Ultrasensitive electrochemiluminescence aptasensor based on a graphene/polyaniline composite film modified electrode and CdS quantum dot coated platinum nanostructured networks as labels

RSC Advances ◽  
2015 ◽  
Vol 5 (86) ◽  
pp. 70345-70351 ◽  
Author(s):  
Qingkun Kong ◽  
Meng Li ◽  
Chao Ma ◽  
Hongmei Yang ◽  
Shenguang Ge ◽  
...  

A simple electrochemiluminescence (ECL) aptasensor for adenosine triphosphate (ATP) based on graphene/polyaniline (GR/PANI) composite films modified glassy carbon electrode (GCE) was successfully fabricated.

2014 ◽  
Vol 6 (18) ◽  
pp. 7496-7501 ◽  
Author(s):  
Xiaoqian Ouyang ◽  
Yaping Ding ◽  
Xi Ba ◽  
Shuqing Gu

A poly-Ni(ii)–curcumin composite film modified electrode was prepared for amperometric detection of NADH with high sensitivity.


A modified glassy carbon electrode (GCE) compositing multi-walled carbon nanotubes (MWCNTs), Nafion and bismuth film was prepared and applied for the sensitive detection of trace Pb (II). MWCNTs were dispersed into ethanol by ultrasonication in the presence of Nafion and the nanotubes are coated onto the bare GCE. After that, an extra Nafion adhesion agent is added to the electrode. By the in situ plating, a bismuth film was fabricated on the MWCNTs-NA/GCE, making the desired electrode, MWCNTs-NA-Bi/GCE. The modified electrode was characterized by differential pulse anodic stripping voltammetry, scanning electron microscopy, and cyclic voltammetry. A deposition potential of –1.4 V (vs. Ag/AgCl) and a deposition time of 300 s were applied to the working electrode under stirred conditions after optimizing. Nanotubes and Nafion concentrations and pH were carefully optimized to determine trace lead ions by using the electrode as an electrochemical-sensing platform. Nafion effectively increased the stability and adhesivity of the composite film. The MWCNTs-NA-Bi film modified electrode can remarkably increase the anodic peak current of Pb2+. The sensitivity of MWCNTs-NA-Bi/GCE is 4.35 times higher than that of the bare GCE with bismuth film. The prepared electrode showed excellent stability and reproducibility and can be applied for determination of Pb2+ contained wastewater.


2015 ◽  
Vol 7 (19) ◽  
pp. 8344-8351 ◽  
Author(s):  
Guzel Ziyatdinova ◽  
Karina Os'kina ◽  
Endzhe Ziganshina ◽  
Herman Budnikov

Simultaneous voltammetric determination of TBHQ and BHA using a MWNT-Brij® 35 modified glassy carbon electrode in Brij® 35 micellar medium.


2007 ◽  
Vol 72 (9) ◽  
pp. 1177-1188 ◽  
Author(s):  
Xinhua Lin ◽  
Wei Li ◽  
Hong Yao ◽  
Yuanyuan Sun ◽  
Liying Huang ◽  
...  

A poly(Eriochrome Black T) chemically modified glassy carbon electrode modified with Eriochrome Black T was prepared by cyclic voltammetry. The modified electrode showed an excellent electrocatalytic activity in oxidation of noradrenaline (NA) and could separate its electrochemical responses from those of L-ascorbic acid (AA) and uric acid (UA). Differences of the oxidation peak potentials for NA-AA and UA-NA were about 150 mV. The responses to NA, AA and UA of the modified electrode are relatively independent. Using differential pulse voltammetry, the peak currents of NA at modified glassy carbon electrode increased linearly with the concentration of NA from 0.5 to 100 μmol l-1. The detection limit was 0.2 μmol l-1. With the modified electrode, UA could be selectively determined in the presence of AA. The method showing a wide linear dynamic range and excellent sensitivity was successfully applied to the determination of NA in pharmaceutical injections and various samples.


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