Controlled synthesis and luminescent properties of assembled spherical YPxV1−xO4:Ln3+ (Ln = Eu, Sm, Dy or Tm) phosphors with high quantum efficiency

RSC Advances ◽  
2015 ◽  
Vol 5 (65) ◽  
pp. 52533-52542 ◽  
Author(s):  
Zhibin An ◽  
Xiuzhen Xiao ◽  
Jun Yu ◽  
Dongsen Mao ◽  
Guanzhong Lu

Controlled morphology and energy transfer in assembled spherical YPxV1−xO4:Ln3+ (Ln = Eu, Sm, Dy or Tm) phosphors with higher luminescent quantum efficiency by the EDTA-assisted hydrothermal method.

Molecules ◽  
2019 ◽  
Vol 24 (4) ◽  
pp. 759 ◽  
Author(s):  
Dong Zhu ◽  
Jinkai Li ◽  
Xiangyang Guo ◽  
Qinggang Li ◽  
Hao Wu ◽  
...  

(Gd0.93−xTb0.07Eux)2O3 (x = 0–0.10) phosphors shows great potential for applications in the lighting and display areas. (Gd0.93−xTb0.07Eux)2O3 phosphors with controlled morphology were prepared by a hydrothermal method, followed by calcination at 1100 °C. XRD, FE-SEM, PL/PLE, luminescent decay analysis and thermal stability have been performed to investigate the Eu3+ content and the effects of hydrothermal conditions on the phase variation, microstructure, luminescent properties and energy transfer. Optimum excitation wavelength at ~308 nm nanometer ascribed to the 4f8-4f75d1 transition of Tb3+, the (Gd0.93−xTb0.07Eux)2O3 phosphors display both Tb3+and Eu3+ emission with the strongest emission band at ~611 nm. For increasing Eu3+ content, the Eu3+ emission intensity increased as well while the Tb3+ emission intensity decreased owing to Tb3+→Eu3+ energy transfer. The energy transfer efficiencies were calculated and the energy transfer mechanism was discussed in detail. The lifetime for both the Eu3+ and Tb3+ emission decreases with the Eu3+ addition, the former is due to the formation of resonant energy transfer net, and the latter is because of contribution by Tb3+→Eu3+ energy transfer. The phosphor morphology can be controlled by adjusting the hydrothermal condition (reaction pH), and the morphological influence to the luminescent properties (PL/PLE, decay lifetime, etc.) has been studied in detail.


2017 ◽  
Vol 41 (17) ◽  
pp. 8947-8958 ◽  
Author(s):  
Paramananda Jena ◽  
Santosh K. Gupta ◽  
Narendra Kumar Verma ◽  
Akhilesh Kumar Singh ◽  
R. M. Kadam

Red purity and high quantum efficiency of BaWO4:Eu3+ projects it as a new red phosphor for application in white LEDs.


2020 ◽  
Vol 8 (48) ◽  
pp. 17176-17184
Author(s):  
Dan Wu ◽  
Yu Xiao ◽  
Liangliang Zhang ◽  
Xiaoling Dong ◽  
Shifeng Zhao ◽  
...  

A high quantum efficiency and improved thermal stability can be achieved with the introduction of Tb3+ into Ca3Gd2Si6O18:Ce3+.


Author(s):  
Kai Li ◽  
Ying Ye ◽  
Wenchao Zhang ◽  
Yuzhou Hu ◽  
Ying Yang ◽  
...  

Nontoxic cadmium-free ZnS and ZnSe QDs QDs with high quantum efficiency have drawn considerable attention for information display. Applications of ZnS and ZnSe QDs are limited by their short emission...


Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 428
Author(s):  
Reza Masoudian Saadabad ◽  
Christian Pauly ◽  
Norbert Herschbach ◽  
Dragomir N. Neshev ◽  
Haroldo T. Hattori ◽  
...  

Fast detection of near-infrared (NIR) photons with high responsivity remains a challenge for photodetectors. Germanium (Ge) photodetectors are widely used for near-infrared wavelengths but suffer from a trade-off between the speed of photodetection and quantum efficiency (or responsivity). To realize a high-speed detector with high quantum efficiency, a small-sized photodetector efficiently absorbing light is required. In this paper, we suggest a realization of a dielectric metasurface made of an array of subwavelength germanium PIN photodetectors. Due to the subwavelength size of each pixel, a high-speed photodetector with a bandwidth of 65 GHz has been achieved. At the same time, high quantum efficiency for near-infrared illumination can be obtained by the engineering of optical resonant modes to localize optical energy inside the intrinsic Ge disks. Furthermore, small junction capacitance and the possibility of zero/low bias operation have been shown. Our results show that all-dielectric metasurfaces can improve the performance of photodetectors.


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