Hierarchical porous nano-MFI zeolite-pillared montmorillonite clay synthesized by recrystallization for hydrocracking of residual oil

RSC Advances ◽  
2015 ◽  
Vol 5 (57) ◽  
pp. 46104-46108 ◽  
Author(s):  
Zhiming Ren ◽  
Baoshan Li ◽  
Liwen Yue ◽  
Naijin Wu ◽  
Kaixuan Lv ◽  
...  

An MFI zeolite nanosheet-pillared montmorillonite clay (MPC) with a uniform hierarchical structure was synthesized by a recrystallization method.

2007 ◽  
Vol 313 (2) ◽  
pp. 747-750 ◽  
Author(s):  
Atsushi Itadani ◽  
Masashi Tanaka ◽  
Takahiro Abe ◽  
Hideki Taguchi ◽  
Mahiko Nagao

1998 ◽  
Vol 4 (S2) ◽  
pp. 744-745
Author(s):  
P. A. Crazier ◽  
M. Pan ◽  
C. Bateman ◽  
J. J. Alcaraz ◽  
J. S. Holmgren

The ability to vary the plane spacing in different clays is becoming increasingly important in catalysis and other technological applications [Baker and Murrell, 1990]. Considerable effort is now being devoted to understanding the mechanisms involved in pillaring such materials with a view to being able to fine-tune parameters such as the plane spacing and active sites for the application of interest. We have been able to use analytical electron microscopy to directly image the pillars in zirconia pillared montmorillonite. By using a combination of TEM techniques, we are able to correlate morphological information with elemental composition and conclusively identify the location of the zirconia pillars.A sample of natural montmorillonite clay, trade name HPM-20, was obtained from American Colloid and used as received. Zirconia pillared clays were prepared following published procedures [Bartley, 1988]. The Z1O2 pillars were prepared by using hydroxyzirconium cations produced by the solvation of zironyl chloride.


2018 ◽  
Vol 352 ◽  
pp. 445-461 ◽  
Author(s):  
Swapnil H. Adsul ◽  
T. Siva ◽  
S. Sathiyanarayanan ◽  
Shirish H. Sonawane ◽  
R. Subasri

Jurnal Kimia ◽  
2020 ◽  
pp. 82
Author(s):  
D. A. D. N. Dewi ◽  
I N. Simpen ◽  
I W. Suarsa

A montmorillonite clay modified with semiconductor metal can act as a photocatalyst material. Montmorillonite clays were chosen because of their natural characteristics which are easily to be modified and have high specific surface area. This research aims to modify montmorillonite clay into photocatalyst material. The montmorillonite clay was intercalated using Fe2O3 to produce Fe2O3-pillared montmorillonite clay, then doped with TiO2 to form a photocatalyst material Fe2O3-PILC / TiO2. Modifications were intended to increase the specific surface area and number of active photocatalyst sites and thus increase the ability of photodegradation. The characterization carried out included characterizing the pillar formation using X-ray Diffraction (XRD), specific surface area by the BET method (Bruneau, Emmet, and Teller), a the number of surface acid-base sites by the titration method. Photocatalyst with the best character was Fe2O3-PILC / TiO2 1: 3 with specific surface area, number of acid and base sites respectively 45,947 m2/g, 20,1736 x 1023 sites/gram and 19,0044 x 1023 sites/gram. The result of photodegradation at optimum condition with visible light at pH 3 using 400 mg photocatalyst was 99.84%.   Keywords: photocatalyst, Fe2O3, montmorillonite clay, TiO2, rhodamine B


Author(s):  
Xia Gao ◽  
Huibin Pan ◽  
Chengfang Qiao ◽  
Yongliang Liu ◽  
Chun-Sheng Zhou ◽  
...  

MOF-derived porous materials Co3O4 and Co/C with hierarchical structure (MHCo3O4 & Co/C) were prepared by the self-sacrificial template strategy, and the surface of such materials were functionally modified with "polydopamine...


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