Preparation of Rh/C and its high electro-catalytic activity for ethanol oxidation in alkaline media

RSC Advances ◽  
2015 ◽  
Vol 5 (111) ◽  
pp. 91829-91835 ◽  
Author(s):  
Fangfang Zhang ◽  
Debi Zhou ◽  
Zejie Zhang ◽  
Mingda Zhou ◽  
Qian Wang
Keyword(s):  
Catalytic Activity ◽  
Ethanol Oxidation ◽  
Alkaline Media ◽  
Ethanol Electrooxidation ◽  
Electro Catalytic Activity

The ethanol electrooxidation behaviors on Rh/C in alkaline media were studied compared with that on Pd/C.

Outstanding electro-catalytic activity of Pt x –(RuO y –CeO2)1−x /C composites towards ethanol oxidation in acid media

2013 ◽  
Vol 43 (9) ◽  
pp. 953-965 ◽  
Author(s):  
Lorenna L. A. Souza ◽  
Gláucia R. O. Almeida ◽  
Lays S. R. Silva ◽  
Franciele O. F. Bergamaski ◽  
Álvaro S. Lima ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ethanol Oxidation ◽  
Acid Media ◽  
Electro Catalytic Activity

Carbonized 1H-benzotriazole modified carbon depositing Pd for ethanol electrooxidation

2016 ◽  
Vol 40 (2) ◽  
pp. 1633-1639
Author(s):  
Yanqin Liu ◽  
Wei Wang ◽  
Fengxia Wang ◽  
Yan Yang ◽  
Dan Chai ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Ethanol Oxidation ◽  
Alkaline Media ◽  
Ethanol Electrooxidation ◽  
Enhanced Electrochemical Performance

A Pd/BTA-MC catalyst was prepared with an enhanced electrochemical performance towards ethanol oxidation in alkaline media.

Role of the Metal-Oxide Support in the Catalytic Activity of Pd Nanoparticles for Ethanol Electrooxidation in Alkaline Media

2015 ◽  
Vol 3 (2) ◽  
pp. 218-227 ◽  
Author(s):  
Evans Angwenyi Monyoncho ◽  
Spyridon Ntais ◽  
Nicolas Brazeau ◽  
Jhing-Jhou Wu ◽  
Chia-Liang Sun ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Oxide ◽  
Pd Nanoparticles ◽  
Alkaline Media ◽  
Ethanol Electrooxidation ◽  
Oxide Support ◽  
Metal Oxide Support

Surfactant-Free Synthesis of PdPt/rGO for the Alkaline Ethanol Oxidation Reaction

NANO ◽  
2017 ◽  
Vol 12 (09) ◽  
pp. 1750105 ◽  
Author(s):  
Meiling Peng ◽  
Tao Wang ◽  
Zhenzhen Jiang ◽  
Sheng Wang
Keyword(s):  
Catalytic Activity ◽  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Uv Light ◽  
Synthesis Method ◽  
Active Surface ◽  
Alkaline Media ◽  
Active Surface Area ◽  
Ethanol Oxidation Reaction ◽  
Direct Alcohol Fuel Cells

In this work, a synthesis method of residue-free PdPt nanodendrites on reduced graphene oxide (rGO) is reported. Using UV light as an energy trigger and methanol as the reducing agent, PdPt nanodendrites are synthesized with clean, residue-free surfaces (e.g., surfactant and polymer). In comparison with commercial Pd/C and Pt/C catalysts, the as-prepared PdPt nanodendrites on rGO have a large electrochemically active surface area, enhanced catalytic activity, high stability, and tolerance toward the ethanol oxidation reaction in alkaline media. Among the nanodendrite composites prepared, those containing a Pd:Pt ratio of 1:2 on rGO exhibit the best stability and durability, and their mass activity is 2.0 and 2.4 times greater than those of commercial Pt/C and Pd/C catalysts, respectively. This strategy presents an environmentally friendly way to fabricate other noble metal catalysts with improved catalytic activity and stability for use in direct alcohol fuel cells.

Preparation and Characterization of the PdW/MWCNT Anode Catalyst for Alkaline Direct Ethanol Fuel Cells

2013 ◽  
Vol 448-453 ◽  
pp. 2986-2989 ◽  
Author(s):  
Wei Min Chen ◽  
Yu Zhang
Keyword(s):  
Ethanol Oxidation ◽  
Reduction Method ◽  
Alkaline Media ◽  
Support Surface ◽  
Ethanol Electrooxidation ◽  
Anode Catalyst ◽  
Direct Ethanol Fuel Cells ◽  
Onset Potential ◽  
Catalytic Performances

The tungsten modified Pd-based nanocatalyst for ethanol oxidation in alkaline media was prepared by an ethylene glycol reduction method, and the catalytic performances of the prepared catalysts were evaluated. The results show that the addition of tungsten improved the dispersion of metal nanoparticles on the support surface and thus increased the current density of Pd-based catalyst for ethanol electrooxidation. In addition, it was found that in the tungsten modified Pd-based catalyst, tungsten interacted with palladium, leading to a low onset potential and a decreased active energy for ethanol oxidation. On the other hand, it was also observed that the addition of tungsten improved the poison resistance of Pd-based catalysts for ethanol oxidation.

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