Structure and asymmetric epoxidation reactivity of chiral Mn(iii) salen catalysts modified by different axial anions

RSC Advances ◽  
2015 ◽  
Vol 5 (98) ◽  
pp. 80772-80778 ◽  
Author(s):  
Xiuxing Xi ◽  
Jing Shao ◽  
Xingbang Hu ◽  
Youting Wu
Keyword(s):  
Electronic Structure ◽  
Asymmetric Epoxidation ◽  
Salen Complexes ◽  
Steric Configuration

The axial anions influence the electronic structure, steric configuration, and enantioselectivity of the chiral Mn(iii) salen complexes.

Zirconium phosphonates-supported chiral Mn (III) Salen complexes for the asymmetric epoxidation of unfunctionalized olefins

2009 ◽  
Vol 10 (8) ◽  
pp. 1261-1266 ◽  
Author(s):  
Zheng Xu ◽  
Xuebing Ma ◽  
Yueyue Ma ◽  
Qiang Wang ◽  
Jinqin Zhou
Keyword(s):  
Asymmetric Epoxidation ◽  
Salen Complexes ◽  
Zirconium Phosphonates

Distorted copper(ii) radicals with sterically hindered salens: electronic structure and aerobic oxidation of alcohols

2020 ◽  
Vol 49 (37) ◽  
pp. 12990-13002
Author(s):  
R. Kunert ◽  
C. Philouze ◽  
F. Berthiol ◽  
O. Jarjayes ◽  
T. Storr ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Aerobic Oxidation ◽  
Phenoxyl Radical ◽  
Redox States ◽  
Salen Complexes ◽  
Oxidation Of Alcohols ◽  
Sterically Hindered ◽  
Unique Stability

Strongly distorted copper salen complexes show a unique stability in four different redox states by CV. Copper phenoxyl radical complexes are structurally characterized. They promote the catalytic aerobic oxidation of 2-phenylethanol under air.

Electronic structure elucidation in oxidized metal–salen complexes

2017 ◽  
Vol 352 ◽  
pp. 67-82 ◽  
Author(s):  
Ryan M. Clarke ◽  
Khrystyna Herasymchuk ◽  
Tim Storr
Keyword(s):  
Electronic Structure ◽  
Structure Elucidation ◽  
Salen Complexes
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