A convenient and efficient synthesis method to improve the emission intensity of rare earth ion doped phosphors: the synthesis and luminescent properties of novel SrO:Ce3+ phosphor

RSC Advances ◽  
2015 ◽  
Vol 5 (114) ◽  
pp. 93951-93956 ◽  
Author(s):  
Jipeng Fu ◽  
Su Zhang ◽  
Tengfei Ma ◽  
Yonglei Jia ◽  
Ran Pang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Reaction Temperature ◽  
Emission Intensity ◽  
Synthesis Method ◽  
Luminescent Properties ◽  
Efficient Synthesis ◽  
Rare Earth Ion ◽  
Harsh Conditions

A convenient and efficient synthesis method that improves the emission intensity of rare earth ion doped phosphors is proposed. This approach can greatly improve the reaction temperature and overcome the requirement for harsh conditions.

scholarly journals Structure, Luminescence, and Magnetic Properties of Crystalline Manganese Tungstate Doped with Rare Earth Ion

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3717
Author(s):  
Jae-Young Jung ◽  
Soung-Soo Yi ◽  
Dong-Hyun Hwang ◽  
Chang-Sik Son
Keyword(s):  
Magnetic Field ◽  
Rare Earth ◽  
Sintering Temperature ◽  
Luminescent Properties ◽  
Concentration Quenching ◽  
Rare Earth Ions ◽  
Precipitation Method ◽  
Rare Earth Ion ◽  
Co Precipitation ◽  
Quenching Phenomenon

The precursor prepared by co-precipitation method was sintered at various temperatures to synthesize crystalline manganese tungstate (MnWO4). Sintered MnWO4 showed the best crystallinity at a sintering temperature of 800 °C. Rare earth ion (Dysprosium; Dy3+) was added when preparing the precursor to enhance the magnetic and luminescent properties of crystalline MnWO4 based on these sintering temperature conditions. As the amount of rare earth ions was changed, the magnetic and luminescent characteristics were enhanced; however, after 0.1 mol.%, the luminescent characteristics decreased due to the concentration quenching phenomenon. In addition, a composite was prepared by mixing MnWO4 powder, with enhanced magnetism and luminescence properties due to the addition of dysprosium, with epoxy. To one of the two prepared composites a magnetic field was applied to induce alignment of the MnWO4 particles. Aligned particles showed stronger luminescence than the composite sample prepared with unsorted particles. As a result of this, it was suggested that it can be used as phosphor and a photosensitizer by utilizing the magnetic and luminescent properties of the synthesized MnWO4 powder with the addition of rare earth ions.

Synthesis, Morphology Control and Luminescent Properties of Rare Earth Ion-Doped CaWO4 Microstructures

2016 ◽  
Vol 16 (4) ◽  
pp. 4029-4034 ◽  
Author(s):  
Chunxia Liu ◽  
Lixia Yang ◽  
Dan Yue ◽  
Mengnan Wang ◽  
Lin Jin ◽  
...  
Keyword(s):  
Rare Earth ◽  
Uv Light ◽  
Luminescent Properties ◽  
Average Diameter ◽  
Rare Earth Ions ◽  
X Ray Diffraction ◽  
Hydrothermal Route ◽  
Rare Earth Ion ◽  
X Ray ◽  
Facile Hydrothermal Route

Rare earth ions (Tb3+, Eu3+) doped CaWO4 microstructures were synthesized by a facile hydrothermal route without using any templates and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence (PL) spectrum. The results indicate that the asprepared samples are well crystallized with scheelite structure of CaWO4, and the average diameter of the microstructures is 2∼4 μm. The morphology of CaWO4:Eu3+ microstructures can be controllably changed from microspheres to microflowers through altering the doping concentration of Eu3+ from 3% to 35%, and the microflowers are constructed by a number of CaWO4:Eu3+ nanoflakes. Under the excitation of UV light, the emission spectrum of CaWO4:Eu3+ is composed of the characteristics emission of Eu3+ 5D0-7FJ (J = 1, 2, 3, 4) transitions, and that of CaWO4:Tb3+ is composed of Tb3+ 5D4-7FJ (J = 6, 5, 4, 3) transitions. Both of the optimal doping concentrations of Tb3+ and Eu3+ in CaWO4 microstructures are about 5%.

