Highly sensitive and selective colorimetric detection of sulphide using Ag–Au nanoalloys: a DFT study

RSC Advances ◽  
2016 ◽  
Vol 6 (20) ◽  
pp. 16285-16291 ◽  
Author(s):  
Le Chang ◽  
Adrian Fisher ◽  
Zhiping Liu ◽  
Daojian Cheng
Keyword(s):  
High Selectivity ◽  
Colorimetric Detection ◽  
Dft Study ◽  
Highly Sensitive ◽  
Ag Cluster ◽  
Better Than

For the colorimetric detection of S, SH, cysteine, and H2S, the sensitivity of Ag–Au nanoalloy is better than pure Ag cluster, and both of them possess high selectivity for the detection of S.

A Three-Dimensional Tetraphenylethylene-Based Fluorescence Covalent Organic Framework for Molecular Recognition

2020 ◽  
Author(s):  
Junxia Ren ◽  
Yaozu Liu ◽  
Xin Zhu ◽  
Yangyang Pan ◽  
Yujie Wang ◽  
...  
Keyword(s):  
Molecular Recognition ◽  
Fluorescence Probe ◽  
Three Dimensional ◽  
Hazardous Substances ◽  
Covalent Organic Framework ◽  
Highly Sensitive ◽  
Volatile Organic ◽  
Polycyclic Aromatic ◽  
Better Than ◽  
Organic Framework

<p><a></a><a></a><a></a><a></a><a></a><a></a><a></a><a>The development of highly-sensitive recognition of </a><a></a><a></a><a></a><a></a><a>hazardous </a>chemicals, such as volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs), is of significant importance because of their widespread social concerns related to environment and human health. Here, we report a three-dimensional (3D) covalent organic framework (COF, termed JUC-555) bearing tetraphenylethylene (TPE) side chains as an aggregation-induced emission (AIE) fluorescence probe for sensitive molecular recognition.<a></a><a> </a>Due to the rotational restriction of TPE rotors in highly interpenetrated framework after inclusion of dimethylformamide (DMF), JUC-555 shows impressive AIE-based strong fluorescence. Meanwhile, owing to the large pore size (11.4 Å) and suitable intermolecular distance of aligned TPE (7.2 Å) in JUC-555, the obtained material demonstrates an excellent performance in the molecular recognition of hazardous chemicals, e.g., nitroaromatic explosives, PAHs, and even thiophene compounds, via a fluorescent quenching mechanism. The quenching constant (<i>K</i><sub>SV</sub>) is two orders of magnitude better than those of other fluorescence-based porous materials reported to date. This research thus opens 3D functionalized COFs as a promising identification tool for environmentally hazardous substances.</p>

scholarly journals Immobilization of Pseudomonas aeruginosa static biomass on eggshell powder for on-line preconcentration and determination of Cr (VI)

2020 ◽  
Vol 18 (1) ◽  
pp. 303-313 ◽  
Author(s):  
Aamir Rasheed ◽  
Tahseen Ghous ◽  
Sumaira Mumtaz ◽  
Muhammad Nadeem Zafar ◽  
Kalsoom Akhter ◽  
...  
Keyword(s):  
Pseudomonas Aeruginosa ◽  
Low Cost ◽  
Colorimetric Detection ◽  
Time Flow ◽  
Highly Sensitive ◽  
Glass Column ◽  
On Line ◽  
Preconcentration Time ◽  
Ultra Trace

AbstractIn the present work, a novel continuous flow system (CFS) is developed for the preconcentration and determination of Cr (VI) using Pseudomonas aeruginosa static biomass immobilized onto an effective and low-cost solid support of powdered eggshells. A mini glass column packed with the immobilized biosorbent is incorporated in a CFS for the preconcentration and determination of Cr (VI) from aqueous solutions. The method is based on preconcentration, washing and elution steps followed by colorimetric detection with 1,5-diphenyl carbazide in sulphuric acid. The effects of several variables such as pH, retention time, flow rate, eluent concentration and loaded volume are studied. Under optimal conditions, the CFS method has a linear range between 10 and 100 μg L-1 and a detection limit of 6.25 μg L-1 for the determination of Cr (VI). The sampling frequency is 10 samples per hour with a preconcentration time of 5 mins. Furthermore, after washing with a 0.1 M buffer (pH 3.0), the activity of the biosorbent is regenerated and remained comparable for more than 200 cycles. Scanning electron microscopy reveals a successful immobilization of biomass on eggshells powder and precipitation of Cr (VI) on the bacterial cell surface. The proposed method proves highly sensitive and could be suitable for the determination of Cr (VI) at an ultra-trace level.

An anthracene–quinoline based dual-mode fluorometric–colorimetric sensor for the detection of Fe3+ and its application in live cell imaging

2021 ◽  
Author(s):  
Tahereh Tehrani ◽  
Soraia Meghdadi ◽  
Zohreh Salarvand ◽  
Behnam Tavakoli ◽  
Kiamars Eskandari ◽  
...  
Keyword(s):  
Live Cell Imaging ◽  
Cell Imaging ◽  
Colorimetric Detection ◽  
Colorimetric Sensor ◽  
Live Cell ◽  
Dual Mode ◽  
Highly Sensitive

A highly sensitive anthracene–quinoline based dual-mode sensor has been synthesized and used for the fluorometric and colorimetric detection of Fe3+ and in live cell imaging.

