Synthesis of half-titanocenes containing 1,3-imidazolidin-2-iminato ligands of type, Cp*TiCl2[1,3-R2(CH2N)2CN]: highly active catalyst precursors in ethylene (co)polymerisation
Cp*TiCl2[1,3-(2,6-Me2C6H3)2(CH2N)2CN] showed remarkable catalytic activities for ethylene/1-hexene copolymerisation with efficient comonomer incorporation (ex. activity 1 750 000 kg-polymer per mol-Ti per h).
2003 ◽
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pp. 1941-1947
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2011 ◽
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2008 ◽
Vol 112
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pp. 11875-11880
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