Luminescent Properties of Rare Earth Doped AlF3-Based Glasses

1991 ◽  
Vol 244 ◽  
Author(s):  
L. R. Copeland ◽  
W. A. Reed ◽  
M. R. Shahriari ◽  
T. Iqbal ◽  
P. Hajcak ◽  
...  
Keyword(s):  
Rare Earth ◽  
Optical Fibers ◽  
Luminescent Properties ◽  
Rare Earth Ions ◽  
Ion Concentration ◽  
Fluoride Glass ◽  
Oxide Glasses ◽  
Low Loss ◽  
Rare Earth Ion ◽  
Rare Earth Doped

ABSTRACTRare earth ions can easily be incorporated into fluoride glasses in moderate to large concentrations and, due to their low phonon energy, these glasses appear to have many advantages over oxide glasses as hosts for rare earth ions used in optical amplifiers and lasers. We have therefore investigated the optical properties of Pr3+, Pr3+/Yb3+ and Pr3+/Yb3+/Lu3+ doped bulk AIF3-based glass samples as a function of rare earth ion concentration. We find that the addition of 2 wt% of Yb increases the fluorescence of Pr3+ at 1.32 μm by a factor of 35 when excited with 488 nm radiation. The fluorescence intensity and excited state lifetimes are found to be comparable to those measured for Pr in a ZBLAN host. Since it has also been demonstrated that optical fibers drawn from AIF3-based glasses exhibit relatively low loss (< 0.05 dB/m) and posses superior chemical durability compared to other fluotide glasses, it is possible that AIF3 glasses may become the fluoride glass of choice for practical fiber laser and amplifier applications.

Rare-Earth-Ion-Doped Hexagonal-Phase NaYF4 Nanowires: Controlled Synthesis and Luminescent Properties

2009 ◽  
Vol 113 (19) ◽  
pp. 8136-8142 ◽  
Author(s):  
De-Kun Ma ◽  
Shao-Ming Huang ◽  
Yan-Yan Yu ◽  
Ying-Feng Xu ◽  
You-Qing Dong
Keyword(s):  
Rare Earth ◽  
Hexagonal Phase ◽  
Luminescent Properties ◽  
Controlled Synthesis ◽  
Rare Earth Ion

ENERGY-TRANSFER PROCESS IN RARE-EARTH-ION DOPED SrTiO3

2001 ◽  
Vol 15 (28n30) ◽  
pp. 3924-3927 ◽  
Author(s):  
SHINJI OKAMOTO ◽  
SHOSAKU TANAKA ◽  
HAJIME YAMAMOTO
Keyword(s):  
Energy Transfer ◽  
Rare Earth ◽  
Temperature Dependence ◽  
Oscillator Strength ◽  
Transfer Process ◽  
Emission Intensity ◽  
Energy Transfer Process ◽  
Rare Earth Ions ◽  
Rare Earth Ion ◽  
Pl Spectra

Enhancement of emission intensity of rare-earth-ion doped SrTiO 3 by Al addition has been investigated. In the case of Pr 3+ and Tb 3+, addition of 23-mol% Al intensifies emission by more than 200 times. In contrast, the addition of 20 mol% Al intensifies emission at most by three times in the case of other rare-earth ions. The temperature dependence of PL spectra shows that the energy transfer from carriers to Pr 3+ or Tb 3+ ions is much more efficient than that to other rare-earth ions in SrTiO 3. It can be speculated that the energy transfer in SrTiO 3: Pr 3 or Tb 3+ occurs from carriers to Pr 3+ or Tb 3+ ion via 4f-5d transitions, which are much higher in oscillator strength than 4f-4f transitions.

scholarly journals Controllable Morphology, Phase and Luminescent Properties of Rare Earth Ion-doped LaPO4Nano-structural Materials

2012 ◽  
Vol 70 (17) ◽  
pp. 1812 ◽  
Author(s):  
Dan Yue ◽  
Chunyang Li ◽  
Wei Lu ◽  
Xinlei Zhang ◽  
Jiazhong Chang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Luminescent Properties ◽  
Structural Materials ◽  
Rare Earth Ion

Nanocrystalline Rare Earth-doped Gallium Nitride Phosphor Powders

2005 ◽  
Vol 866 ◽  
Author(s):  
G.A. Hirata ◽  
J. Tao ◽  
P. Chen ◽  
K.C. Mishra ◽  
J. McKittrick
Keyword(s):  
Rare Earth ◽  
Gallium Nitride ◽  
High Purity ◽  
Photoelectron Spectroscopy ◽  
Single Phase ◽  
Luminescent Properties ◽  
Nanocrystalline Powder ◽  
Rare Earth Ion ◽  
Chemical Route ◽  
Rare Earth Doped

