Magnetically recoverable mesoporous melamine–formaldehyde nanoparticles as an efficient adsorbent for hexavalent chromium removal

RSC Advances ◽  
2015 ◽  
Vol 5 (102) ◽  
pp. 83788-83794 ◽  
Author(s):  
Zhongfei Lv ◽  
Dandan Zhao ◽  
Changsheng Liang ◽  
Jiayang Cui ◽  
Yangben Cai ◽  
...  

Functional porous nanoparticles have been considered as potential adsorbents for chromium (Cr) removal due to their unique properties such as high surface area, nanosized structure and specific affinity for heavy metal ions.

RSC Advances ◽  
2016 ◽  
Vol 6 (93) ◽  
pp. 90516-90525 ◽  
Author(s):  
Shani Egodawatte ◽  
Katherine E. Greenstein ◽  
Ivy Vance ◽  
Edris Rivera ◽  
Nosang V. Myung ◽  
...  

Functionalized nanomaterials hold tremendous promise for water treatment because their high surface area makes them ideal sorbents for pollutants like heavy metal ions that are pervasive in global water supplies.


2016 ◽  
Vol 4 (2) ◽  
pp. 400-406 ◽  
Author(s):  
Shuliang Yang ◽  
Peipei Huang ◽  
Li Peng ◽  
Changyan Cao ◽  
Yanan Zhu ◽  
...  

3D hierarchical flowerlike MgO hollow spheres with extremely high surface area showed excellent adsorption properties for heavy metal ions and catalytic properties for the Claisen–Schmidt condensation reaction.


2014 ◽  
Vol 2 (14) ◽  
pp. 5034-5040 ◽  
Author(s):  
Zhihui Dong ◽  
Dong Wang ◽  
Xia Liu ◽  
Xianfeng Pei ◽  
Liwei Chen ◽  
...  

By utilizing the synergistic effect of poly-dopamine (PD) with functional groups and graphene oxide (GO) with a high surface area, a series of sub-nano thick PD layer coated GO (PD/GO) composites were fabricated and used for effectively decontaminating wastewater.


Nanomaterials ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 866 ◽  
Author(s):  
Ying He ◽  
Li Ma ◽  
Liya Zhou ◽  
Guanhua Liu ◽  
Yanjun Jiang ◽  
...  

A nano-form composite of MXenes (Ti3C2Tx, Tx = -O, -OH, -F) was synthesized through depositing bismuth-nanoparticle (BiNPs) onto Ti3C2Tx sheets. Because of the preventive effect of the two-dimensional layered structure of Ti3C2Tx, the nanoparticles of Bi were uniform and well attached on the Ti3C2Tx. The obtained BiNPs/Ti3C2Tx nano-composite was applied for sensors construction of electrochemical detecting of Pb2+ and Cd2+ heavy metal ions. The produced BiNPs@Ti3C2Tx-based sensor showed high effective surface area and excellent conductivity. Also, the BiNPs were efficient for anodic-stripping voltammetric to detect heavy metal ions. After conditions optimization, the BiNPs@Ti3C2Tx nano-sensor could detect Pb2+ and Cd2+ simultaneously and the detection limits were 10.8 nM for Pb2+ and 12.4 nM for Cd2+. The BiNPs@Ti3C2Tx was promising for detecting heavy metal ions due to their high surface area, fast electron-transfer ability, environmental friendliness, and facial preparation.


Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7725
Author(s):  
Amanda Kulpa-Koterwa ◽  
Tadeusz Ossowski ◽  
Paweł Niedziałkowski

Over the past few decades, nanoparticles of iron oxide Fe3O4 (magnetite) gained significant attention in both basic studies and many practical applications. Their unique properties such as superparamagnetism, low toxicity, synthesis simplicity, high surface area to volume ratio, simple separation methodology by an external magnetic field, and renewability are the reasons for their successful utilisation in environmental remediation, biomedical, and agricultural applications. Moreover, the magnetite surface modification enables the successful binding of various analytes. In this work, we discuss the usage of core–shell nanoparticles and nanocomposites based on Fe3O4 for the modification of the GC electrode surface. Furthermore, this review focuses on the heavy metal ions electrochemical detection using Fe3O4-based nanoparticles-modified electrodes. Moreover, the most frequently used electrochemical methods, such as differential pulse anodic stripping voltammetry and measurement conditions, including deposition potential, deposition time, and electrolyte selection, are discussed.


Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1907
Author(s):  
Fatma Hussain Emamy ◽  
Ali Bumajdad ◽  
Jerzy P. Lukaszewicz

Optimizing the physicochemical properties of the chitosan-based activated carbon (Ch-ACs) can greatly enhance its performance toward heavy metal removal from contaminated water. Herein, Ch was converted into a high surface area (1556 m2/g) and porous (0.69 cm3/g) ACs with large content of nitrogen (~16 wt%) using K2CO3 activator and urea as nitrogen-enrichment agents. The prepared Ch-ACs were tested for the removal of Cr(VI) and Pb(II) at different pH, initial metal ions concentration, time, activated carbon dosage, and temperature. For Cr(VI), the best removal was at pH = 2, while for Pb(II) the best pH for its removal was in the range of 4–6. At 25 °C, the Temkin model gives the best fit for the adsorption of Cr(VI), while the Langmuir model was found to be better for Pb(II) ions. The kinetics of adsorption of both heavy metal ions were found to be well-fitted by a pseudo-second-order model. The findings show that the efficiency and the green properties (availability, recyclability, and cost effectiveness) of the developed adsorbent made it a good candidate for wastewaters treatment. As preliminary work, the prepared sorbent was also tested regarding the removal of heavy metals and other contaminations from real wastewater and the obtained results were found to be promising.


RSC Advances ◽  
2015 ◽  
Vol 5 (21) ◽  
pp. 16549-16553 ◽  
Author(s):  
Donghun Kim ◽  
Bradley F. Chmelka

Transparent functionalized mesoporous silica membranes have been prepared with high surface areas (∼500 m2 g−1) that exhibit high sensitivities for colorimetric detection and sensing of dilute heavy-metal ions (e.g., Pb2+).


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