New ion-imprinted polymer-functionalized mesoporous SBA-15 for selective separation and preconcentration of Cr(iii) ions: modeling and optimization

RSC Advances ◽  
2015 ◽  
Vol 5 (128) ◽  
pp. 105789-105799 ◽  
Author(s):  
Mahdi Jamshidi ◽  
Mehrorang Ghaedi ◽  
Kheibar Dashtian ◽  
Shaaker Hajati

A new Cr(iii) ion-imprinted polymer (Cr(iii)-IIP), prepared by functionalizing an SBA-15 support with dithizone (DZ) indicator, is promising and highly efficient for the separation and preconcentration of Cr(iii) ions from aqueous media.

Author(s):  
Tapan Kumar Biswas ◽  
Mashitah Mohd Yusoff ◽  
Mohd Sani Sarjadi ◽  
Sazmal Effendi Arshad ◽  
Baba Musta ◽  
...  

2011 ◽  
Vol 306-307 ◽  
pp. 705-708
Author(s):  
Qing Peng Liu ◽  
Hui Zhi Li ◽  
Hai Yan Zhuang ◽  
Mei Shan Pei

Neodymium ion imprinted polymers (IIP) were synthesized by formation of ternary complexes of neodymium ion with Vanillin Benzidine(VLB) and 4-vinylpyridine (VP) as chelating agent following copolymerizing with styrene as func­tional monomer and ethylene glycol dimethacrylate (EGDMA) as cross-linking monomer using 2,2´-azobisisobutyronitrile as initiator. Control polymers(CPs) were prepared under identical conditions without the use of neodymium imprint ion. The synthesized polymers were characterized by IR spectroscopy and elemental analyzer techniques. Of the several polymers synthesized, only the imprinted polymer formed with ternary complex of Nd3+–VLB–VP(1:1:2 IIP) showed quantitative enrichment of neodymium ion from aqueous solution.


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