Controllable growth of organic nanostructures from 0D to 1D with different optical properties

RSC Advances ◽  
2015 ◽  
Vol 5 (122) ◽  
pp. 100457-100463 ◽  
Author(s):  
Yusen Luo ◽  
Zheng Xue ◽  
Yongjun Li ◽  
Huibiao Liu ◽  
Wensheng Yang ◽  
...  

Controllable nano/microstructures from 0D to 1D were fabricated by adjusting the growth rate. The difference in symmetry between two molecules results in distinct self-assembly behaviours and different optical properties.

2003 ◽  
Vol 771 ◽  
Author(s):  
Pavel I. Lazarev ◽  
Michael V. Paukshto ◽  
Elena N. Sidorenko

AbstractWe report a new method of Thin Crystal Film deposition. In the present paper we describe the method of crystallization, structure, and optical properties of Bisbenzimidazo[2,1-a:1',2',b']anthra[2,1,9-def:6,5,10-d'e'f']-diisoquinoline-6,9-dion (mixture with cis-isomer) (abbreviated DBI PTCA) sulfonation product. The Thin Crystal Film has a thickness of 200-1000 nm, with anisotropic optical properties such as refraction and absorption indices. X-ray diffraction data evidences a lyotropic liquid crystalline state in liquid phase and crystalline state in solid film. Anisotropic optical properties of the film make it useful in optical devices, e.g. liquid crystal displays.


2020 ◽  
Vol 15 (1) ◽  
Author(s):  
Xiaowei Wang ◽  
Feng Liang ◽  
Degang Zhao ◽  
Zongshun Liu ◽  
Jianjun Zhu ◽  
...  

Abstract Three InGaN/GaN MQWs samples with varying GaN cap layer thickness were grown by metalorganic chemical vapor deposition (MOCVD) to investigate the optical properties. We found that a thicker cap layer is more effective in preventing the evaporation of the In composition in the InGaN quantum well layer. Furthermore, the quantum-confined Stark effect (QCSE) is enhanced with increasing the thickness of GaN cap layer. In addition, compared with the electroluminescence measurement results, we focus on the difference of localization states and defects in three samples induced by various cap thickness to explain the anomalies in room temperature photoluminescence measurements. We found that too thin GaN cap layer will exacerbates the inhomogeneity of localization states in InGaN QW layer, and too thick GaN cap layer will generate more defects in GaN cap layer.


1995 ◽  
Vol 22 (5) ◽  
pp. 843 ◽  
Author(s):  
YP Wang ◽  
RM Gifford

Kernel growth after anthesis is simulated as a function of the potential kernel growth rate, current photosynthate production and mobilisation of stored reserves. The potential growth rate of the kernel is simulated as two temperature-sensitive processes, cell production and cell growth. The difference between the potential and actual growth rates of the kernel depends on the carbon supply to the free space of the kernel endosperm, while the carbon supply is itself affected by the actual kernel growth rate. Sensitivity analysis showed that the growth rate of the grain per plant is most sensitive to the potential growth rate of the kernel and number of kernels per plant. This model is able to simulate the observed rates of grain growth and leaf senescence from anthesis to physiological maturity for wheat plants grown in two CO2 concentrations. The simulated temperature response of grain growth agrees well with the experimenal observations.


2015 ◽  
Vol 48 (3) ◽  
pp. 836-843 ◽  
Author(s):  
Oindrila Mondal ◽  
Manisha Pal ◽  
Ripandeep Singh ◽  
Debasis Sen ◽  
Subhasish Mazumder ◽  
...  

The effect of dopant size (ionic radius) on the crystal growth, structure and optical properties of nanocrystalline calcium titanate, CaTiO3(CTO), have been studied using small-angle neutron scattering. X-ray diffraction, along with high-resolution transmission electron microscopy, confirms the growth of pure nanocrystalline CTO. Rietveld analysis reveals that the difference of ionic radii between dopant and host ions induces strain within the lattice, which significantly affects the lattice parameters. The induced strain, due to the difference of ionic radii, causes the shrinkage of the optical band gap, which is manifested by the redshift of the absorbance band. Mesoscopic structural analysis using scattering techniques demonstrates that the ionic radius of the dopant influences the agglomeration behaviour and particle size. A high-resolution transmission electron microscopy study reconfirms the formation of pure highly crystalline CTO nanoparticles.


2019 ◽  
Vol 10 (18) ◽  
pp. 2316-2326 ◽  
Author(s):  
Vitalii Tkachenko ◽  
Camélia Matei Ghimbeu ◽  
Cyril Vaulot ◽  
Loïc Vidal ◽  
Julien Poly ◽  
...  

Diblock copolymer nanoparticles were prepared by photomediated polymerization-induced self-assembly (“photo-PISA”) in dispersion.


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