AbstractWe report on the fabrication and luminescent properties of rare earth-doped gallium nitride (GaN) phosphor powders. Single phase GaN and GaN:RE3+ powders were prepared by using a novel chemical route.In this work a new method for the synthesis of high purity, single phase doped GaN powders is reported. (Ga1-xREx)N powders are obtained by dissolving metal nitrates (Ga(NO3)3, (RE(NO3)3) in deionized water and an organic fuel (hydrazine) in order to form a gallium/RE amorphous/nanocrystalline powder. The RE-oxide powders are then reacted with heated ammonia at different temperatures and processing times producing GaN:RE phosphors. X-ray diffraction analysis showed that single phase GaN powders are formed. Preliminary results show (Ga0.95Eu0.05)N powders are luminescent, with the main emission occurring at 611 nm which is due to the 5Do→7F2 transitions in Eu3+. High-purity GaN powders are obtained according to Xray photoelectron spectroscopy (XPS) chemical analysis. Low-temperature cathodoluminescence and photoluminescence measurements indicate that the emission at λ=611 nm is originated from energy transfer from the host to the rare earth ion and to a direct excitation to the Eu3+ electronic levels.This method can be used to obtain red-luminescence GaN:Eu3+ and other rare earth (e.g. Er, Tb, Tm)-doped GaN powders to produce green and blue luminescence as well.

scholarly journals Photoluminescence Properties of Eu3+ and Ce3+ Activated Calcium Chlorophosphate Via Combustion Synthesis Method

2016 ◽  
Vol 1 (1-2) ◽  
pp. 10-15
Author(s):  
Nahida Baig ◽  
N. S. Dhoble ◽  
N. S. Kokode ◽  
S. J. Dhoble
Keyword(s):  
Rare Earth ◽  
Combustion Synthesis ◽  
Synthesis Method ◽  
Ultra Violet ◽  
Luminescent Properties ◽  
Rare Earth Ions ◽  
Excitation Spectra ◽  
Pl Emission ◽  
Narrow Bands ◽  
Uv Range

Calcium chlorophosphate (Ca2PO4Cl) phosphors, activated by rare earth ions Eu3+ and Ce3+ were prepared by urea assisted combustion synthesis technique and their characterization and luminescent properties were studied. The synthesized phosphors were investigated by powdered XRD, SEM and Photoluminescence characterization (PL) methods. PL excitation spectra of Ca2PO4Cl:Eu3+/Ce3+ phosphor exhibit narrow bands in the near ultra violet (n-UV) range, and the PL emission spectra of Ca2PO4Cl: Eu3+/Ce3+ phosphor shows sharp narrow bands typical of rare earth ions. The bands observed in the PL emission and excitation spectra of Ca2PO4Cl: Eu3+/Ce3+ phosphors can be ascribed to the electronic transitions within 4f configurations of rare earth ions. The excitation peaks for Ca2PO4Cl: Eu3+ is in n-UV range. The obtained results suggest that these phosphors may be favorable for lamp industry.

Metal and Non-Metal Catalysts in the Synthesis of Five-Membered S-Heterocycles

2019 ◽  
Vol 16 (2) ◽  
pp. 258-275 ◽  
Author(s):  
Navjeet Kaur
Keyword(s):  
Organic Synthesis ◽  
Biological Activities ◽  
Reaction Times ◽  
Research Field ◽  
Environmentally Benign ◽  
Metal Catalyst ◽  
Efficient Synthesis ◽  
Heterocyclic Molecules ◽  
The Past ◽  
Harsh Conditions

Background:A wide variety of biological activities are exhibited by N, O and S containing heterocycles and recently, many reports appeared for the synthesis of these heterocycles. The synthesis of heterocycles with the help of metal and non-metal catalyst has become a highly rewarding and important method in organic synthesis. This review article concentrated on the synthesis of S-heterocylces in the presence of metal and non-metal catalyst. The synthesis of five-membered S-heterocycles is described here.Objective:There is a need for the development of rapid, efficient and versatile strategy for the synthesis of heterocyclic rings. Metal, non-metal and organocatalysis involving methods have gained prominence because traditional conditions have disadvantages such as long reaction times, harsh conditions and limited substrate scope.Conclusion:The metal-, non-metal-, and organocatalyst assisted organic synthesis is a highly dynamic research field. For ßthe chemoselective and efficient synthesis of heterocyclic molecules, this protocol has emerged as a powerful route. Various methodologies in the past few years have been pointed out to pursue more sustainable, efficient and environmentally benign procedures and products. Among these processes, the development of new protocols (catalysis), which avoided the use of toxic reagents, are the focus of intense research.

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