesized by a green and rapid strategy, exhibit greatly improved catalytic activity for 4-nitrophenol reduction.


2020 ◽  
Vol 5 (44) ◽  
pp. 13878-13887
Author(s):  
Golnoosh MirMoghtadaei ◽  
Manoj K. Ghosalya ◽  
Luca Artiglia ◽  
Jeroen A. Bokhoven ◽  
Cavus Falamaki

Author(s):  
Yonis Fornazier Filho ◽  
Ana Caroliny Carvalho da Cruz ◽  
Rolando Pedicini ◽  
José Ricardo Cezar Salgado ◽  
Priscilla Paiva Luz ◽  
...  

AbstractPhysical and electrochemical properties of Pd catalysts combined with Ru and Mo on carbon support were investigated. To this end, Pd, Pd1.3Ru1.0, Pd3.2Ru1.3Mo1.0 and Pd1.5Ru0.8Mo1.0 were synthesized on Carbon Vulcan XC72 support by the method of thermal decomposition of polymeric precursors and then physically and electrochemically characterized. The highest reaction yields are obtained for Pd3.2Ru1.3Mo1.0/C and Pd1.5Ru0.8Mo1.0/C and, as demonstrated by thermal analysis, they also show the smallest metal/carbon ratio compared the other catalysts. XRD (X-ray Diffraction) and Raman analyses show the presence of PdO and RuO2 for the Pd/C and the Pd1.3Ru1.0/C catalysts, respectively, a fact not observed for the Pd3.2Ru1.3 Mo1.0 /C and the Pd1.5Ru0.8Mo1.0/C catalysts. The catalytic activities were tested for the ethanol oxidation in alkaline medium. Cyclic voltammetry (CV) shows Pd1.3Ru1.0/C exhibiting the highest peak of current density, followed by Pd3.2Ru1.3Mo1.0/C, Pd1.5Ru0.8Mo1.0/C and Pd/C. From, chronoamperometry (CA), it is possible to observe the lowest rate of poisoning for the Pd1.3Ru1.0/C, followed by Pd3.2Ru1.3Mo1.0/C, Pd1.5Ru0.8Mo1.0/C and Pd/C. These results suggested that catalytic activity of the binary and the ternary catalysts are improved in comparison with Pd/C. The presence of RuO2 activated the bifunctional mechanism and improved the catalytic activity in the Pd1.3Ru1.0/C catalyst. The addition of Mo in the catalysts enhanced the catalytic activity by the intrinsic mechanism, suggesting a synergistic effect between metals. In summary, we suggest that it is possible to synthesize ternary PdRuMo catalysts supported on Carbon Vulcan XC72, resulting in materials with lower poisoning rates and lower costs than Pd/C. Graphic abstract


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