Palladium complexes with 3-phenylpropylamine ligands: synthesis, structures, theoretical studies and application in the aerobic oxidation of alcohols as heterogeneous catalysts

RSC Advances ◽  
2015 ◽  
Vol 5 (124) ◽  
pp. 102424-102435 ◽  
Author(s):  
Kazem Karami ◽  
Nasrin Haghighat Naeini ◽  
Vaclav Eigner ◽  
Michal Dusek ◽  
Janusz Lipkowski ◽  
...  

Palladium complexes with 3-phenylpropylamine ligands were synthesized and characterized. Palladium nanoparticles were supported on cucurbit[6]uril and used as heterogeneous catalysts for the aerobic oxidation of alcohols to corresponding compounds.

ChemCatChem ◽  
2015 ◽  
Vol 7 (24) ◽  
pp. 4131-4136 ◽  
Author(s):  
Yong-Ming Lu ◽  
Hai-Zhou Zhu ◽  
Jian-Wei Liu ◽  
Shu-Hong Yu

RSC Advances ◽  
2016 ◽  
Vol 6 (108) ◽  
pp. 106769-106777 ◽  
Author(s):  
Esmail Vessally ◽  
Mostafa Ghasemisarabbadeih ◽  
Zeynab Ekhteyari ◽  
Rahim Hosseinzadeh-Khanmiri ◽  
Ebrahim Ghorbani-Kalhor ◽  
...  

In this manuscript, we demonstrate that functionalized magnetic silica nanoparticles are efficient and recyclable catalysts for the selective, aerobic oxidation of various primary and secondary alcohols.


Polymers ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 1344 ◽  
Author(s):  
Yuta Nabae ◽  
Masa-aki Kakimoto

Aromatic polymers such as poly(ether sulfone), poly(ether ketone), and polyimide have been widely used in industry due to their thermal, mechanical, and chemical stabilities. Although their application to catalysis has been limited, the introduction of a hyperbranched architecture to such aromatic polymers is effective in developing catalytic materials that combine the advantages of homogenous and heterogeneous catalysts. This review article overviews the recent progress on the design and synthesis of hyperbranched aromatic polymers. Several acid catalyzed reactions and the aerobic oxidation of alcohols have been demonstrated using hyperbranched aromatic polymers as catalysts. The advantage of hyperbranched polymers against linear polymers is also discussed.


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