Fixed bed adsorption of diquat dibromide from aqueous solution using carbon nanotubes

RSC Advances ◽  
2015 ◽  
Vol 5 (76) ◽  
pp. 61508-61512 ◽  
Author(s):  
Anthony B. Dichiara ◽  
Samuel F. Harlander ◽  
Reginald E. Rogers

Carbon nanotubes are increasingly studied as attractive adsorbents for wastewater treatment. The present work exploits the attributes of different types of CNTs in a fixed bed column for the dynamic uptake of diquat dibromide from aqueous solutions.

2009 ◽  
Vol 9 (6) ◽  
pp. 661-670 ◽  
Author(s):  
S. P. Dubey ◽  
K. Gopal

The activated carbon of Eucalyptus globulus was tested for their effectiveness in removing hexavalent chromium from aqueous solution using column experiments. Result revealed that adsorption of chromium(VI) on eucalyptus bark carbon was endothermic in nature. Thermodynamic parameters such as the entropy change, enthalpy change and Gibbs free energy change were found to be 1.39 kJ mol−1 K−1, 1.08 kJ mol−1 and −3.85 kJ mol−1, respectively. Different chromium concentrations were used for the fixed bed adsorption studies. The pre- and post-treated adsorbents were characterized using a FTIR spectroscopic technique. It was concluded that Eucalyptus bark carbon column could be used effectively for removal of hexavalent chromium from aqueous solution at optimal column conditions. This study showed that this biological material is potential adsorbent of Cr(VI) from water.


2017 ◽  
Vol 18 (2) ◽  
pp. 94-104
Author(s):  
Rozaimi Abu Samah

The main objective of this work was to design and model fixed bed adsorption column for the adsorption of vanillin from aqueous solution. Three parameters were evaluated for identifying the performance of vanillin adsorption in fixed-bed mode, which were bed height, vanillin initial concentration, and feed flow rate. The maximum adsorption capacity was increased more than threefold to 314.96 mg vanillin/g resin when the bed height was increased from 5 cm to 15 cm. Bohart-Adams model and Belter equation were used for designing fixed-bed column and predicting the performance of the adsorption process. A high value of determination coefficient (R2) of 0.9672 was obtained for the modelling of vanillin adsorption onto resin H103.


2010 ◽  
Vol 55 (9) ◽  
pp. 3548-3554 ◽  
Author(s):  
Nuria Miralles ◽  
César Valderrama ◽  
Ignasi Casas ◽  
María Martínez ◽  
Antonio Florido

2022 ◽  
Vol 10 (4) ◽  
pp. 22-30
Author(s):  
S. Valliammai ◽  
K. Gopal ◽  
R. Nithya ◽  
L. Rama Priya ◽  
D. Kavitha

A continuous adsorption study in a fixed-bed column was carried out using Multi-walled Carbon Nanotubes derived from Rosmarinus officinalis oil as an adsorbent for removing the textile dye Acid blue 40 from an aqueous solution. The adsorbent, MWNTs were prepared from Rosmarinus officinalis oil as a precursor to Fe/Mo catalyst supported on silica at 650 ºC under N2 atmosphere by spray pyrolysis process characterized by scanning electron microscopy, Transmission Electron microscopy, and Raman spectroscopy. The effects of adsorbent bed height (2–6 cm), initial ion concentration (20– 60 mg/L), and flow rate (10–30 mL/min) on the column performance were analyzed. The breakthrough curve was analyzed using the mathematical models of Thomas, Yoon-Nelson, and bed depth service time. The Thomas model at different conditions defined the behaviors of the breakthrough curves. The bed depth service time model showed good agreement with the experimental data. The high values of correlation coefficients (R2 0.9875) obtained indicate the validity of the bed depth service time model for the present column system.


Author(s):  
Marcela Levio-Raiman ◽  
Heidi Schalchli ◽  
Gabriela Briceño ◽  
Cristian Bornhardt ◽  
Gonzalo Tortella ◽  
...  

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