Insight into the catalytic properties and applications of metal–organic frameworks in the cyanosilylation of aldehydes

RSC Advances ◽  
2015 ◽  
Vol 5 (97) ◽  
pp. 79355-79360 ◽  
Author(s):  
Zhiguo Zhang ◽  
Jingwen Chen ◽  
Zongbi Bao ◽  
Ganggang Chang ◽  
Huabin Xing ◽  
...  
Keyword(s):  
Catalytic Properties ◽  
Metal Organic Frameworks ◽  
Systematic Investigation ◽  
Metal Organic ◽  
Insight Into

This paper presents a systematic investigation of the cyanosilylation of aldehydes with TMSCN by using several MOFs as catalysts.

Quantum Mechanical Interpretation of the Ultra-Low Energy Methyl-Rotation Dynamics in Porous Metal-Organic Frameworks Probed by Low-Frequency Vibrational Spectroscopy and ab initio Simulations

2018 ◽  
Author(s):  
Qi Li ◽  
Adam J. Zaczek ◽  
Timothy M. Korter ◽  
J. Axel Zeitler ◽  
Michael T. Ruggiero
Keyword(s):  
Ab Initio ◽  
Metal Organic Frameworks ◽  
Low Frequency ◽  
Rotor Dynamics ◽  
Quantum Mechanical ◽  
Valuable Insight ◽  
Void Space ◽  
Ab Initio Simulations ◽  
Metal Organic ◽  
Insight Into

<div>Understanding the nature of the interatomic interactions present within the pores of metal-organic frameworks</div><div>is critical in order to design and utilize advanced materials</div><div>with desirable applications. In ZIF-8 and its cobalt analogue</div><div>ZIF-67, the imidazolate methyl-groups, which point directly</div><div>into the void space, have been shown to freely rotate - even</div><div>down to cryogenic temperatures. Using a combination of ex-</div><div>perimental terahertz time-domain spectroscopy, low-frequency</div><div>Raman spectroscopy, and state-of-the-art ab initio simulations,</div><div>the methyl-rotor dynamics in ZIF-8 and ZIF-67 are fully charac-</div><div>terized within the context of a quantum-mechanical hindered-</div><div>rotor model. The results lend insight into the fundamental</div><div>origins of the experimentally observed methyl-rotor dynamics,</div><div>and provide valuable insight into the nature of the weak inter-</div><div>actions present within this important class of materials.</div>

Metal-Organic Frameworks (MOFs) as Fuels for Advanced Applications: Evaluating and Modifying the Combustion Energy of Popular MOFs

2019 ◽  
Author(s):  
Hatem M. Titi ◽  
Mihails Arhangelskis ◽  
Athanassis Katsenis ◽  
Cristina Mottillo ◽  
Ghada Ayoub ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Energy Content ◽  
Metal Organic Frameworks ◽  
Systematic Investigation ◽  
Combustion Energy ◽  
Metal Organic ◽  
Advanced Applications ◽  
Ligand Replacement

Systematic investigation of combustion energies for popular metal-organic frameworks (MOFs) reveals energy content comparable to conventional energetic materials and can be further modified and dine-tuned by polymorphism and isostructural ligand replacement to yield materials with energy densities comparable to Diesel or kerosene.<br>

scholarly journals Effect of linker functionalisation on the catalytic properties of Cu nanoclusters embedded in MOFs in direct CO and CO2 reduction by H2

2021 ◽  
Author(s):  
Cornelia Elizabeth Pompe ◽  
Petra Agota Szilagyi
Keyword(s):  
Catalytic Properties ◽  
Metal Organic Frameworks ◽  
Co2 Reduction ◽  
Catalytically Active ◽  
Metal Organic ◽  
Cu Nanoclusters

Metal-organic frameworks are promising host supporting matrices for catalytically active guest. In particular, their crystallinity renders them desirable as their pores may act as atom-precise templates for the growth of...

Biomimetic Catalysts of Iron–based Metal-Organic Frameworks with High Peroxidase-Mimicking Activity for Colorimetric Biosensing

2021 ◽  
Author(s):  
Xiao-Ning Wang ◽  
Yu-Meng Zhao ◽  
Jialuo Li ◽  
Jiandong Pang ◽  
Qiang Wang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Systematic Investigation ◽  
Biomimetic Catalysts ◽  
Biomimetic Catalyst ◽  
Metal Organic ◽  
Iron Based ◽  
Colorimetric Biosensing

The field of Metal-Organic Frameworks (MOFs)-based biomimetic catalyst has achieved great progresses, but is still in its infancy stage. The systematic investigation on the tailored construction of MOF-based biomimetic catalysts...

Small Molecules, Big Effects: Tuning Adsorption and Catalytic Properties of Metal–Organic Frameworks

2021 ◽  
Vol 33 (4) ◽  
pp. 1444-1454
Author(s):  
Xinyao Liu ◽  
Kent O. Kirlikovali ◽  
Zhijie Chen ◽  
Kaikai Ma ◽  
Karam B. Idrees ◽  
...  
Keyword(s):  
Small Molecules ◽  
Catalytic Properties ◽  
Metal Organic Frameworks ◽  
Metal Organic

Insight into the Unique Fluorescence Quenching Property of Metal-Organic Frameworks upon DNA Binding

2017 ◽  
Vol 89 (21) ◽  
pp. 11366-11371 ◽  
Author(s):  
Huai-Song Wang ◽  
Hai-Ling Liu ◽  
Kang Wang ◽  
Ya Ding ◽  
Jing-Juan Xu ◽  
...  
Keyword(s):  
Dna Binding ◽  
Fluorescence Quenching ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Insight Into
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