Bio-based green solvent for the catalyst free oxidation of arylboronic acids into phenols

RSC Advances ◽  
2015 ◽  
Vol 5 (108) ◽  
pp. 89133-89138 ◽  
Author(s):  
Surabhi Gupta ◽  
Priyanka Chaudhary ◽  
Lavudi Seva ◽  
Shahulhameed Sabiah ◽  
Jeyakumar Kandasamy
Keyword(s):  
Hydrogen Peroxide ◽  
Lactic Acid ◽  
Reaction Medium ◽  
Boronic Acids ◽  
Green Solvent ◽  
Aqueous Hydrogen Peroxide ◽  
Arylboronic Acids ◽  
Catalyst Free ◽  
Free Oxidation

A bio-based green solvent, lactic acid is found to be an efficient reaction medium for the catalyst free oxidation of aryl boronic acids into phenols with aqueous hydrogen peroxide.

ChemInform Abstract: Bio-Based Green Solvent for the Catalyst Free Oxidation of Arylboronic Acids into Phenols.

ChemInform ◽  
2016 ◽  
Vol 47 (10) ◽  
pp. no-no
Author(s):  
Surabhi Gupta ◽  
Priyanka Chaudhary ◽  
Lavudi Seva ◽  
Shahulhameed Sabiah ◽  
Jeyakumar Kandasamy
Keyword(s):  
Green Solvent ◽  
Arylboronic Acids ◽  
Catalyst Free ◽  
Free Oxidation

A facile catalyst-free synthesis of gem-dihydroperoxides with aqueous hydrogen peroxide

2010 ◽  
Vol 46 (10) ◽  
pp. 1772 ◽  
Author(s):  
Norihiro Tada ◽  
Lei Cui ◽  
Hiroaki Okubo ◽  
Tsuyoshi Miura ◽  
Akichika Itoh
Keyword(s):  
Hydrogen Peroxide ◽  
Aqueous Hydrogen Peroxide ◽  
Catalyst Free

Organic Solvent- and Halide-Free Oxidation of Alcohols with Aqueous Hydrogen Peroxide

1997 ◽  
Vol 119 (50) ◽  
pp. 12386-12387 ◽  
Author(s):  
Kazuhiko Sato ◽  
Masao Aoki ◽  
Junko Takagi ◽  
Ryoji Noyori
Keyword(s):  
Hydrogen Peroxide ◽  
Organic Solvent ◽  
Aqueous Hydrogen Peroxide ◽  
Oxidation Of Alcohols ◽  
Free Oxidation

ChemInform Abstract: A Facile Catalyst-Free Synthesis of gem-Dihydroperoxides with Aqueous Hydrogen Peroxide.

ChemInform ◽  
2010 ◽  
Vol 41 (28) ◽  
pp. no-no
Author(s):  
Norihiro Tada ◽  
Lei Cui ◽  
Hiroaki Okubo ◽  
Tsuyoshi Miura ◽  
Akichika Itoh
Keyword(s):  
Hydrogen Peroxide ◽  
Aqueous Hydrogen Peroxide ◽  
Catalyst Free

A chemoselective ipso-hydroxylation of arylboronic acids using urea-hydrogen peroxide under catalyst free condition

2016 ◽  
Vol 57 (23) ◽  
pp. 2506-2510 ◽  
Author(s):  
Surabhi Gupta ◽  
Priyanka Chaudhary ◽  
Vandana Srivastava ◽  
Jeyakumar Kandasamy
Keyword(s):  
Hydrogen Peroxide ◽  
Free Condition ◽  
Arylboronic Acids ◽  
Catalyst Free ◽  
Urea Hydrogen Peroxide

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

Sign in / Sign up

Export Citation Format

Share Document