Thermally stable polylactides by stereocomplex formation and conjugation of both terminals with bio-based cinnamic acid derivatives

RSC Advances ◽  
2015 ◽  
Vol 5 (111) ◽  
pp. 91423-91430 ◽  
Author(s):  
Hang Thi Tran ◽  
Hiroharu Ajiro ◽  
Mitsuru Akashi

A series of polylactide stereocomplexes with conjugation of both terminals showed high thermal stability and photoreactivity, and are useful as high performance polymers and photoreactive polymers based on natural products.

1995 ◽  
Vol 7 (2) ◽  
pp. 157-180 ◽  
Author(s):  
Marie-Florence Grenier-Loustalot ◽  
Vincent Denizot ◽  
Daniel Beziers

We have investigated the polymerization of polypropargylic butanedioldimeth-acrylate derivatives using electron and x-ray irradiation. The results obtained with the pure resin and carbon-fibre-based composites were compared in terms of kinetics, mechanisms and properties with those obtained by thermal polymerization. Data gathered using a panoply of solid state physicochemical techniques have shown that these polymers are good systems for obtaining composites having high thermal stability at temperatures higher than 350°C.


RSC Advances ◽  
2016 ◽  
Vol 6 (90) ◽  
pp. 87013-87020 ◽  
Author(s):  
Kaiju Luo ◽  
Yan Wang ◽  
Junrong Yu ◽  
Jing Zhu ◽  
Zuming Hu

Aromatic furanic polyamides with relatively high molecular weight were synthesized, and good thermal stability and mechanical properties were demonstrated.


RSC Advances ◽  
2015 ◽  
Vol 5 (39) ◽  
pp. 30472-30477 ◽  
Author(s):  
Fu-Wen Lin ◽  
Xiao-Ling Xu ◽  
Ling-Shu Wan ◽  
Jian Wu ◽  
Zhi-Kang Xu

Thermally stable films with ordered pores are fabricated from porphyrinated polyimides and they exhibit excellent property in HCl gas sensing.


2019 ◽  
Vol 45 (9) ◽  
pp. 11749-11755 ◽  
Author(s):  
Shangkai He ◽  
Biaolin Peng ◽  
Glenn J.T. Leighton ◽  
Christopher Shaw ◽  
Ningzhang Wang ◽  
...  

2019 ◽  
Vol 32 (6) ◽  
pp. 662-668
Author(s):  
Xiao-fang Guan ◽  
Cong Liao ◽  
Li Yang ◽  
Guan-jun Chang

The preparation of high-performance polymeric materials with both excellent overall mechanical properties and heat resistance remains a considerable challenge. Inspired by the delicate self-assembly processes in nature, a facile strategy is reported for the preparation of high-performance polymeric materials with enhanced mechanical strength and improved thermal stability. In this instance, we successfully constructed a cation- π cross-linked polyimide (Na-poly(aryl indole) imide (Na-PINI)) film with enhanced mechanical performance and heat resistance (∼490°C). This work presents an innovative design strategy for realizing robust polymeric materials with integrated strength and thermal stability; the cation- π interaction is demonstrated to be a new method that may achieve many useful properties for high-performance polymers.


2017 ◽  
Vol 30 (4) ◽  
pp. 475-479 ◽  
Author(s):  
Wenxuan Wei ◽  
Li Yang ◽  
Guanjun Chang

Indole-based poly(ether sulfone)s (PINESs), as novel high-performance polymers, have been obtained by the condensation polymerization of 4-hydroxyindole and hydroquinone with activated difluoro monomers via a catalyst-free nucleophilic substitution reaction. The structures of the polymers are characterized by means of Fourier transform infrared and proton nuclear magnetic resonance spectroscopy, and the results show good agreement with the proposed structures. Differential scanning calorimetry and thermogravimetric analysis measurements exhibit that polymers possess high glass transition temperature ( Tgs > 245°C) and good thermal stability with high decomposition temperatures ( Tds > 440°C). In addition, due to their special structure, PINESs are endowed with significantly strong photonic luminescence in N, N-dimethylformamide.


Alloy Digest ◽  
2013 ◽  
Vol 62 (5) ◽  

Abstract ToughMet 2 is a high performance, wrought, heat treatable, lead-free strip Cu-Ni alloy that imparts superior mechanical performance and high thermal stability to plain bearing applications. Parts are easily formed and they can be machined either before or after heat treatment. ToughMet alloys are a line of spinodal hardened Cu-Ni anti-galling alloys for bearings capable of performing with a variety of shafting materials and lubricants. The alloys combine a high lubricity with wear resistance in these severe loading conditions. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness and fatigue. It also includes information on corrosion resistance as well as forming and machining. Filing Code: Cu-724. Producer or source: Materion Brush Performance Alloys. Originally published September 2004, revised May 2013.


2021 ◽  
Author(s):  
Xiaota Cheng ◽  
Yang Si ◽  
Jianyong Yu ◽  
Bin Ding

Abstract Ceramic aerogels are attractive for many applications due to their ultralow density, high porosity, and multifunctionalities but are limited by the typical trade-off relationship between mechanical properties and thermal stability when used in extreme environments. In this work, we designed and synthesized a unique ceramic nanofibrous aerogels with three-dimensional (3D) interwoven crimped-nanofibre structures that endow the aerogels with superior mechanical performances and high thermal stability. These ceramic aerogels were synthesized by a direct and facile route, 3D reaction electrospinning. They displayed robust structural stability with structure-derived mechanical ultra-stretchability up to 100% tensile strain and superior restoring capacity up to 40% tensile strain, 95% bending strain and 60% compressive strain, high thermal stability from -196 to 1400°C, repeatable stretchability at working temperatures up to 1300 ℃, and a low thermal conductivity of 0.0228 W m−1 K−1 in air. This work should enable the innovative design of high-performance ceramic aerogels for various applications.


2000 ◽  
Vol 639 ◽  
Author(s):  
Jun Kudo ◽  
Yuji Hishida ◽  
Masanori Watanabe ◽  
Tomoaki Hatayama ◽  
Takashi Fuyuki

ABSTRACTAdvanced high frequency devices using GaN-based semiconductor require the technology to form high resistivity regions with high thermal stability to electrically isolate the active elements from surroundings, as well as from the underlying substrate. The present paper describes the preparation of thermally stable, high resistivity GaN layers by ion implantation. It was confirmed that C or Zn implantation yielded high resistivity layers. In particular, Zn implantation yielded the layers with resistivity on the order of 1010 cm, which could be sustained at temperatures as high as 1000.


Sign in / Sign up

Export Citation Format

Share Document