Seeded swelling polymerized sea urchin-like core–shell typed polystyrene/polyaniline particles and their electric stimuli-response

RSC Advances ◽  
2015 ◽  
Vol 5 (99) ◽  
pp. 81546-81553 ◽  
Author(s):  
Dana Kim ◽  
Yu Tian ◽  
Hyoung Jin Choi
Keyword(s):  
Sea Urchin ◽  
Silicone Oil ◽  
Dispersion Stability ◽  
Core Shell ◽  
Stimuli Response ◽  
Er Fluid

Sea urchin-like polystyrene/polyaniline particles were synthesized by a seeded swelling polymerization. When dispersed in silicone oil to produce an electrorheological (ER) fluid, they exhibit typical ER behaviors with better dispersion stability.

Measurement of Interaction Forces at Small Distance under Electric Field in a Smectite Dispersed Silicone Oil Based ER Fluid

2001 ◽  
Vol 15 (06n07) ◽  
pp. 811-816 ◽  
Author(s):  
Toyohisa FUJITA ◽  
Toshio MIYAZAKI ◽  
Toshiharu TANAKA ◽  
Ke Jun Liu ◽  
Eiich KUZUNO ◽  
...  
Keyword(s):  
Electric Field ◽  
Silicone Oil ◽  
Small Distance ◽  
Surface Forces ◽  
Attraction Force ◽  
Interaction Forces ◽  
Repulsive Energy ◽  
Inflection Points ◽  
Dc Electric Field ◽  
Er Fluid

The apparatus to measure interaction forces under an electric field at small distance between a conductive hemisphere and a flat plate has been developed. The surface forces at small distance sandwiched ER fluid dispersing ultrafine smectite particles (20 to 50 nm thickness) in silicone oil has been measured. This fluid shows 0.7 kPa of apparent yield stress by applying 2.5 kV/mm of DC electric field. When an electric field applies to this ER fluid, the repulsive energy curves shows inflection points at about 0.2 μ m distance periodically at small distance of less than 1 μ m because the repulsion force decreases for a vacancy of particles after the particles are pushed out and the dipole attraction force acts between hemisphere and plate. On the other hand, when the electric field becomes off and it passes enough time, the inflection points is observed more shorter distance of about 0.15 μ m periodically. The coagulated particle size is estimated about 0.15 μ m under no electric field and becomes larger by applying electric field.

LANTHANUM TITANATE NANOPARTICLES ER FLUIDS WITH HIGH PERFORMANCE

2012 ◽  
Vol 26 (13) ◽  
pp. 1250079 ◽  
Author(s):  
DE WANG ◽  
RONG SHEN ◽  
SHIQIANG WEI ◽  
KUNQUAN LU
Keyword(s):  
Yield Stress ◽  
Silicone Oil ◽  
Heating Temperature ◽  
Hydroxyl Group ◽  
Lanthanum Titanate ◽  
Different Temperatures ◽  
Static Yield ◽  
Er Fluids ◽  
Er Fluid ◽  
Static Yield Stress

A new type of electrorheological (ER) fluid consisting of lanthanum titanate (LTO) nanoparticles is developed. The ER fluids were prepared by suspending LTO powder in silicone oil and the particles were fabricated by wet chemical method. This ER fluid shows excellent ER properties: The static yield stress reaches over 150 kPa under 5 kV/mm with linear dependence on the applied DC electric field, and the current density is below 10 μA/cm2. In order to investigate the affect factor on the ER behavior, the LTO powder were heated under different temperatures. The ER performances of two particles treated under different temperatures were compared and the composition changes for those particles were analyzed with TG-FTIR technique. It was found that the static yield stress of the suspensions fell from over 150 kPa to about 40 kPa and the current densities decreased prominently as the rise of the heating temperature. TG-FTIR analysis indicated that polar groups remained in the particles such as alkyl group, hydroxyl group and carbonyl group etc., contribute to the ER effect significantly. The experimental results are helpful to understand the mechanism of the high ER effect and to synthesize better ER materials.

Electrorheological Properties of Ni-Group Nano Particles and Multilayer Compound Polar Molecule Modify

2012 ◽  
Vol 476-478 ◽  
pp. 1749-1752
Author(s):  
Suo Kui Tan ◽  
Xiao Ping Song ◽  
Song Ji ◽  
Hong Zhao ◽  
Min Wu ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Shear Stress ◽  
Polar Molecule ◽  
Nano Particles ◽  
Core Shell ◽  
Shell Particles ◽  
The Relationship ◽  
Er Fluid ◽  
Electrorheological Properties ◽  
Molecule Type

This paper emphasis has researched the ER properties of Ni group core-shell nano particles modifier with Urea，SDBS and other polar molecule，analysis the relationship among ER properties and polar molecule type ，compound modifier under different electric field or magnetic field. It is found that the shear stress increasing with adding polar molecule, compound polar molecule modify can marked advance the properties of Ni group core-shell particles ER fluid.

HIGH PERFORMANCE CALCIUM TITANATE NANOPARTICLE ER FLUIDS

2005 ◽  
Vol 19 (07n09) ◽  
pp. 1110-1113 ◽  
Author(s):  
XUEZHAO WANG ◽  
RONG SHEN ◽  
WEIJIA WEN ◽  
KUNQUAN LU
Keyword(s):  
High Performance ◽  
Silicone Oil ◽  
Calcium Titanate ◽  
Hydroxyl Group ◽  
Long Term Stability ◽  
Dc Electric Field ◽  
Wet Chemical ◽  
Er Fluids ◽  
Er Fluid

A type of calcium titanate (CTO) nanoparticles was synthesized by means of wet chemical method [1] without coating on the particles. The CTO/silicone oil ER fluid exhibits excellent electrorheological properties: high shear stress (~50-100 kPa ) under dc electric field, a low current density (less than 2μA/cm2 at 5kV/mm), and long term stability against sedimentation. Although there are not special additives in the ER fluids, it is found from the chemical analysis that a trace of alkyl group, hydroxyl group, carbonyl group and some ions is remained in the particles which may dominate the ER response.

