Ultra-sensitive polyaniline–iron oxide nanocomposite room temperature flexible ammonia sensor

RSC Advances ◽  
2015 ◽  
Vol 5 (84) ◽  
pp. 68964-68971 ◽  
Author(s):  
D. K. Bandgar ◽  
S. T. Navale ◽  
M. Naushad ◽  
R. S. Mane ◽  
F. J. Stadler ◽  
...  

We report for the first time a room temperature smart NH3sensor based on PAni–Fe2O3nanocomposite loading on flexible PET substrate byin situchemical oxidative polymerization method.

2018 ◽  
Vol 42 (9) ◽  
pp. 6918-6931 ◽  
Author(s):  
Madhurima Das ◽  
Saptarshi Ghosh ◽  
Somenath Roy

This article describes the non-covalent functionalization of multiwall carbon nanotubes (MWCNTs) with polycarbazole (PCz) via an in situ chemical oxidative polymerization method and subsequent fabrication of resistive humidity sensors.


2015 ◽  
Vol 51 (35) ◽  
pp. 7524-7527 ◽  
Author(s):  
Shouli Bai ◽  
Yangbo Zhao ◽  
Jianhua Sun ◽  
Ye Tian ◽  
Ruixian Luo ◽  
...  

A room temperature smart NH3 sensor based on rGO–PANI hybrid loading on flexible PET thin film prepared by in situ chemical oxidative polymerization is reported for the first time. The sensor not only exhibits high sensitivity, good selectivity and fast response but also has flexibility, is inexpensive and has wearable characteristics.


2014 ◽  
Vol 904 ◽  
pp. 159-163 ◽  
Author(s):  
Jia Ping Lao ◽  
Chao Yang ◽  
Hao Dao Mo ◽  
Yu Ping Li ◽  
Li Min Zang ◽  
...  

Functional floating bead (F-FB), prepared by anchoring the organic sulfonic acid on the surface of the blackberry-like structural FB, was used as both the inorganic substrate and the in situ dopant for the in situ chemical oxidative polymerization of pyrrole to obtain the plypyrrole/functional floating bead (PPy/F-FB) nanocomposite material. The composites possess high electrical conductivity at room temperature. Thermogravimetric analysis shows that the thermal stability of PPy/F-FB composites was enhanced and these can be attributed to the retardation effect of sulfonic acid-functionalized FB as barriers for the degradation of PPy. The morphology of PPy/FB composites showed the well-defined blackberry-like morphology.


2017 ◽  
Vol 16 (03) ◽  
pp. 1650037 ◽  
Author(s):  
Nishigandh S. Pande ◽  
Dipika Jaspal ◽  
Jalindar Ambekar

Poly (N-ethyl aniline)/Ag organic–inorganic composite has been synthesized by a single step in situ chemical oxidative polymerization method. The synthesis of Poly (N-ethyl aniline)/Ag nanocomposite has been confirmed by X-ray diffraction (XRD), Ultraviolet-Vis Spectroscopy (UV-visible), Fourier transform infrared analysis (FTIR) and FE-SEM investigations. XRD spectral study exhibited major diffraction in the range 20–80[Formula: see text] (2[Formula: see text]) and indicated the semicrystalline nature of poly (N-ethyl aniline)/Ag nanocomposite. Characteristic peaks in UV-visible and FTIR spectra of poly (N-ethyl aniline) switched to higher wave numbers in poly (N-ethyl aniline)/Ag nanocomposite. Peaks at 1789[Formula: see text]cm[Formula: see text], 1595[Formula: see text]cm[Formula: see text], 667[Formula: see text]cm[Formula: see text] and 501[Formula: see text]cm[Formula: see text] in FTIR spectrum confirmed the formation of poly (N-ethyl aniline)/Ag nanocomposite. FE-SEM photographs reported agglomerated granular particulate nature of poly (N-ethyl aniline)/Ag nanocomposite. Synthesized poly (N-ethyl aniline)/Ag nanocomposite exhibited a high response to humidity, good reproducibility and stability at room temperature. An appreciable response was shown in the presence of 40% humid atmosphere for up to successive four cycles. Composite sensitivity has been found to increase with the increasing concentration of humidity, at room temperature.


2014 ◽  
Vol 687-691 ◽  
pp. 4218-4222
Author(s):  
Wei Hua Han ◽  
Yong Wan ◽  
Bin Sun ◽  
Yun Ze Long ◽  
Qing Chang ◽  
...  

Aligned poly (vinylidene fluoride) (PVDF) nanofibers and the nanoropes have been fabricated via a novel electrospinning technique. And then conducting polyaniline (PANI) was coated on the surfaces of the nanoropes using an in situ chemical oxidative polymerization method. It is found that the conductivity increased drastically at first and then tended to be saturation in the polymerization process. In addition, the flexibility and stretchability of the composites have been measured: With an increase of bending curvature and tensile strain, the conductivity rose at the beginning because the fibers among the nanoropes get tight; and then the conductivity dropped, which may due to the PANI layer broke and becomes discontinuous with the adding stress.


RSC Advances ◽  
2017 ◽  
Vol 7 (32) ◽  
pp. 20037-20048 ◽  
Author(s):  
Mandira Majumder ◽  
Ram Bilash Choudhary ◽  
Anukul. K. Thakur ◽  
Indrapal Karbhal

A ternary composite of polypyrrole/copper oxide/europium oxide (PPY/CuO/Eu2O3), synthesized via a facile in situ chemical oxidative polymerization method, exhibits the maximum specific capacitance of 320 F g−1 at the current density of 1 A g−1.


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