New insights into the elasticity and multi-level relaxation of filler network with studies on the rheology of isotactic polypropylene/carbon black nanocomposite

RSC Advances ◽  
2015 ◽  
Vol 5 (81) ◽  
pp. 65874-65883 ◽  
Author(s):  
Luqiong Yang ◽  
Shilin Huang ◽  
Feng Wu ◽  
Shaodi Zheng ◽  
Wei Yang ◽  
...  

The elasticity and multi-level relaxation behavior of filler network in isotactic polypropylene/carbon black nanocomposites were systematically studied, which was instructive for the development and application of viscoelastic materials.

2011 ◽  
Vol 289 (15-16) ◽  
pp. 1673-1681 ◽  
Author(s):  
Shilin Huang ◽  
Zhengying Liu ◽  
Chaolu Yin ◽  
Yu Wang ◽  
Yongjuan Gao ◽  
...  

2011 ◽  
Vol 011 (9) ◽  
pp. 1068-1072
Author(s):  
Shilin HUANG ◽  
Zhengying LIU ◽  
Chaolu YIN ◽  
Yongjuan GAO ◽  
Yu WANG ◽  
...  

2012 ◽  
Vol 48 (2) ◽  
pp. 702-713 ◽  
Author(s):  
Bibhu Prasad Sahoo ◽  
Kinsuk Naskar ◽  
K. Abhinav Dubey ◽  
Ram N. P. Choudhary ◽  
Deba Kumar Tripathy

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Atip Boonbumrung ◽  
Pongdhorn Sae-oui ◽  
Chakrit Sirisinha

The properties of nitrile rubber (NBR) reinforced by multiwalled carbon nanotube (MWCNT), conductive carbon black (CCB), carbon black (CB), and precipitated silica (PSi) were investigated via viscoelastic behavior, bound rubber content, electrical properties, cross-link density, and mechanical properties. The filler content was varied from 0 to 15 phr. MWCNT shows the greatest magnitude of reinforcement considered in terms of tensile strength, modulus, hardness, and abrasion resistance followed by CCB, CB, and PSi. The MWCNT filled system also exhibits extremely high levels of filler network and trapped rubber even at relatively low loading (5 phr) leading to high electrical properties and poor dynamic mechanical properties. Although CCB possesses the highest specific surface area, it gives lower level of filler network than MWCNT and also gives the highest elongation at break among all fillers. Both CB and PSi show comparable degree of reinforcement which is considerably lower than CCB and MWCNT.


Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1653
Author(s):  
Imran Hussain Syed ◽  
Jorge Lacayo-Pineda

A systematic study of several SBR compounds filled with carbon black of various grades were analysed with the high-frequency Dynamic Mechanical Analyzer (HF DMA) in order to quantify the degree of nonlinearity induced by fillers in rubber compounds. These filler grades indirectly reflect different degrees of microdispersion, which seems to be the main influence on the superharmonic resonance phenomenon observed in HF DMA. This statement arises from the comparison of the microdispersion observed in TEM images. In the second part of the paper, a model compound filled with carbon black is enhanced with a standard reinforcing resin, which leads to a more compact filler network. This induces a higher superharmonic resonance response as well as a higher transmissibility behaviour.


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