POSS-tethered fluorinated diblock copolymers with linear- and star-shaped topologies: synthesis, self-assembled films and hydrophobic applications

RSC Advances ◽  
2015 ◽  
Vol 5 (68) ◽  
pp. 55048-55058 ◽  
Author(s):  
Aizhao Pan ◽  
Shao Yang ◽  
Ling He
Keyword(s):  
Diblock Copolymers ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Self Assembled ◽  
Oligomeric Silsesquioxane

Polyhedral oligomeric silsesquioxane (POSS) tethered fluorinated diblock copolymers are synthesized using octakis(dibromoethyl)POSS and aminopropylisobutyl POSS initiation of methylmethacrylate and dodecafluoroheptylmethacrylate.

Structural complexity induced by topology change in hybrids consisting of hexa-peri-hexabenzocoronene and polyhedral oligomeric silsesquioxane

2017 ◽  
Vol 53 (62) ◽  
pp. 8679-8682 ◽  
Author(s):  
Meng-Yao Zhang ◽  
Sheng Zhou ◽  
Hong-Bing Pan ◽  
Jing Ping ◽  
Wei Zhang ◽  
...  
Keyword(s):  
Polyhedral Oligomeric Silsesquioxane ◽  
Structural Complexity ◽  
Topology Change ◽  
New Approach ◽  
Design And Synthesis ◽  
Self Assembled ◽  
Oligomeric Silsesquioxane ◽  
Synthesis Of Materials

Increasing POSS content (or changing topology) of organic–inorganic hybrids with HBC and POSS results in more complex self-assembled structures. This work provides a new approach for the design and synthesis of materials with sub-10 nm sizes.

Strong and fast-recovery organic/inorganic hybrid AuNPs–supramolecular gels based on loofah-like 3D networks

Soft Matter ◽  
2016 ◽  
Vol 12 (3) ◽  
pp. 957-964 ◽  
Author(s):  
Huiwen He ◽  
Si Chen ◽  
Xiaoqian Tong ◽  
Yining Chen ◽  
Bozhen Wu ◽  
...  
Keyword(s):  
Gold Nanoparticle ◽  
Three Dimensional ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Fast Recovery ◽  
Inorganic Hybrid ◽  
Supramolecular Gels ◽  
Self Assembled ◽  
Oligomeric Silsesquioxane ◽  
First Time ◽  
3D Networks

Super strong and fast-recovery organic/inorganic hybrid gold nanoparticle (AuNPs)-supramolecular gels based on a three-dimensional loofah-like nanoscale network self-assembled by polyhedral oligomeric silsesquioxane (POSS) core supramolecular gelators are reported for the first time.

Functional groups on POSS nanoparticles influence the self-assembled structures of diblock copolymer composites

RSC Advances ◽  
2014 ◽  
Vol 4 (66) ◽  
pp. 34849-34859 ◽  
Author(s):  
Yi-Syuan Lu ◽  
Shiao-Wei Kuo
Keyword(s):  
Functional Groups ◽  
Diblock Copolymer ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
The Self ◽  
Self Assembled ◽  
Oligomeric Silsesquioxane ◽  
Copolymer Composites

The influence of the functional groups presented by polyhedral oligomeric silsesquioxane (POSS) nanoparticles (NPs) on the self-assembled structures formed by diblock copolymer composites were detail discussed.

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