Position Control of a Cylinder Using a Hydraulic Bridge Circuit With ER Valves

1997 ◽  
Vol 122 (1) ◽  
pp. 202-209 ◽  
Author(s):  
Seung-Bok Choi ◽  
Woo-Yeon Choi
Keyword(s):  
Electric Field ◽  
Position Control ◽  
Bridge Circuit ◽  
Silicone Oil ◽  
Network Control ◽  
Operational Parameters ◽  
Pressure Drops ◽  
Feedback Error Learning ◽  
Feedback Error ◽  
Er Fluid

This paper presents the position control of a double-rod cylinder system using a hydraulic bridge circuit with four electro-rheological (ER) valves. After synthesizing a silicone oil-based ER fluid, a Bingham property of the ER fluid is first tested as a function of electric field in order to determine operational parameters for the ER valves. On the basis of the level of the field-dependent yield stress of the composed ER fluid, four cylindrical ER valves are designed and manufactured. Subsequently, step responses for pressure drops of the ER valve are empirically analyzed with respect to the intensity of the electric field. A cylinder system with a cart is then constructed using a hydraulic bridge circuit with four ER valves, and its governing equation of motion is derived. A neural network control scheme incorporating the proportional-integral-derivative (PID) controller is formulated through the feedback error learning method, and experimentally implemented for the position control of the cylinder system. Both regulating and tracking position control responses for square and sinusoidal trajectories are presented in time domain. In addition, a tracking durability of the control system is provided to demonstrate the practical feasibility of the proposed methodology. [S0022-0434(00)00701-2]

ELECTRORHEOLOGICAL BEHAVIOR OF CHITOSAN DERIVATIVE SUSPENSIONS

2001 ◽  
Vol 15 (06n07) ◽  
pp. 1025-1032 ◽  
Author(s):  
Ung-su Choi ◽  
Byeng-gil Ahn ◽  
Oh-kwan Kwon
Keyword(s):  
Electric Field ◽  
Volume Fraction ◽  
Silicone Oil ◽  
Flow Behavior ◽  
Chitosan Derivative ◽  
Shear Yield Stress ◽  
Bingham Flow ◽  
Shear Yield ◽  
The Difference ◽  
Er Fluid

The electrorheological (ER) behavior of chitosan and chitosan phosphate suspensions in silicone oil was investigated. Chitosan and chitosan phosphate suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited excellent shear yield stress compared with chitosan suspension. The difference in behavior results from the difference in the conductivity of the chitosan and chitosan phosphate particles due to their degree of the polarizability. The shear stress for chitosan and chitosan phosphate suspensions showed a linear dependence on the volume fraction of particles. The values of structure factor, A s obtained 1 and 3~4 for chitosan and chitosan phosphate suspensions and it may be due to the formation of single-row chains and multiple chains upon application of the electric field. Throughtout the experimental results, chitosan and chitosan phosphate suspensions were shown to be an ER fluid.

Electrorheological Properties of Suspensions Based on Polyaniline-montmorillonite Clay Nanocomposite

2002 ◽  
Vol 17 (6) ◽  
pp. 1513-1519 ◽  
Author(s):  
Jun Lu ◽  
Xiaopeng Zhao
Keyword(s):  
Dielectric Constant ◽  
Dielectric Loss ◽  
Yield Stress ◽  
Electric Fields ◽  
High Dielectric Constant ◽  
Silicone Oil ◽  
Transmission Electron ◽  
High Dielectric ◽  
Er Fluid ◽  
Electrorheological Properties

It is thought that high-dielectric constant, suitable conductivity, and dielectric loss dominate electrorheological (ER) effects. According to this viewpoint, the polyaniline/montmorillonite nanocomposite (PANI-MMT) particles with high-dielectric constant and suitable conductivity were synthesized by an emulsion intercalation method. The electrorheological properties of the suspensions of PANI-MMT particles in silicone oil have been investigated under direct current electric fields. At room temperature, it was found that the yield stress of PANI-MMT ER fluid was 7.19 kPa in 3 kV/mm, which is much higher than that of pure polyaniline (PANI), that of pure montmorillonite (MMT) as well as that of the mixture of polyaniline with clay (PANI+MMT). In the range of 10–100 °C, the yield stress changed only 6.5% with the variation of temperature. The sedimentation ratio of PANI-MMT ERF was about 98% after 60 days. The structure of PANI-MMT particles was characterized by infrared, x-ray diffraction (XRD), and transmission electron microscopy (TEM) spectrometry, respectively. The XRD spectra show that the inner layer distance of PANI-MMT can be enhanced to 1.52 nm when the PANI was inserted into the interlayer of MMT, whereas it is only 0.96 nm for free MMT. TEM shows that the diameter of PANI-MMT particles is about 100 nm. The dielectric constant of PANI-MMT nanocomposite was increased 5.5 times that of PANI and 2.7 times that of MMT, besides, the conductivity of PANI-MMT particle was increased about 8.5 times that of PANI at 1000 Hz. Meanwhile, the dielectric loss tangent can also be increased about 1.7 times that of PANI. It is apparent that the notable ER effect of PANI-MMT ER fluid was attributed to the prominent dielectric property of the polyaniline-montmorillonite nanocomposite particles.

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