An ultra-highly sensitive and selective self-enhanced AIECL sensor for public security early warning in a nuclear emergency via a co-reactive group poisoning mechanism

2021 ◽  
Author(s):  
Ziyu Wang ◽  
Meiyun Xu ◽  
Nan Zhang ◽  
Jian-Bin Pan ◽  
Xinqi Wu ◽  
...  
Keyword(s):  
Detection Limit ◽  
Early Warning ◽  
High Selectivity ◽  
Public Security ◽  
Reactive Group ◽  
Low Detection Limit ◽  
Highly Sensitive ◽  
Vapor Sensors ◽  
Nuclear Emergency

A mechanism of co-reactive group poisoning (CGP) was discovered for designing efficient I2 vapor sensors for early warning of a nuclear emergency, which give an ultra-low detection limit of 0.13 ppt as well as high selectivity.

scholarly journals Highly sensitive and selective colorimetric detection of dual metal ions (Hg2+ and Sn2+) in water: an eco-friendly approach

RSC Advances ◽  
2021 ◽  
Vol 11 (24) ◽  
pp. 14700-14709
Author(s):  
Rintumoni Paw ◽  
Moushumi Hazarika ◽  
Purna K. Boruah ◽  
Amlan Jyoti Kalita ◽  
Ankur K. Guha ◽  
...  
Keyword(s):  
Metal Ions ◽  
Ag Nanoparticles ◽  
Limit Of Detection ◽  
Colorimetric Detection ◽  
Garlic Extract ◽  
Selective Detection ◽  
Highly Sensitive ◽  
Dual Metal

Synthesis of Ag nanoparticles using Allin based garlic extract for highly sensitive and selective detection of metal ions Hg2+ and Sn2+ in water. The limit of detection (LoD) for Hg2+ and Sn2+ ions were found as 15.7 nM and 11.25 nM respectively.

scholarly journals Highly sensitive colorimetric detection of 17β-estradiol using split DNA aptamers immobilized on unmodified gold nanoparticles

2014 ◽  
Vol 4 (1) ◽  
Author(s):  
Jinchuan Liu ◽  
Wenhui Bai ◽  
Shucao Niu ◽  
Chao Zhu ◽  
Shuming Yang ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Colorimetric Detection ◽  
Dna Aptamers ◽  
Highly Sensitive ◽  
17Β Estradiol

A rapid and accurate method for screening T-2 toxin in food and feed using competitive AlphaLISA

2021 ◽  
Vol 368 (6) ◽  
Author(s):  
Liwen Zhang ◽  
Qingyu Lv ◽  
Yuling Zheng ◽  
Xuan Chen ◽  
Decong Kong ◽  
...  
Keyword(s):  
High Sensitivity ◽  
Accurate Method ◽  
Detection Methods ◽  
Cereal Crops ◽  
Detection Range ◽  
Highly Sensitive ◽  
Food And Feed ◽  
Good Repeatability ◽  
Feed Samples ◽  
Better Than

ABSTRACT T-2 is a common mycotoxin contaminating cereal crops. Chronic consumption of food contaminated with T-2 toxin can lead to death, so simple and accurate detection methods in food and feed are necessary. In this paper, we establish a highly sensitive and accurate method for detecting T-2 toxin using AlphaLISA. The system consists of acceptor beads labeled with T-2-bovine serum albumin (BSA), streptavidin-labeled donor beads and biotinylated T-2 antibodies. T-2 in the sample matrix competes with T-2-BSA for antibodies. Adding biotinylated antibodies to the test well followed by T-2 and T-2-BSA acceptor beads yielded a detection range of 0.03–500 ng/mL. The half-maximal inhibitory concentration was 2.28 ng/mL and the coefficient of variation was &lt;10%. In addition, this method had no cross-reaction with other related mycotoxins. This optimized method for extracting T-2 from food and feed samples achieved a recovery rate of approximately 90% in T-2 concentrations as low as 1 ng/mL, better than the performance of a commercial ELISA kit. This competitive AlphaLISA method offers high sensitivity, good specificity, good repeatability and simple operation for detecting T-2 toxin in food and feed.

Highly Sensitive Colorimetric Detection of a Variety of Analytes via the Tyndall Effect

2019 ◽  
Vol 91 (23) ◽  
pp. 15114-15122 ◽  
Author(s):  
Wencheng Xiao ◽  
Zihao Deng ◽  
Jinkun Huang ◽  
Ziheng Huang ◽  
Miaomiao Zhuang ◽  
...  
Keyword(s):  
Colorimetric Detection ◽  
Tyndall Effect ◽  
Highly Sensitive

scholarly journals A Simple and Highly Sensitive Colorimetric Detection Method for Gaseous Formaldehyde

2010 ◽  
Vol 132 (12) ◽  
pp. 4046-4047 ◽  
Author(s):  
Liang Feng ◽  
Christopher J. Musto ◽  
Kenneth S. Suslick
Keyword(s):  
Detection Method ◽  
Colorimetric Detection ◽  
Highly Sensitive ◽  
Gaseous Formaldehyde
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